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    • 2. 发明申请
    • IMPACT MODIFIED IGNITION RESISTANT CARBONATE POLYMER COMPOSITION
    • 冲击改性耐燃碳酸酯聚合物组合物
    • WO2011110365A1
    • 2011-09-15
    • PCT/EP2011/001221
    • 2011-03-11
    • STYRON EUROPE GMBHVAN NUFFEL, Claude T. E.LAKEMAN, Pascal E.R.E.J.
    • VAN NUFFEL, Claude T. E.LAKEMAN, Pascal E.R.E.J.
    • C08L69/00C09K21/12
    • C08L69/00C08K5/523C08L27/18C08L51/04C08L51/085C08L55/02C08L69/005C09K21/12C08L2666/02
    • The present invention is an ignition resistant carbonate polymer composition, a method to make said composition and fabricated articles made therefrom. The ignition resistant carbonate polymer composition consists of: (i) an aromatic polycarbonate or an aromatic polyester carbonate, (ii) a graft (co)polymer produced by mass polymerization, (iii) a silicon-containing graft (co)polymer having a core-shell morphology, including a grafted shell that contains polymerized alkyl(meth)acrylate and a composite rubber core that contains polyorganosiloxane and poly(meth)alkyl acrylate components, wherein said core comprises at least 20 percent by weight silicon based on the total weight of (iii), (iv) an oligomeric aromatic phosphate compound represented by the formula I: wherein, R 1 , R 2 , R 3 and R 4 independently of one another each denote optionally halogenated C 1 - to C 8 -alkyl, or C 5 - to C 6 - cycloalkyl, C 6 - to C 20 - aryl or C 7 - to C 12 - aralkyl, in each case optionally substituted by alkyl and/or halogen, X denotes a mono- or polynuclear aromatic radical having 6 to 30 C atoms, n independently of one another is 0 or 1, N represents values greater than 0 and less than 30, (v) a polytetrafluoroethylene polymer, a fluorothermoplast, or mixture thereof, and (vi) one or more of a thermoplastic vinyl (co)polymer, an impact modifier different from (iii), a filler, a reinforcing material, a stabilizer, a pigment, a dye, a mold release, a lubricant, or an anti-static agent.
    • 本发明是一种耐点燃碳酸酯聚合物组合物,由其制成所述组合物和制造制品的方法。 耐点燃碳酸酯聚合物组合物由以下组成:(i)芳族聚碳酸酯或芳族聚酯碳酸酯,(ii)通过大量聚合制备的接枝(共)聚合物,(iii)具有芯的含硅接枝(共)聚合物 壳形态,包括含有聚合的(甲基)丙烯酸烷基酯的接枝壳和包含聚有机硅氧烷和聚(甲基)丙烯酸烷基酯组分的复合橡胶芯,其中所述芯包含至少20重量%的硅,基于 (iii),(iv)由式I表示的低聚芳族磷酸酯化合物:其中,R 1,R 2,R 3和R 4彼此独立地各自表示任选卤代的C 1 -C 8 - 烷基或C 5 -C 6 - 环烷基, C 6 -C 20 - 芳基或C 7 -C 12 - 芳烷基,在每种情况下任选被烷基和/或卤素取代,X表示具有6至30个C原子的单核或多核芳族基团,n彼此独立地为0或 1,N表示较大值 (v)聚四氟乙烯聚合物,含氟热塑性塑料或其混合物,和(vi)一种或多种热塑性乙烯基(共)聚合物,与(iii)不同的抗冲改性剂,填料, 增强材料,稳定剂,颜料,染料,脱模剂,润滑剂或抗静电剂。
    • 3. 发明申请
    • IMPROVED FLOW IGNITION RESISTANT CARBONATE POLYMER COMPOSITION
    • 改进的耐燃碳酸酯聚合物组合物
    • WO2011107273A1
    • 2011-09-09
    • PCT/EP2011/001035
    • 2011-03-02
    • STYRON EUROPE GMBHVAN NUFFEL, Claude T. E.LAKEMAN, Pascal E. R. E J.PARISI, Giacomo
    • VAN NUFFEL, Claude T. E.LAKEMAN, Pascal E. R. E J.PARISI, Giacomo
    • C08L69/00C09K21/12
    • C09K21/12C08K5/521C08L25/12C08L27/12C08L51/04C08L55/02C08L67/02C08L69/00C08L2205/03C08L2666/02
    • The present invention is an ignition resistant carbonate polymer composition, a method to make said composition and fabricated articles made therefrom. The ignition resistant carbonate polymer composition consists of: (i) an aromatic polycarbonate or an aromatic polyester carbonate, (ii) a graft (co)polymer produced by mass polymerization, (iii) a thermoplastic semi-crystalline polyalkylene dicarboxylate polymer having an intrinsic viscosity of from 0.4 to 0.7 dl/g, (iv) an aromatic phosphate compound represented by the formula (I) : wherein, R 1 , R 2 , R 3 and R 4 independently of one another each denote optionally halogenated C 1 - to C 8 -alkyl, or C 5 - to C 6 - cycloalkyl, C 6 - to C 20 - aryl or C 7 - to C 12 - aralkyl, in each case optionally substituted by alkyl and/or halogen, X denotes a mono- or polynuclear aromatic radical having 6 to 30 C atoms, n independently of one another is 0 or 1, N represents values from 0 to 30, (v) a polytetrafluoroethylene polymer, a fluorothermoplast, or mixture thereof, and (vi) one or more of a thermoplastic vinyl (co)ρolymer, an impact modifier, a filler, a reinforcing material, a stabilizer, a pigment, a dye, a mold release, a lubricant, or an anti-static agent.
    • 本发明是耐点燃碳酸酯聚合物组合物,由其制成所述组合物和制造制品的方法。 耐点燃碳酸酯聚合物组合物包括:(i)芳族聚碳酸酯或芳族聚酯碳酸酯,(ii)通过大量聚合制备的接枝(共)聚合物,(iii)热塑性半结晶聚亚烷基二羧酸酯聚合物,其特性粘度 为0.4〜0.7dl / g,(iv)由式(I)表示的芳族磷酸酯化合物:其中,R 1,R 2,R 3和R 4各自独立地表示任选卤代的C 1至C 8烷基或C 5 - 至C6-环烷基,C6至C20-芳基或C7-至C12-芳烷基,在任何情况下均可任选被烷基和/或卤素取代,X表示具有6至30个C原子的单核或多核芳族基团,n独立地 (v)聚四氟乙烯聚合物,含氟热塑性弹性体或其混合物,和(vi)一种或多种热塑性乙烯基(共)聚合物,抗冲击改性剂 ,填料,增强材料,稳定剂,颜料,染料,a 脱模剂,润滑剂或抗静电剂。