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1. 发明申请

WO2012091588A2 NEW (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES AND A NEW CATALYTIC METHOD FOR OBTAINING NEW AND CONVENTIONAL SUBSTITUTED (TRIORGANOSILYL)ALKYNES AND THEIR DERIVATIVES 审中-公开
标题翻译：新的（三氯硅烷基）烷基化合物及其衍生物和新的催化方法，用于获得新的和常规的取代（三氯硅烷基）烷基化合物及其衍生物
公开(公告)号：WO2012091588A2
公开(公告)日：2012-07-05
申请号：PCT/PL2011/050056
申请日：2011-12-29
申请人： ADAM MICKIEWICZ UNIVERSITY , KOWNACKI, Ireneusz , MARCINIEC, Bogdan , DUDZIEC, Beata , KOWNACKA, Agnieszka , MAJCHRZAK, Mariusz , SZULC, Mateusz , ORWAT, Bartosz
发明人： DUDZIEC, Beata , KOWNACKA, Agnieszka , MAJCHRZAK, Mariusz , SZULC, Mateusz , ORWAT, Bartosz
IPC分类号： C07F7/08 , C07F7/18 , C07F17/02
CPC分类号： C07F7/0827 , C07F7/0809 , C07F7/0818 , C07F7/0856 , C07F7/0869 , C07F7/0887 , C07F7/0896 , C07F7/10 , C07F7/1852 , C07F7/1856 , C07F7/1864 , C07F7/1876 , C07F7/188 , C07F7/1892 , C07F13/00 , C07F17/02
摘要： The present invention relates to new (triorganosilyl)alkynes and their derivatives having general formula 1 R 1 -C≡C-Z (I) In its second aspect, this invention relates to a new selective method for the preparation of new and conventional (triorganosilyl)alkynes and their derivatives having the general formula 1, by the silylative coupling of terminal alkynes with halogenotriorganosilanes in the presence of an iridium catalyst and a tertiary amine.
摘要翻译：本发明涉及具有通式1的新的（三有机甲硅烷基）炔及其衍生物R1-C = CZ（I）其第二方面涉及一种制备新的和常规的（三有机甲硅烷基）炔的新的选择性方法，其衍生物具有通式1，通过在铱催化剂和叔胺的存在下，末端炔烃与卤代有机硅烷的甲硅烷基偶联。

2. 发明申请

WO2011028143A1 SYNTHESIS OF FLUOROSILICONES AND THEIR DERIVATIVES 审中-公开
标题翻译：氟化物及其衍生物的合成
公开(公告)号：WO2011028143A1
公开(公告)日：2011-03-10
申请号：PCT/PL2010/000074
申请日：2010-08-16
申请人： ADAM MICKIEWICZ UNIVERSITY , MARCINIEC, Bogdan , MACIEJEWSKI, Hieronim , KARASIEWICZ, Joanna , DĄBEK, Izabela
发明人： MARCINIEC, Bogdan , MACIEJEWSKI, Hieronim , KARASIEWICZ, Joanna , DĄBEK, Izabela
IPC分类号： C08G77/385 , C08G77/04 , B01J23/46
CPC分类号： C08G77/385 , C07F7/0879 , C08G77/045 , C08G77/12 , C08G77/14 , Y02P20/582
摘要： The subject of invention is the method of synthesis of fluorosilicone co-polymers of arbitrary topology and general formula 1 in which among others if A stands for CH-O(CH 2 ) m (CF 2 ) n CF 2 H group, then the method is based on hydrosilylation reaction of appropriate fluoroalkyl-allyl ether with polyhydrosiloxanes containing at least one Si-H group, catalyzed by siloxide rhodium complex. If A stands for in which Z stands for divalent group either then the method is based on the reaction of nucleophilic opening of oxirane ring in appropriate epoxyfunctional co-polysiloxanes, in acidic environment.
摘要翻译：本发明的主题是任意拓扑结构和通式1的氟硅氧烷共聚物的合成方法，其中如果A代表CH-O（CH 2）m（CF 2）n CF 2 H基团，则该方法基于氢化硅烷化反应的合适的氟烷基 - 烯丙基醚与含有至少一个Si-H基团的聚氢硅氧烷，由硅化铑络合物催化。如果A代表其中Z代表二价基团，则该方法基于在酸性环境中环氧乙烷环在合适的环氧官能共聚硅氧烷中的亲核性开环的反应。

3. 发明申请

WO2008020774A1 NEW SILYLSUBSTITUTED 1,2-ALKYNES AND SYNTHESIS OF SILYLSUBSTITUTED 1,2-AIKYNES 审中-公开
标题翻译：新的硅烷化1,2-亚烷基和硅氧烷化1,2-亚烷基的合成
公开(公告)号：WO2008020774A1
公开(公告)日：2008-02-21
申请号：PCT/PL2007/000057
申请日：2007-08-14
申请人： ADAM MICKIEWICZ UNIVERSITY , MARCINIEC, Bogdan , DUDZIEC, Beata , SZUBERT, Karol , WALKOWIAK, Jedrzej
发明人： MARCINIEC, Bogdan , DUDZIEC, Beata , SZUBERT, Karol , WALKOWIAK, Jedrzej
IPC分类号： C07F7/08 , C07F7/18
CPC分类号： C07F7/0809 , C07F7/0818 , C07F7/0849
摘要： The subject of the invention are new silylsubstituted 1,2-alkynes of the general formula 1 and a new way of synthesis of new and already known silylsubstituted 1,2-alkynes of the general formula 1. The unknown silylsubstituted 1,2-alkynes of general formula 1, in which R 1 stands for trialkoxysilyl group, dimethyl(trimethylsiloxy)silyl group, phenyldimethylsilyl group, methylbis(trimethylsiloxy)silyl group; R 2 stands for alkyl, trialkylsilyl group with all alkyl substituents the same, 1-trimethylsiloxycycloalkyl group, cycloalkyl group, tertbutyl group, 1-trimethylsiloxyalkyl group, tertbutyldimethylsilyl group or 1-alkoxyalkyl group. The subject matter of the invention is a new way of synthesis of new and already known silylsubstituted 1,2-alkynes of general formula 1, in which R 1 and R 2 specified above, in which an alkene of general formula 2, with R 1 specified above is subjected to silylative coupling with a terminal alkynes of the general formula 3, with R 2 specified above, in the presence of a catalyst.
摘要翻译：本发明的主题是通式1的新的甲硅烷基取代的1,2-炔烃，以及新的和已知的通式1的已知甲硅烷基取代的1,2-炔烃的新方法。未知的甲硅烷基取代的1,2-炔烃通式1，其中R 1代表三烷氧基甲硅烷基，二甲基（三甲基甲硅烷氧基）甲硅烷基，苯基二甲基甲硅烷基，甲基双（三甲基甲硅烷氧基）甲硅烷基; R 2表示全部烷基取代基相同的烷基，三烷基甲硅烷基，1-三甲基甲硅烷氧基环烷基，环烷基，叔丁基，1-三甲基硅氧烷基，叔丁基二甲基甲硅烷基或1-烷氧基烷基。本发明的主题是合成新的已知的通式1的甲硅烷基取代的1,2-炔烃的新方法，其中R 1和R 2指定其中将具有上述R 1的通式2的烯烃与上述R 2的末端炔进行甲硅烷基偶联，，在催化剂的存在下。

4. 发明申请

WO2012091586A1 FLUOROCARBOFUNCTIONAL SILSESQUIOXANES CONTAINING OTHER REACTIVE FUNCTIONAL GROUPS AND A METHOD TO OBTAIN THE SAME 审中-公开
标题翻译：含有其他反应性功能组的氟官能硅烷氧化物及其获得方法
公开(公告)号：WO2012091586A1
公开(公告)日：2012-07-05
申请号：PCT/PL2011/050053
申请日：2011-12-27
申请人： ADAM MICKIEWICZ UNIVERSITY , MACIEJEWSKI, Hieronim , MARCINIEC, Bogdan , DUTKIEWICZ, Michał , KARASIEWICZ, Joanna
发明人： MACIEJEWSKI, Hieronim , MARCINIEC, Bogdan , DUTKIEWICZ, Michał , KARASIEWICZ, Joanna
IPC分类号： C07F7/21
CPC分类号： C07F7/21
摘要： This invention relates to new silsesquioxane derivatives, containing two functional group types having the general formula 1, [R 1 (SiR 3 2 O) m ] n [R 2 (SiR 3 2 O) m ] 8-n [(SiO 1.5 ) 8 ] wherein • R 1 denotes the group HCF 2 (CF 2 ) x (CH 2 ) y O(CH 2 ) 3 - or CF 3 (CF 2 ) Z CH 2 CH 2 -; • R 2 denotes the glycidoxypropyl, triethoxysilylethyl functional group: • R 3 are equal and denote a methyl or phenyl group; • m - are equal and take the value 0 or 1, n=1-7, x=1-12, y=1-4, z=0-12. In its second aspect, this invention relates to a method to obtain new and conventional silsesquioxane derivatives having the general formula 1, by two-step hydrosilylation. A fluorinated olefin is hydrosilylated with hydridosilsesquioxane in the first step, followed by the second step where a functional olefin is hydrosilylated with a partly substituted hydridosilsesquioxane resulting from the first step, in the presence of conventional catalysts for hydrosilylation processes, specifically transition metal complexes.
摘要翻译：本发明涉及含有两个具有通式1的官能团类型的新的倍半硅氧烷衍生物[R1（SiR32O）m] n [R2（SiR32O）m] 8-n [（SiO1.5）8]其中R1 表示基团HCF2（CF2）x（CH2）yO（CH2）3-或CF3（CF2）ZCH2CH2-; °R2表示缩水甘油氧基丙基，三乙氧基甲硅烷基乙基官能团：°R 3相同，表示甲基或苯基; 取值为0或1，n = 1-7，x = 1-12，y = 1-4，z = 0-12。在其第二方面，本发明涉及通过两步氢化硅烷化获得具有通式1的新的和常规的倍半硅氧烷衍生物的方法。在第一步中氟化烯烃与氢化倍半硅氧烷氢化，随后是第二步，其中在常规的氢化硅烷化方法的催化剂，特别是过渡金属配合物的存在下，功能性烯烃与第一步产生的部分取代的氢化倍半硅氧烷氢化硅烷化。

5. 发明申请

WO2011031172A1 NEW VINYL-ALKYNYLSUBSTITUTED GERMANIUM COMPOUNDS AND METHOD TO OBTAIN VINYL- ALKYNYLSUBSTITUTED GERMANIUM COMPOUNDS 审中-公开
标题翻译：新的乙烯基烷基化锗化合物和获得乙烯基烷基化锗化合物的方法
公开(公告)号：WO2011031172A1
公开(公告)日：2011-03-17
申请号：PCT/PL2010/000077
申请日：2010-08-20
申请人： ADAM MICKIEWICZ UNIVERSITY , MARCINIEC, Bogdan , DUZIEC, Beata
发明人： MARCINIEC, Bogdan , DUZIEC, Beata
IPC分类号： C07F7/30
CPC分类号： C07F7/30
摘要： New vinyl-alkynylsubstituted germanium compounds having the general formula 1 are the subject of the invention. The invention also relates to a new method of obtaining vinyl- alkynylsubstituted germanium compounds having the general formula 1. - A denotes: diethylgermyl - R denotes: triethylsilyl, l-(trimethylsiloxy)-l-cyclohexyl The invention also provides a solution to the problem of the method of obtaining vinyl- alkynylsubstituted germanium compounds having the general formula 1, involving the germylative coupling reaction between a suitable substituted terminal alkyne and a suitable divinylsubstituted germanium compound in the presence of a ruthenium(II) complex as catalyst.
摘要翻译：具有通式1的新的乙烯基 - 炔基取代的锗化合物是本发明的主题。本发明还涉及一种获得具有通式1的乙烯基 - 炔基取代的锗化合物的新方法.A表示：二乙基锗烷基-R表示：三乙基甲硅烷基，1-（三甲基甲硅烷氧基）-1-环己基本发明还提供了该问题的解决方案获得具有通式1的乙烯基 - 炔基取代的锗化合物的方法，其涉及在钌（II）络合物作为催化剂存在下，合适的取代的末端炔与合适的二乙烯基取代的锗化合物之间的生成偶联反应。

6. 发明申请

WO2010009752A1 CURABLE SILICONE COMPOSITIONS COMPRISING CYCLO-ALKYLPHOSPHITES 审中-公开
标题翻译：包含环烷基磷灰石的可固化硅氧烷组合物
公开(公告)号：WO2010009752A1
公开(公告)日：2010-01-28
申请号：PCT/EP2008/059513
申请日：2008-07-21
申请人： MOMENTIVE PERFORMANCE MATERIALS GMBH , STEINBERGER, Helmut , MARCINIEC, Bogdan , KOWNACKI, Ireneusz
发明人： STEINBERGER, Helmut , MARCINIEC, Bogdan , KOWNACKI, Ireneusz
IPC分类号： C08L83/04 , C08K5/524
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20 , C08K5/524 , C08L83/00
摘要： The present invention relates to hydrosilylation-curing polyorganosiloxane compositions and/or silane compositions comprising phosphites, transition metal compounds comprising phosphite ligands, cured products prepared from the hydrosilylation-curing polyorganosiloxane compositions and/or silane compositions and new phosphites.
摘要翻译：本发明涉及包含亚磷酸酯，包含亚磷酸酯配体的过渡金属化合物，由氢化硅烷化固化聚有机硅氧烷组合物和/或硅烷组合物和新的亚磷酸酯制备的固化产物的含硅烷化固化的聚有机硅氧烷组合物和/或硅烷组合物。

7. 发明申请

WO2013000788A1 HYDROSILYLATION REACTION CURABLE COMPOSITIONS AND METHODS FOR THEIR PREPARATION AND USE 审中-公开
标题翻译：氢化反应可固化组合物及其制备和使用方法
公开(公告)号：WO2013000788A1
公开(公告)日：2013-01-03
申请号：PCT/EP2012/061826
申请日：2012-06-20
申请人： DOW CORNING CORPORATION , CRAY, Stephen , MARCINIEC, Bogdan , NGUYEN, Binh , SURGENOR, Avril , TAYLOR, Richard , TZOU, Ming-shin , VANDORT, Paul , POSALA, Krystian , KOWNACKI, Ireneusz
发明人： CRAY, Stephen , MARCINIEC, Bogdan , NGUYEN, Binh , SURGENOR, Avril , TAYLOR, Richard , TZOU, Ming-shin , VANDORT, Paul , POSALA, Krystian , KOWNACKI, Ireneusz
IPC分类号： C07F17/02
CPC分类号： C07F7/1876 , C07F7/0838
摘要： A composition contains (A) a hydrosilylation reaction catalyst and (B) an aliphatically unsaturated compound having an average, per molecule, of one or more aliphatically unsaturated organic groups capable of undergoing hydrosilylation reaction. The composition is capable of reacting via hydrosilylation reaction to form a reaction product, such as a silane, a gum, a gel, a rubber, or a resin. Ingredient (A) contains a platinum-ligand complex that can be prepared by reacting a platinum precursor and a ligand.
摘要翻译：组合物含有（A）氢化硅烷化反应催化剂和（B）具有每分子平均能够进行氢化硅烷化反应的一种或多种脂族不饱和有机基团的脂族不饱和化合物。组合物能够通过氢化硅烷化反应反应形成反应产物，例如硅烷，胶，凝胶，橡胶或树脂。成分（A）含有可以通过使铂前体和配体反应制备的铂 - 配体配合物。

8. 发明申请

WO2011031171A1 NEW (E)-STYRYL-ALKYNYLSUBSTITUTED SILICON COMPOUNDS AND METHOD OF OBTAINING (E)- STYRYL-ALKYNYLSUBSTITUTED SILICON COMPOUNDS 审中-公开
标题翻译：新的（E） - 氨基 - 亚烷基硅氧烷化合物及其获得方法（E） - 苯乙烯 - 烷基硅氧烷化合物
公开(公告)号：WO2011031171A1
公开(公告)日：2011-03-17
申请号：PCT/PL2010/000076
申请日：2010-08-20
申请人： ADAM MICKIEWICZ UNIVERSITY , MARCINIEC, Bogdan , DUZIEC, Beata , RZONSOWSKA, Monika
发明人： MARCINIEC, Bogdan , DUZIEC, Beata , RZONSOWSKA, Monika
IPC分类号： C07F7/08 , C07F7/10 , C07F7/18 , C07F7/30
CPC分类号： C07F7/10 , C07F7/0849 , C07F7/1856 , C07F7/30
摘要： New ( E )-styryl-alkynylsubstituted silicon compounds having the generalized formula (1) are the subject of the invention. The invention also relates to a new method of obtaining ( E )- styryl-alkynylsubstituted silicon compounds having the generalized formula (1). A denotes: phenylmethylsilyl, 1,4-bis(dimethylsilyl)benzene, 1,2-bis(dimethylsilyl)ethane, 1, 1,3,3-tetramethyldisilazane, 1,1,3,3-tetramethyldisiloxane, R' denotes: tri(isopropyl)silyl, 1-pentyl, 2-(trimethylsiloxy)-2-butyl, 1-(trimethylsiloxy)-1- cyclohexyl, triethylgermyl, - R" denotes: H or Cl and when A denotes phenylmethylsilyl then R" denotes also methyl or a methoxy group. In its second aspect, the inventon relates to a method of obtaining (E)-styryl- alkynylsubstituted silicon compounds having the generalized formula (1) where A, R' and R" denote the same as stated above by way of a silylative coupling reaction between a suitable substituted styrene and a suitable vinyl-alkynylsubstituted silicon compound in the presence of a ruthenium (II) complex as catalyst.
摘要翻译：具有通式（1）的新的（E） - 苯乙烯基 - 炔基取代的硅化合物是本发明的主题。本发明还涉及一种获得具有通式（1）的（E） - 苯乙烯基 - 炔基取代的硅化合物的新方法。 A表示：苯甲基甲硅烷基，1,4-双（二甲基甲硅烷基）苯，1,2-双（二甲基甲硅烷基）乙烷，1,1,3,3-四甲基二硅氮烷，1,1,3,3-四甲基二硅氧烷，R'表示：三（异丙基）甲硅烷基，1-戊基，2-（三甲基甲硅烷氧基）-2-丁基，1-（三甲基甲硅烷氧基）-1-环己基，三乙基锗烷基，-R“表示H或Cl，当A表示苯基甲基甲硅烷基时，R” 或甲氧基。在其第二方面，本发明涉及一种获得具有通式（1）的（E） - 苯乙烯基 - 炔基取代的硅化合物的方法，其中A，R'和R“表示与上述相同，通过甲硅烷基偶联反应在合适的取代苯乙烯和合适的乙烯基 - 炔基取代的硅化合物之间，在钌（II）络合物作为催化剂存在下。

9. 发明申请

WO2011028142A1 SYNTHESIS OF FLUOROCARBOFUNCTIONAL SILSESQUIOXANES 审中-公开
标题翻译：氟代官能团硅藻糖的合成
公开(公告)号：WO2011028142A1
公开(公告)日：2011-03-10
申请号：PCT/PL2010/000073
申请日：2010-08-16
申请人： ADAM MICKIEWICZ UNIVERSITY , MARCINIEC, Bogdan , MACIEJEWSKI, Hieronim , DUTKIEWICZ, Michał
发明人： MARCINIEC, Bogdan , MACIEJEWSKI, Hieronim , DUTKIEWICZ, Michał
IPC分类号： C08G77/04
CPC分类号： C08G77/045 , C08G77/38 , C08G77/385 , C08G77/46
摘要： The subject of the invention is the method of synthesis of fluorocarbofunctional cage silsesquioxanes of the general formula in which • R 1 stands for HCF 2 (CF 2 ) n (CH 2 )mO(CH 2 ) 3 Si(CH 3 ) 2 O or HCF 2 (CF 2 ) n (CH 2 ) m O(CH 2 ) 3 group in which n=1-12, m=1-4; • R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 can be the same as R 1 or different from it and stand all either for the (C 1 -C 25 ) alkyl group or any aryl group, based on hydrosilylation of fluoroalkyl-allyl ether with an appropriate hydrogensilsesquioxane in the presence of siloxide rhodium complex [{Rh(OSiMe 3 )(cod)} 2 ] as a catalyst.
摘要翻译：本发明的主题是通式的氟代官能笼型倍半硅氧烷的合成方法，其中R1表示HCF2（CF2）n（CH2）mO（CH2）3Si（CH3）2O或HCF2（CF2）n（CH2） mO（CH 2）3基，其中n = 1-12，m = 1-4; °R 2，R 3，R 4，R 5，R 6，R 7，R 8可以与R 1相同或不同，并且基于氟烷基 - 烯丙基醚的氢化硅烷化，全部用于（C 1 -C 25）烷基或任何芳基在合适的氢氟倍半硅氧烷存在下，作为催化剂存在硅氧烷铑络合物[{Rh（OSiMe 3）（cod）} 2]。

10. 发明申请

WO2011028141A1 SYNTHESIS OF FLUOROCARBOFUNCTIONAL ALKOXYSILANES AND CHLOROSILANES 审中-公开
标题翻译：氟代烷氧基硅烷和氯代硅烷的合成
公开(公告)号：WO2011028141A1
公开(公告)日：2011-03-10
申请号：PCT/PL2010/000072
申请日：2010-08-16
申请人： ADAM MICKIEWICZ UNIVERSITY , MARCINIEC, Bogdan , MACIEJEWSKI, Hieronim , DUTKIEWICZ, Michal , DĄBEK, Izabela , KARASIEWICZ, Joanna
发明人： MARCINIEC, Bogdan , MACIEJEWSKI, Hieronim , DUTKIEWICZ, Michal , DĄBEK, Izabela , KARASIEWICZ, Joanna
IPC分类号： C07F7/14 , C07F7/18
CPC分类号： C07F7/1876 , C07F7/14
摘要： The subject of invention is the method of synthesis of fluorocarbofunctional alkoxysilanes and chlorosilanes of the general formula HCF 2 (CF 2 ) n (CH 2 ) m OC 3 H 7 SiR 1 R 2 R 3 in which - n takes values from 1 to 12, m takes values from 1 to 4, - R 1 stands for an alkoxy group or halogen, if R 1 stands for an alkoxy group, then R 2 and R 3 can be the same or different and stand for an alkoxy group containing C= 1-4, alkyl group containing C = 1-12 or an aryl group, if R 1 stands for a halogen, then R 2 and R 3 can be the same or different and stand for based on hydrosilylation of an appropriate fluoroalkyl-allyl ether with an appropriate trisubstituted silane of the general formula HSiR 1 R 2 R 3 in the presence of siloxide rhodium complex [{Rh(OSiMe 3 )(cod)} 2 ] as a catalyst.
摘要翻译：本发明的主题是通式为HCF2（CF2）n（CH2）mOC3H7SiR1R2R3的氟代官能团烷氧基硅烷和氯代硅烷的合成方法，其中-n取值为1至12，m取值为1至4，-R 1表示烷氧基或卤素，如果R1代表烷氧基，则R2和R3可以相同或不同，代表含C = 1-4的烷氧基，含C = 1-12的烷基或芳基，如果R1代表卤素，则R2和R3可以相同或不同，并且基于合适的氟代烷基 - 烯丙基醚与适当的三取代硅烷通式为HSiR1R2R3在硅氧烷铑络合物[{Rh （OSiMe 3）（cod）} 2]作为催化剂。

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