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1. 发明申请

WO2010106053A2 PROCESS FOR CONVERTING POLYSACCHARIDES IN AN INORGANIC MOLTEN SALT HYDRATE 审中-公开
标题翻译：在无机盐水中转化多糖的方法
公开(公告)号：WO2010106053A2
公开(公告)日：2010-09-23
申请号：PCT/EP2010/053359
申请日：2010-03-16
申请人： BIOeCON INTERNATIONAL HOLDING N.V. , MAKKEE, Michiel , MOULIJN, Jacob Adriaan , MENEGASSI DE ALMEIDA, Rafael , O'CONNOR, Paul
发明人： MAKKEE, Michiel , MOULIJN, Jacob Adriaan , MENEGASSI DE ALMEIDA, Rafael , O'CONNOR, Paul
IPC分类号： C07H1/00
CPC分类号： C07D493/04 , C07D307/20
摘要： A process is disclosed for converting a polysaccharide-containing biomass material to platform chemicals. The process comprises dissolving the polysaccharides in an inorganic molten salt hydrate, converting the polysaccharides to monosaccharides, and converting the monosaccharides to dehvatized (di) anhydro sugars that are easily separable from the inorganic molten salt hydrate. The dehvatized (di) anhydro sugars are useful as fuel additives and fuel substitutes.
摘要翻译：公开了将含多糖的生物质材料转化为平台化学品的方法。该方法包括将多糖溶解在无机熔融盐水合物中，将多糖转化为单糖，并将单糖转化为易于与无机熔融盐水合物分离的脱氢化（二）脱氢糖。脱氢（di）脱氢糖可用作燃料添加剂和燃料替代品。

2. 发明申请

WO1994009901A1 CATALYST ELEMENT, REACTOR COMPRISING SUCH CATALYST ELEMENT, DIE FOR PRODUCING SUCH CATALYST ELEMENT, AND METHOD FOR THE HYDROGENATING CONVERSION OF AN OIL 审中-公开
标题翻译：催化元件，包含这种催化元素的反应器，用于生产这种催化元素的DIE，以及油的氢化转化方法
公开(公告)号：WO1994009901A1
公开(公告)日：1994-05-11
申请号：PCT/NL1993000231
申请日：1993-11-04
申请人： TECHNISCHE UNIVERSITEIT DELFT , SIE, Swan, Tiong , CYBULSKI, Andrzej , MOULIJN, Jacob, Adriaan
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： B01J35/04
CPC分类号： B01J19/2485 , B01J19/24 , B01J19/32 , B01J35/04 , B01J2219/32293 , B01J2219/32296 , B01J2219/32425 , B01J2219/32466
摘要： There is described a catalyst element (1) consisting of an integral whole having channels (2) extending therethrough. These channels (2) have, in circumferential sense of the cross section thereof, at least one concave wall portion and at least one convex wall portion, preferably provided by longitudinal projections (4) or grooves (7). As a result, a liquid phase (10) will preferentially be located in cavities (5) defined along the channel walls, and a gas phase (20) will preferentially be located centrally in the channels (2). Consequently, the catalyst element (1) according to the invention offers the possibility of being operated in countercurrent mode with only a slight loss of pressure.
摘要翻译：描述了由具有从其延伸的通道（2）的一体整体组成的催化剂元件（1）。这些通道（2）在其横截面的圆周方向具有至少一个凹壁部分和至少一个凸形壁部分，优选地由纵向突起（4）或凹槽（7）提供。结果，液相（10）将优先位于沿着通道壁限定的空腔（5）中，气相（20）将优先位于通道（2）的中央。因此，根据本发明的催化剂元件（1）提供以仅具有轻微的压力损失的逆流模式操作的可能性。

3. 发明申请

WO2012035160A1 SIMULTANEOUS HYDROLYSIS AND HYDROGENATION OF CELLULOSE 审中-公开
标题翻译：同时水解和加氢纤维素
公开(公告)号：WO2012035160A1
公开(公告)日：2012-03-22
申请号：PCT/EP2011066156
申请日：2011-09-16
申请人： BIOECON INT HOLDING NV , MAKKEE MICHIEL , MOULIJN JACOB ADRIAAN , LI JIANRONG , O'CONNOR PAUL , RASSER JACOBUS CORNELIS , ROSHEUVEL ARMAND EDUARD
发明人： MAKKEE MICHIEL , MOULIJN JACOB ADRIAAN , LI JIANRONG , O'CONNOR PAUL , RASSER JACOBUS CORNELIS , ROSHEUVEL ARMAND EDUARD
IPC分类号： C08B15/02 , C07C31/26 , C08B16/00
CPC分类号： C07C29/132 , C08B15/02 , C08B16/00 , C07C31/26
摘要： A process is disclosed for conversion of cellulose in an Ionic Liquid medium. The process is characterized in that a cellulose-containing feedstock and an Ionic Liquid are mixed at a temperature below 80 °C. The mixture is heated to a conversion temperature in the range of 80 °C to 220 °C under a hydrogen atmosphere. The presence of hydrogen during the heating step significantly reduces the formation of degradation products.
摘要翻译：公开了用于在离子液体介质中转化纤维素的方法。该方法的特征在于将含纤维素的原料和离子液体在低于80℃的温度下混合。将混合物在氢气氛下加热到80℃至220℃范围内的转化温度。在加热步骤期间氢的存在显着降低了降解产物的形成。

4. 发明申请

WO2010106057A1 PROCESS FOR CONVERTING POLYSACCHARIDES IN AN INORGANIC MOLTEN SALT HYDRATE 审中-公开
标题翻译：在无机盐水中转化多糖的方法
公开(公告)号：WO2010106057A1
公开(公告)日：2010-09-23
申请号：PCT/EP2010/053363
申请日：2010-03-16
申请人： BIOeCON INTERNATIONAL HOLDING N.V. , MAKKEE, Michiel , MOULIJN, Jacob Adriaan
发明人： MAKKEE, Michiel , MOULIJN, Jacob Adriaan
IPC分类号： C07D493/04 , C08B37/00 , C10L1/18 , C13K1/02
CPC分类号： C07D493/04 , C08H8/00 , C10L1/1852 , C10L1/191 , C13K1/02
摘要： A process is disclosed for converting polysaccharide-containing biomass material to platform chemicals. The process comprises dissolving the polysaccharides in an inorganic molten salt hydrate, converting the polysaccharides to monosaccharides, and converting the monosaccharides to platform chemicals that are easily separable from the inorganic molten salt hydrate. The process comprises a dehydration step in which sugar alcohols are converted to the corresponding (di) anhydro sugars. The dehydration step is carried out in the substantial absence of transition metal salts.
摘要翻译：公开了将多糖生物质材料转化为平台化学品的方法。该方法包括将多糖溶解在无机熔融盐水合物中，将多糖转化为单糖，并将单糖转化为易于与无机熔融盐水合物分离的平台化学品。该方法包括将糖醇转化成相应的（二）脱水糖的脱水步骤。脱水步骤基本上不存在过渡金属盐进行。

5. 发明申请

WO2008101949A1 IMPROVED PROCESS FOR CONVERTING CARBON-BASED ENERGY CARRIER MATERIAL 审中-公开
标题翻译：改进基于碳的能量载体材料的改进方法
公开(公告)号：WO2008101949A1
公开(公告)日：2008-08-28
申请号：PCT/EP2008/052050
申请日：2008-02-20
申请人： BIOECON INTERNATIONAL HOLDING N.V. , O'CONNOR, Paul , MOULIJN, Jacob Adriaan
发明人： O'CONNOR, Paul , MOULIJN, Jacob Adriaan
IPC分类号： C10G1/00 , C10G1/08 , C10G11/00
CPC分类号： C10B49/20 , C10G1/08 , C10G11/18 , Y02E50/14
摘要： A catalytic process is disclosed for converting solid or high viscosity carbon-based energy carrier materials, such as heavy crudes, oil sands, synthetic polymeric wastes and cellulosic or aquatic biomass. The conversion temperature is less than 450°C. The reaction products are separated from the catalyst within 10 seconds after being formed. The temperature of the reaction products is lowered to less than 200°C within 10 seconds after being formed. The process results in less deterioration of the reaction products.
摘要翻译：公开了用于转化固体或高粘度碳基能量载体材料（例如重质原油，油砂，合成聚合物废物和纤维素或水生生物质）的催化方法。转换温度低于450°C。在形成后10秒内将反应产物与催化剂分离。反应产物的温度在形成后10秒钟内降低到低于200℃。该方法导致反应产物的劣化较少。

6. 发明申请

WO1993018341A1 METHOD AND APPARATUS FOR COMBUSTING A CARBONACEOUS MATERIAL 审中-公开
标题翻译：用于燃烧碳质材料的方法和装置
公开(公告)号：WO1993018341A1
公开(公告)日：1993-09-16
申请号：PCT/NL1992000043
申请日：1992-03-05
申请人： TECHNISCHE UNIVERSITEIT DELFT , WOJTOWICZ, Marek, Andrzej , MOULIJN, Jacob, Adriaan
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： F23C11/02
CPC分类号： F23C10/10 , F23C6/04 , F23C10/005 , F23C2206/101 , F23G2201/40 , F23G2202/101 , F23G2202/103 , F23G2203/501 , F23G2203/503 , F23J7/00 , F23J2215/101 , Y02E20/344
摘要： A method and an apparatus are described for combusting carbonaceous materials in a two-stage process. In a first reaction chamber (2), operating under fuel-rich conditions in a bubbling fluidisation regime, fuel undergoes primary combustion or gasification. Oxidising gas (5) is fed into the first reaction chamber at a velocity sufficient to maintain fluidisation. Combustion products leave the first chamber and enter a second reaction chamber (3), operating under oxygen-rich conditions as a circulating fluidised-bed combustor. A second stream of oxidising gas (6) is fed to the second chamber, preferably tangentially to generate a turbulent swirl. Particles of a sulphur-capture agent, preferably limestone, are fed to the second chamber, preferably with the second stream of gas. In the second stage, char and combustible gases generated in the first stage are burnt. The fuel-bound sulphur is removed and advantageously converted to calcium sulphate, while the fuel-bound nitrogen is advantageously converted to nitrogen gas.
摘要翻译：描述了用于在两阶段工艺中燃烧碳质材料的方法和装置。在第一反应室（2）中，在气泡流化状态下在富燃料条件下运行，燃料经历一次燃烧或气化。氧化气体（5）以足以维持流化的速度进料到第一反应室中。燃烧产物离开第一室并进入第二反应室（3），在富氧条件下作为循环流化床燃烧器运行。氧化气体（6）的第二流被输送到第二室，优选切向地产生湍流漩涡。硫捕获剂，优选石灰石的颗粒，最好用第二气体流进料至第二室。在第二阶段，第一阶段产生的焦炭和可燃气体燃烧。燃料结合的硫被去除并有利地转化为硫酸钙，而燃料结合的氮有利地转化为氮气。

7. 发明申请

WO2010106053A3 PROCESS FOR CONVERTING POLYSACCHARIDES IN AN INORGANIC MOLTEN SALT HYDRATE 审中-公开
标题翻译：在无机盐酸盐水溶液中转化多糖的方法
公开(公告)号：WO2010106053A3
公开(公告)日：2011-01-13
申请号：PCT/EP2010053359
申请日：2010-03-16
申请人： BIOECON INT HOLDING NV , MAKKEE MICHIEL , MOULIJN JACOB ADRIAAN , MENEGASSI DE ALMEIDA RAFAEL , O'CONNOR PAUL
发明人： MAKKEE MICHIEL , MOULIJN JACOB ADRIAAN , MENEGASSI DE ALMEIDA RAFAEL , O'CONNOR PAUL
IPC分类号： C07D493/04 , C07D307/20 , C08K5/1535
CPC分类号： C07D493/04 , C07D307/20
摘要： A process is disclosed for converting a polysaccharide-containing biomass material to platform chemicals. The process comprises dissolving the polysaccharides in an inorganic molten salt hydrate, converting the polysaccharides to monosaccharides, and converting the monosaccharides to dehvatized (di) anhydro sugars that are easily separable from the inorganic molten salt hydrate. The dehvatized (di) anhydro sugars are useful as fuel additives and fuel substitutes.
摘要翻译：公开了将含多糖的生物质材料转化为平台化学品的方法。该方法包括将多糖溶解在无机熔融盐水合物中，将多糖转化为单糖，并将单糖转化为易于与无机熔融盐水合物分离的脱氢化（二）脱氢糖。脱氢（di）脱氢糖可用作燃料添加剂和燃料替代品。

8. 发明申请

WO2010106052A1 PROCESS FOR CONVERTING POLYSACCHARIDES IN AN INORGANIC MOLTEN SALT HYDRATE 审中-公开
标题翻译：在无机盐水中转化多糖的方法
公开(公告)号：WO2010106052A1
公开(公告)日：2010-09-23
申请号：PCT/EP2010/053358
申请日：2010-03-16
申请人： BIOeCON INTERNATIONAL HOLDING N.V. , MOULIJN, Jacob Adriaan , O'CONNOR, Paul
发明人： MOULIJN, Jacob Adriaan , O'CONNOR, Paul
IPC分类号： C13K1/02
CPC分类号： C13K1/02
摘要： A process is disclosed for converting sugar-containing biomass material to platform chemicals. The biomass material preferably is sugar cane or sugar beet material. The process comprises dissolving the polysaccharides in a inorganic molten salt hydrate, converting the polysaccharides to monosaccharides, and converting the monosaccharides to platform chemicals that are easily separable from the inorganic molten salt hydrate.
摘要翻译：公开了将含糖生物质材料转化为平台化学品的方法。生物质材料优选为甘蔗或甜菜料。该方法包括将多糖溶解在无机熔融盐水合物中，将多糖转化为单糖，并将单糖转化为易于与无机熔融盐水合物分离的平台化学品。

9. 发明申请

WO2003062196A3 GAS-PHASE PROCESS AND CATALYST FOR THE PREPARATION OF PROPYLENE OXIDE 审中-公开
公开(公告)号：WO2003062196A3
公开(公告)日：2003-07-31
申请号：PCT/US2003/001873
申请日：2003-01-22
申请人： HUNTSMAN INTERNATIONAL LLC , MAKKEE, Michiel , ZWIJNENBURG, Aalbert , MOULIJN, Jacob, Adriaan
发明人： MAKKEE, Michiel , ZWIJNENBURG, Aalbert , MOULIJN, Jacob, Adriaan
IPC分类号： C07D301/10
摘要： Gas-phase process for the preparation of propylene oxide comprising contacting propylene with oxygen and hydrogen in the presence of a catalyst comprising a bimetallic compound supported on a titanium containing support, the bimetallic compound comprising gold and a metal M selected from the group consisting of platinum, tin, and rhodium. The invention also provides for the catalyst.

10. 发明申请

WO03062196A2 GAS-PHASE PROCESS AND CATALYST FOR THE PREPARATION OF PROPYLENE OXIDE 审中-公开
标题翻译：用于制备丙烯氧化物的气相工艺和催化剂
公开(公告)号：WO03062196A2
公开(公告)日：2003-07-31
申请号：PCT/US0301873
申请日：2003-01-22
申请人： HUNTSMAN INT LLC , MAKKEE MICHIEL , ZWIJNENBURG AALBERT , MOULIJN JACOB ADRIAAN
发明人： MAKKEE MICHIEL , ZWIJNENBURG AALBERT , MOULIJN JACOB ADRIAAN
IPC分类号： B01J21/06 , B01J23/42 , B01J23/52 , B01J23/68 , B01J37/03 , C07D301/10 , C07D
CPC分类号： C07D301/10 , B01J21/063 , B01J23/42 , B01J23/52 , B01J23/68 , B01J37/031 , Y02P20/52
摘要： Gas−phase process for the preparation of propylene oxide comprising contacting propylene with oxygen and hydrogen in the presence of a catalyst comprising a bimetallic compound supported on a titanium containing support, the bimetallic compound comprising gold and a metal M selected from the group consisting of platinum, tin, and rhodium. The invention also provides for the catalyst.
摘要翻译：用于制备环氧丙烷的气相方法包括在包含负载在含钛载体上的双金属化合物的催化剂存在下使丙烯与氧和氢接触，所述双金属化合物包含金和选自铂的金属M ，锡和铑。本发明还提供了催化剂。

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