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    • 1. 发明申请
    • METHOD AND APPARATUS FOR SURFACE TREATMENT OF MATERIALS UTILIZING MULTIPLE COMBINED ENERGY SOURCES
    • 利用多种组合能源进行材料表面处理的方法和设备
    • WO2013001306A2
    • 2013-01-03
    • PCT/GB2012/051516
    • 2012-06-28
    • MISTRY, Pravin
    • MISTRY, Pravin
    • D06M10/025D06M10/005
    • Material treatment is effected in a treatment region (124) by at least two energy sources, such as (i) an atmospheric pressure (AP) plasma and (ii) an ultraviolet (UV) laser directed into the plasma and optionally onto the material being treated. Precursor materials (323) may be dispensed before, and finishing material (327) may be dispensed after treatment. Electrodes (e1, e2) for generating the plasma may comprise two spaced-apart rollers (212/214; 412/414; 436/438). Nip rollers (416/418; 436/438) adjacent the electrode rollers (412/414) define a semi-airtight cavity (440), and may have a metallic outer layer (437/439).
    • 通过至少两种能量源(例如(i)大气压力(AP)等离子体和(ii)紫外线(UV)激光器)在处理区域(124)中进行材料处理, 等离子体以及任选地在待处理的材料上。 前体材料(323)可以在之前分配,并且修饰材料(327)可以在处理之后分配。 用于产生等离子体的电极(e1,e2)可以包括两个间隔开的辊(212/214; 412/414; 436/438)。 与电极辊(412/414)相邻的夹辊(416/418; 436/438)限定了半气密空腔(440),并且可以具有金属外层(437/439)。
    • 2. 发明申请
    • SURFACE TREATMENT TECHNIQUES
    • 表面处理技术
    • WO1995031584A1
    • 1995-11-23
    • PCT/US1995005941
    • 1995-05-11
    • QQC, INC.MISTRY, PravinTURCHAN, Manuel, C.
    • QQC, INC.
    • C23C16/48
    • C23C16/27C23C14/22C23C14/28C23C16/26C30B25/105C30B29/04
    • Energy, such as from a UV excimer laser (712), an infrared Nd:YAG laser (714) and an infrared CO2 laser (716) is directed through a nozzle (722) at the surface of a substrate (702) to mobilize and vaporize a carbon constituent (e.g., carbide) within the substrate (e.g., steel). An additional secondary source (e.g., a carbon-containing gas, such as CO2) (720) and an inert shielding gas (e.g., N2) are also delivered through the nozzle. The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material.
    • 例如来自UV准分子激光器(712),红外Nd:YAG激光器(714)和红外CO 2激光器(716)的能量被引导通过在基底(702)的表面处的喷嘴(722) 在基体(例如钢)内蒸发碳成分(如碳化物)。 附加的二次源(例如含碳气体,例如CO 2)(720)和惰性保护气体(例如N 2)也通过喷嘴输送。 蒸发的构成元素通过能量反应以改变其物理结构(例如,从碳到金刚石)到​​作为复合材料漫反射到基底中的复合材料的物理结构。
    • 6. 发明申请
    • METHOD AND APPARATUS FOR SURFACE TREATMENT OF MATERIALS UTILIZING MULTIPLE COMBINED ENERGY SOURCES
    • 用于表面处理利用多种组合能源的材料的方法和装置
    • WO2013001306A3
    • 2013-06-20
    • PCT/GB2012051516
    • 2012-06-28
    • MISTRY PRAVIN
    • MISTRY PRAVIN
    • D06M10/02D06M10/00
    • D06M10/025D06M10/005
    • Material treatment is effected in a treatment region (124) by at least two energy sources, such as (i) an atmospheric pressure (AP) plasma and (ii) an ultraviolet (UV) laser directed into the plasma and optionally onto the material being treated. Precursor materials (323) may be dispensed before, and finishing material (327) may be dispensed after treatment. Electrodes (e1, e2) for generating the plasma may comprise two spaced-apart rollers (212/214; 412/414; 436/438). Nip rollers (416/418; 436/438) adjacent the electrode rollers (412/414) define a semi-airtight cavity (440), and may have a metallic outer layer (437/439).
    • 通过至少两种能量源(例如,(i)大气压(AP)等离子体和(ii)引导到等离子体中的紫外线(UV)激光)和任选地到材料上的材料处理在处理区域(124)中进行材料处理 对待。 前体材料(323)可以在之前分配,并且整理材料(327)可以在处理后分配。 用于产生等离子体的电极(e1,e2)可以包括两个间隔开的辊(212/214; 412/414; 436/438)。 邻近电极辊(412/414)的压辊(416/418; 436/438)限定半气密腔(440),并且可以具有金属外层(437/439)。
    • 7. 发明申请
    • USING LASERS TO FABRICATE COATINGS ON SUBSTRATES
    • 使用激光在衬底上织造涂层
    • WO1995020253A2
    • 1995-07-27
    • PCT/US1995000782
    • 1995-01-17
    • QQC, INC.MISTRY, PravinTURCHAN, Manuel
    • QQC, INC.
    • H01S00/00
    • B05D3/06B23K26/0604B23K26/0622C23C14/0605C23C14/22C23C14/28C23C16/26C23C16/27C23C16/4418C30B23/02C30B25/105C30B25/18C30B29/04
    • Laser energy is directed at a substrate to mobilize, vaporize and react a constituent (primary) element (e.g., carbon) contained within the substrate, so as to modify the composition (e.g., crystalline structure) of the constituent element, and to diffuse the modified constituent back into the substrate, as an adjunct to fabricating a coating (e.g., diamond or diamond-like carbon) on the surface of the substrate. This creates a conversion zone immediately beneath the substrate, which transitions metallurgically from the composition of the underlying substrate to a composition of the coating being fabricated on the surface of the substrate, which results in diffusion bonding of the coating to the substrate. Additional (secondary) similar (e.g., carbon) or dissimilar elements may be introduced in a reaction zone on and above the surface of the substrate to augment the fabrication of and to determine the composition of the coating. The laser energy is provided by a combination of an excimer laser, and Nd: YAG laser and a CO2 laser, the output beams of which are preferably directed through a nozzle delivering the secondary element to the reaction zone. The reaction zone is shielded by an inert (non-reactive) shielding gas (e.g., N2) delivered through the nozzle. A flat plasma is created by the lasers, constituent element and secondary element on the surface of the substrate and the flat plasma optionally extends around the edges of the substrate to fabricate a coating thereon. Pre-treatment and coating fabrication can be performed in conjunction with one another (in-situ). Alternatively, a substrate can be pre-treated to characterize its surface for subsequent coating. In either case, certain advantageous metallurgical changes are induced in the substrate due to the pre-treatment. The processes (pre-treatment and coating fabrication) are suitably performed in ambient, without preheating the substrate and without a vacuum. Substrates of numerous geometries, sizes and shapes, such as flat cutting tool inserts as well as round cutting tools, are readily coated in this manner. The lasers are directed at any suitable angle (including coaxial) relative to the substrate and/or the plasma.
    • 激光能量被引导到衬底上以动员,蒸发并反应包含在衬底内的成分(主要)元素(例如,碳),以便改变构成元素的组成(例如晶体结构),并且扩散 改进的组分返​​回到基底中,作为在基底表面上制造涂层(例如,金刚石或类金刚石碳)的辅助物。 这在基底的正下方产生转化区,该转化区从冶金学上从下面的基底的组成转变成在基底的表面上制造的涂层组合物,这导致涂层扩散到基底上。 可以在衬底表面上和上方的反应区中引入另外的(次级)类似(例如碳)或不同元素,以增加涂层的组成并确定涂层的组成。 激光能量由准分子激光器和Nd:YAG激光器和CO2激光器的组合提供,其输出光束优选地通过将次要元件传送到反应区域的喷嘴引导。 反应区被通过喷嘴输送的惰性(非反应性)保护气体(例如N 2)屏蔽。 由衬底表面上的激光器,构成元件和次要元件产生平坦的等离子体,并且平坦的等离子体可选择地围绕衬底的边缘延伸以在其上制造涂层。 预处理和涂层制造可以彼此结合(原位)进行。 或者,可以对基底进行预处理以表征其表面以用于随后的涂覆。 在任一情况下,由于预处理,在衬底中诱发某些有利的冶金变化。 工艺(预处理和涂覆制造)在环​​境温度下适当地进行,而不预热基板并且没有真空。 具有许多几何形状,尺寸和形状的基底,例如平切刀具刀片以及圆形刀具,以这种方式容易地涂覆。 激光器相对于衬底和/或等离子体指向任何合适的角度(包括同轴)。
    • 8. 发明申请
    • NANOSCALE PARTICLES, AND USES FOR SAME
    • 纳米颗粒,并为其使用
    • WO9606700A2
    • 1996-03-07
    • PCT/US9510815
    • 1995-08-25
    • QQC INCLIU SHENGZHONGMISTRY PRAVINTURCHAN MANUEL C
    • LIU SHENGZHONGMISTRY PRAVINTURCHAN MANUEL C
    • F16H41/28B01J2/00B01J19/12B01J37/34B05D7/24B22F9/14B22F9/30B23K23/00B23K26/00B23K26/14B23K35/02B23K35/24B23K35/34B23K35/40C01B13/18C01B21/064C01B21/076C01B31/30C01B33/18C01F5/02C01F5/06C01F7/30C01F7/44C01F11/02C01F17/00C01G23/04C01G49/00C04B2/10B23K9/00
    • C04B2/10B01J2/00B01J37/349B22F9/30B23K1/0056B23K23/00B23K26/21B23K35/0222B23K35/0238B23K35/0244B23K35/025B23K35/0255B23K35/28B23K35/284B23K35/286B23K35/288B23K35/34B23K2201/001B23K2203/04B82Y30/00C01B13/18C01F5/06C01F7/30C01F7/44C01P2004/64F16H41/28Y10S977/777Y10T29/49321
    • Nanoscale particles and powders are made from a starting material, including larger-size starting particles and solid targets. Various techniques are disclosed all of which generally involve heating and decomposing the starting material with an energy source selected from the group consisting of laser, electric arc, flame and plasma. The various techniques disclosed herein all exhibit a high throughput and a nearly instantaneous rate of production of nanoscale powders for a variety of applications. In certain of the embodiments, cooling is required to prevent agglomeration of the nanoscale particles into larger (non-nanoscale) particles. The nanoscale particles are useful for painting, coating, joining, bonding, brazing, soldering, welding, etc. For example, thermal stresses normally associated with joining (e.g., brazing) may be alleviated by a low-temperature joining technique of the present invention. A low-temperature joining material is applied (as a paste, or as a powder spray, or as a tape, or as a paint, or as a putty) at the junction of two components desired to be joined together. Energy from a source such as a laser beam (for example an Nd:YAG or a CO2 laser) or by a flame, arc, plasma, or the like, is either "walked" along the joining material to react the entire amount joining material, or the joining material is self-sustaining and simply requires igniting a selected portion of the joining material by the energy source. In an exemplary application of the process, vanes are brazed to the bowl and/or to the shroud of an automatic transmission bowl (impeller or turbine) assembly, preferably using the low-temperature joining material. Systems for delivering the joining material and the energy are described. The fabrication of hollow vanes is described. The fabrication of shroudless bowl components, and stator components subsuming the function of the shroud are described.
    • 纳米颗粒和粉末由起始材料制成,包括较大尺寸的起始颗粒和固体靶。 公开了各种技术,其中所有技术通常涉及用选自激光,电弧,火焰和等离子体的能量源来加热和分解起始材料。 本文公开的各种技术都表现出高通量和几乎瞬时的用于各种应用的纳米级粉末的生产速率。 在某些实施方案中,需要冷却以防止纳米级颗粒聚集成更大的(非纳米级)颗粒。 纳米级颗粒可用于涂覆,涂覆,接合,粘合,钎焊,焊接,焊接等。例如,通过本发明的低温接合技术可以减轻通常与接合(例如钎焊)相关的热应力 。 在期望连接在一起的两种组分的接合处施加低温接合材料(作为糊剂,或作为粉末喷涂,或作为胶带,或作为油漆,或作为油灰)。 源自诸如激光束(例如Nd:YAG或CO 2激光)或火焰,电弧,等离子体等的源的能量沿着接合材料“走动”以使整个量的接合材料 或者接合材料是自维持的,并且仅需要通过能量源点燃连接材料的选定部分。 在该方法的示例性应用中,叶片被钎焊到自动传动碗(叶轮或涡轮机)组件的碗和/或护罩上,优选地使用低温接合材料。 描述了用于传送接合材料和能量的系统。 描述了中空叶片的制造。 描述了制造无罩碗部件和包含护罩功能的定子部件。