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    • 1. 发明申请
    • THERMAL REDUCTION OF SULFUR DIOXIDE TO SULFUR WITH TEMPERATURE CONTROLLED FURNACE
    • 硫化二氧化硫与温度控制炉的热降低
    • WO2012177281A1
    • 2012-12-27
    • PCT/US2011/061143
    • 2011-11-17
    • RAMESHNI, Mahin
    • RAMESHNI, MahinSANTO, Stephen, L.
    • C01B17/04
    • C01B17/0404C01B3/36C01B17/0408C01B17/0421C01B17/0478C01B17/164C01B2203/025C01B2203/045C01B2203/0485Y02P20/129
    • Processes for the thermal reduction of sulfur dioxide to elemental sulfur are described and disclosed. The processes described include three general reaction sections, including the reaction furnace portion where the S02-containing stream is combusted, the second reaction zone where the temperature is moderated to encourage the reaction of sulfur with hydrogen to consume the hydrogen carbon monoxide and produce the H2S and CO with allowing adequate residence time. The temperature moderation is achieved by one or combinations of three different methods including adding external waste heat boiler, using inter-stage internal cooling coil or adding a quench fluid. The third reaction zone is a Claus conversion portion, wherein residual H2S and S02 are further reacted to produce additional elemental sulfur in one or more reactors containing Claus type catalyst or combination of them.
    • 描述和公开了将二氧化硫热还原成元素硫的方法。 所描述的方法包括三个通用反应段,包括含有含SO 2的物流燃烧的反应炉部分,温度调节的第二反应区域,以促进硫与氢气反应以消耗氢气一氧化碳并产生H 2 S 和CO,允许足够的停留时间。 温度调节是通过一种或三种不同方法的组合实现的,包括添加外部余热锅炉,使用阶段内冷却盘管或加入淬火液。 第三反应区是克劳斯转化部分,其中残余的H 2 S和SO 2进一步反应以在一个或多个含克劳斯型催化剂或它们的组合的反应器中产生另外的元素硫。