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1. 发明申请

WO1997000282A1 WATER-SOLUBLE FILMS 审中-公开
标题翻译：水溶胶膜
公开(公告)号：WO1997000282A1
公开(公告)日：1997-01-03
申请号：PCT/GB1996001264
申请日：1996-05-24
申请人： ZENECA RESINS B.V. , ZENECA LIMITED , HEUTS, Martinus, Petrus, Josef , PADGET, John, Christopher
发明人： ZENECA RESINS B.V. , ZENECA LIMITED
IPC分类号： C08J05/18
CPC分类号： C08J5/18 , B65D65/46 , C08J2333/06 , C08L33/064 , C08L33/12 , C08L2666/04
摘要： Water-soluble film, suitable for sachets, comprised of a combination of soft and hard acid-functional polymers having Tg's of /= 40 DEG C respectively, the polymers being at least partially neutralised and present in a weight ratio (soft to hard polymer) within the range 90/10 to 65/35. Sachets made from the film are particularly suitable for packaging agrochemical and laundry care compositions.
摘要翻译：适用于小袋的水溶性薄膜分别由Tg分别为Tg = 20℃和40℃的软酸和硬酸功能聚合物的组合组成，聚合物至少部分中和并以重量比存在（软硬聚合物）在90/10至65/35的范围内。由该片制成的香囊特别适用于包装农药和洗衣护理组合物。

2. 发明申请

WO1995031512A1 AQUEOUS COATING COMPOSITIONS 审中-公开
标题翻译：水性涂料组合物
公开(公告)号：WO1995031512A1
公开(公告)日：1995-11-23
申请号：PCT/GB1995001005
申请日：1995-05-02
申请人： ZENECA LIMITED , PADGET, John, Christopher , CAREY, John, Gerard , PEARS, David, Alan
发明人： ZENECA LIMITED
IPC分类号： C09D133/06
CPC分类号： C09D133/066 , C07F7/1804 , C08G59/306 , C08G59/3254 , C08G59/4085 , C08K5/5435 , C08L33/066 , C08L63/00 , C09D201/10 , Y10T428/31511 , C08L2666/14 , C08L2666/28
摘要： A composition comprising water and the following components: (a) an epoxy compound comprising at least one epoxy group and at least one hydrolysable silyl group; and (b) a hydroxy functional polymer having carboxy and/or sulpho groups. The compositions are generally water-based and may be used for making films and coatings having good mechanical and physical properties.
摘要翻译：包含水和以下组分的组合物：（a）包含至少一个环氧基和至少一个可水解甲硅烷基的环氧化合物; 和（b）具有羧基和/或磺基的羟基官能聚合物。组合物通常是水基的，并且可以用于制备具有良好机械和物理性质的膜和涂层。

3. 发明申请

WO0233012A3 AQUEOUS VINYL POLYMER COATING COMPOSITIONS 审中-公开
标题翻译：水性聚乙烯涂料组合物
公开(公告)号：WO0233012A3
公开(公告)日：2003-03-13
申请号：PCT/GB0104510
申请日：2001-10-11
申请人： AVECIA BV , AVECIA LTD , OVERBEEK GERARDUS CORNELIS , SCHEERDER JURGEN , MARTIN EMILIO , BUCKMANN ALFRED JEAN PAUL , ANNABLE TOM , PADGET JOHN CHRISTOPHER
发明人： OVERBEEK GERARDUS CORNELIS , SCHEERDER JURGEN , MARTIN EMILIO , BUCKMANN ALFRED JEAN PAUL , ANNABLE TOM , PADGET JOHN CHRISTOPHER
IPC分类号： C09D133/06 , C09D201/00 , C09D5/02
CPC分类号： C09D201/00 , C09D133/062 , C08L2666/02
摘要： An aqueous coating composition comprising a crosslinkable water-dispersible vinyl oligomer(s) wherein said composition when drying to form a coating has an open time of at least 20 minutes, a wet edge time of at least 10 minutes, a tack free time of and at 23 + 2 DEG C..
摘要翻译：一种包含可交联的水分散性乙烯基低聚物的水性涂料组合物，其中当干燥形成涂料时所述组合物的开放时间为至少20分钟，湿边缘时间为至少10分钟，使用任何剪切速率在9±0.5〜90±5s -1和23±2℃的范围内干燥20〜55重量％时，任何固形物含量为5,000Pa.s ..

4. 发明申请

WO1994021738A1 CROSSLINKABLE COATING COMPOSITIONS 审中-公开
标题翻译：可交联涂料组合物
公开(公告)号：WO1994021738A1
公开(公告)日：1994-09-29
申请号：PCT/GB1994000496
申请日：1994-03-14
申请人： ZENECA LIMITED , YEATES, Stephen, George , THOMAS, Mark , BROWN, Richard, Andrew , PADGET, John, Christopher
发明人： ZENECA LIMITED
IPC分类号： C09D201/06
CPC分类号： C09D167/00 , C09D133/062 , C09D201/06 , C08L2666/28
摘要： A crosslinkable liquid carrier-based coating composition formulated from components comprising an organic polymer(s) having acetoacetyl group functionality, a polyamine compound(s) having at least two acetoacetyl-reactive amino groups per molecule, and a non-polymeric monoacetoacetyl compound(s) which can evaporate on coating formulation selected from at least one of alkyl acetoacetate, alkyl acetoacetamide and 1-alkyl-1,3-butanedione where said alkyl groups in said compounds have from 1 to 3 carbon atoms, and wherein the ratio of the number of acetoacetyl groups from said monoacetoacetyl compound(s) to the number of polymer-bound acetoacetyl groups from said organic polymer(s) having acetoacetyl group functionality is within the range of from 0.8/1 to 1.5/1. The preferred monoacetoacetyl compound is methyl acetoacetate.
摘要翻译：由包含具有乙酰乙酰基官能团的有机聚合物的组分配配的可交联液体载体基涂料组合物，每分子具有至少两个乙酰乙酰基反应性氨基的多胺化合物和非聚合单乙酰乙酰化合物），其可以在选自至少一种乙酰乙酸烷基酯，烷基乙酰乙酰胺和1-烷基-1,3-丁二酮的涂料配方上蒸发，其中所述化合物中的所述烷基具有1至3个碳原子，并且其中数目的乙酰乙酰基从所述单乙酰乙酰化合物到具有乙酰乙酰基官能团的所述有机聚合物的聚合物结合的乙酰乙酰基的数目在0.8 / 1-1.5 / 1的范围内。优选的单乙酰乙酰化合物是乙酰乙酸甲酯。

5. 发明申请

WO1993018075A2 AQUEOUS COATING COMPOSITIONS 审中-公开
标题翻译：水性涂料组合物
公开(公告)号：WO1993018075A2
公开(公告)日：1993-09-16
申请号：PCT/GB1993000468
申请日：1993-03-05
申请人： ZENECA LIMITED , SATGURUNATHAN, Rajasingham , HINDE, David, Charles , PADGET, John, Christopher , CAREY, John, Gerard
发明人： ZENECA LIMITED
IPC分类号： C08G59/32
CPC分类号： C09D167/00 , C08L51/003 , C08L67/00 , C08L75/04 , C09D133/068 , C09D151/003 , C09D175/04 , Y10T428/31855 , C08L2666/14 , C08L2666/04 , C08L51/00 , C08L33/00
摘要： Aqueous curable polymer dispersion comprising a polyester and/or polyurethane and a polymeric product having a Tg from 25-100 DEG C obtainable by free-radical polymerisation of a mixture of (a) an olefinic monomer free from epoxy and epoxy reactive groups, (b) a monomer and/or oligomer having at least two epoxy groups and (c) a group reactive towards epoxy groups.
摘要翻译：包含聚酯和/或聚氨酯的聚合物水分散体和通过（a）不含环氧树脂和环氧反应性基团的烯烃单体的混合物的自由基聚合可获得的Tg为25-100℃的聚合产物，（b ）具有至少两个环氧基团的单体和/或低聚物和（c）对环氧基团具有反应性的基团。

6. 发明申请

WO1996019512A1 METHOD OF GRAFTING 审中-公开
标题翻译：招募方式
公开(公告)号：WO1996019512A1
公开(公告)日：1996-06-27
申请号：PCT/EP1995005021
申请日：1995-12-19
申请人： ZENECA LIMITED , ZENECA RESINS B.V. , PADGET, John, Christopher , BEDELLS, Alison, Dawn , OVERBEEK, Gerardus, Cornelis
发明人： ZENECA LIMITED , ZENECA RESINS B.V.
IPC分类号： C08F291/00
CPC分类号： C08F290/141 , C08F291/00 , C08F2/16
摘要： Method of grafting a water-soluble organic oligomer(s) to an organic polymer(s) in aqueous latex form, which method comprises forming a water-based mixture of a water-soluble oligomer(s), an aqueous latex of a polymer(s), and at least one free radical polymerisable monomer, both of said oligomer(s) and polymer(s) being preformed, and carrying out free radical polymerisation of said at least one monomer to effect grafting between said oligomer(s) and said polymer(s).
摘要翻译：将水溶性有机低聚物以水性胶乳形式接枝到有机聚合物的方法，该方法包括形成水溶性低聚物，聚合物的水性胶乳的水基混合物（ s）和至少一种可自由基可聚合单体，所述低聚物和聚合物都被预先形成，并且进行所述至少一种单体的自由基聚合以实现所述低聚物和所述聚合物之间的接枝聚合物（S）。

7. 发明申请

WO1993023486A1 AQUEOUS COATING COMPOSITIONS 审中-公开
标题翻译：水性涂料组合物
公开(公告)号：WO1993023486A1
公开(公告)日：1993-11-25
申请号：PCT/GB1993000969
申请日：1993-05-12
申请人： ZENECA LIMITED , SATGURUNATHAN, Rajasingham , PADGET, John, Christopher , CAREY, John, Gerard
发明人： ZENECA LIMITED
IPC分类号： C09D133/06
CPC分类号： C09D133/064 , C09D133/066 , Y10T428/31786 , Y10T428/31935 , C08L2666/54 , C08L2666/28
摘要： An aqueous crosslinkable coating composition comprising an aqueous dispersion of: (A) at least one copolymer, said copolymer being obtainable or derived from the addition polymerisation of 2 or more olefinically unsaturated monomers and bearing lateral carboxyl groups which are provided at least in part by polymerised units in said copolymer of a monomer of formula (1): CH2=CR -Q-CO2H, where R is H or lower alkyl of 1 to 5 carbon atoms and Q is a non carboxyl-containing spacer group providing a spacer chain of at least 3 atoms, and (B) at least one carboxyl-reactive material for providing crosslinking during and/or after coating formation from the composition in which the polymer-bound carboxyl groups provided by the monomer of formula (1) take part, and wherein the components (A) and (B) are provided by different and/or the same substance(s).
摘要翻译：一种含水可交联涂料组合物，其包含以下物质的水性分散体：（A）至少一种共聚物，所述共聚物可获得或衍生自2种或更多种烯属不饱和单体的加成聚合并带有侧向羧基，其至少部分地由聚合的式（1）单体的所述共聚物中的单元：CH 2 = CR 1 -Q-CO 2 H，其中R 1是H或1至5个碳原子的低级烷基，Q是不含羧基的间隔基提供至少3个原子的间隔链，和（B）至少一种羧基反应性材料，用于在组合物中和/或之后提供交联，其中由式（1）的单体提供的聚合物键合的羧基），其中组分（A）和（B）由不同的和/或相同的物质提供。

8. 发明申请

WO1998021118A1 SOLUBLE SACHET FOR WATER-BASED COMPOSITIONS 审中-公开
标题翻译：用于水基组合物的可溶性香料
公开(公告)号：WO1998021118A1
公开(公告)日：1998-05-22
申请号：PCT/GB1997002889
申请日：1997-10-16
申请人： ZENECA LIMITED , PADGET, John, Christopher , YEATES, Terence , HINDE, David, Charles , LANDHAM, Rowena, Roshanthi
发明人： ZENECA LIMITED
IPC分类号： B65D65/46
CPC分类号： C11D17/043
摘要： Water-soluble sachet suitable for packaging a water-based composition the sachet comprising a water-soluble film which is formed from an aqueous solution or dispersion of a water-soluble organic polymer in admixture with an aqueous dispersion of wax(es).
摘要翻译：适用于包装水性组合物的水溶性小袋包含由水溶性有机聚合物的水溶液或分散体与蜡水分散体混合形成的水溶性薄膜的香囊。

9. 发明申请

WO1995031511A1 AQUEOUS COATING COMPOSITIONS 审中-公开
标题翻译：水性涂料组合物
公开(公告)号：WO1995031511A1
公开(公告)日：1995-11-23
申请号：PCT/GB1995001004
申请日：1995-05-02
申请人： ZENECA LIMITED , PADGET, John, Christopher , CAREY, John, Gerard , PEARS, David, Alan
发明人： ZENECA LIMITED
IPC分类号： C09D133/06
CPC分类号： C09D133/064 , C07D303/16 , C07D303/24 , C08G59/28 , C08G59/3227 , C08K5/17 , C08K5/5435 , C08K5/544 , C09D133/068 , C09D163/00 , C08L33/062 , C08L2666/02 , C08L2666/44 , C08L2666/36
摘要： A composition comprising water and the following components: (a) an epoxy compound comprising at least one epoxy group and at least one nitrogen atom; and (b) a carboxy functional polymer, a hydroxy functional polymer, a polymer having carboxy and hydroxy functionality, or a mixture comprising two or more of said polymers; provided that when the epoxy compound has only one epoxy group it has at least one hydrolysable silyl group. Also claimed are epoxy cross-linkers, films, coatings and processes for their preparation.
摘要翻译：一种包含水和以下组分的组合物：（a）包含至少一个环氧基和至少一个氮原子的环氧化合物; 和（b）羧基官能聚合物，羟基官能聚合物，具有羧基和羟基官能团的聚合物，或包含两种或更多种所述聚合物的混合物; 条件是当环氧化合物仅具有一个环氧基时，它具有至少一个可水解的甲硅烷基。还要求的是环氧交联剂，薄膜，涂料及其制备方法。

10. 发明申请

WO1995029944A1 PRODUCTION OF AQUEOUS POLYMER COMPOSITIONS 审中-公开
标题翻译：生产水性聚合物组合物
公开(公告)号：WO1995029944A1
公开(公告)日：1995-11-09
申请号：PCT/GB1995000948
申请日：1995-04-27
申请人： ZENECA RESINS BV , ZENECA LIMITED , OVERBEEK, Gerardus, Cornelis , SMAK, Yvonne, Wilhelmina , BUCKMANN, Alfred, Jean, Paul , PADGET, John, Christopher
发明人： ZENECA RESINS BV , ZENECA LIMITED
IPC分类号： C08F265/04
CPC分类号： C09D151/00 , C08F265/04 , C08F265/06 , C08F2/22
摘要： Process for making organic solvent-free aqueous crosslinkable polymer composition comprising: a) preparing an aqueous solution of an acid-functional oligomer with Tg below 50 DEG C and having crosslinker functional groups; b) conducting an aqueous emulsion polymerisation to make an aqueous emulsion of an olefinic hydrophobic polymer in the presence of the aqueous oligomer solution, the hydrophobic polymer having Tg at least 25 DEG C higher than that of the oligomer and optionally crosslinker functional groups, and c) combining with a crosslinking agent reactable with the crosslinker groups of the oligomer and polymer, said composition having Koening hardness of >/= 40 sec. and minimum film forming temperature (MFFT)
摘要翻译：制备无机溶剂的含水可交联聚合物组合物的方法，包括：a）制备Tg低于50℃并具有交联剂官能团的酸官能低聚物的水溶液; b）进行水性乳液聚合以在低聚物溶液的存在下制备烯属疏水性聚合物的水性乳液，所述疏水性聚合物的Tg比低聚物和任选的交联剂官能团的Tg高至少25℃，c ）与可与低聚物和聚合物的交联剂基团反应的交联剂组合，所述组合物具有≥40秒的科宁硬度。和最低成膜温度（MFFT）<55℃。此外，如此形成的水性组合物及其在各种应用中的用途。水性组合物具有优异的性能，特别是MFFT和Koening硬度的有利平衡。

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