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    • 1. 发明申请
    • AUTOMOTIVE FUELS AND FINE CHEMICALS FROM CRUDE TALL OIL
    • 汽油和精细化学品来自原油
    • WO2007050030A1
    • 2007-05-03
    • PCT/SE2006/050414
    • 2006-10-19
    • KIRAM ABSTIGSSON, Lars
    • STIGSSON, Lars
    • C11C3/04C07C68/08C07C69/003C10L1/02C10L1/18C11B13/00
    • C10L1/02C07C67/08C10L1/19C11C3/003Y02P20/127C07C69/24C07C69/52
    • There is disclosed a method for manufacturing fatty acid alkyl esters from tall oil comprising the steps of a) esterifying tall oil in at least one esterification reactor in the presence of an acidic catalyst and an C1 to C8 alcohol to form a crude product stream comprising fatty acid alkyl esters and H2O, b) separating H2O and alcohol from the crude product stream formed in step a) to form a dehydrated fatty acid alkyl ester product stream, and c) separating dehydrated fatty acid alkyl ester product stream from step b) into at least two product streams wherein one product stream is enriched in fatty acid alkyl esters and one product stream is enriched in resin acid compounds. There are disclosed fatty acid alkyl esters and resin acids manufactured by the method. Moreover there is disclosed a fuel composition and its use as an automotive fuel, said fuel composition comprises the fatty acid alkyl esters produced according to the present invention.
    • 公开了一种从妥尔油制备脂肪酸烷基酯的方法,包括以下步骤:a)在酸性催化剂和C1至C8醇的存在下,在至少一个酯化反应器中酯化妥尔油,形成含有脂肪酸的粗产物流 酸性烷基酯和H 2 O,b)从步骤a)中形成的粗产物流中分离出H 2 O和醇,以形成脱水的脂肪酸烷基酯产物流,和c)从步骤b)将脱水的脂肪酸烷基酯产物流分离成 至少两个产物流,其中一个产物流富含脂肪酸烷基酯,一个产物流富含树脂酸化合物。 公开了通过该方法制造的脂肪酸烷基酯和树脂酸。 此外,公开了燃料组合物及其作为汽车燃料的用途,所述燃料组合物包含根据本发明生产的脂肪酸烷基酯。
    • 3. 发明申请
    • PARTIAL OXIDATION OF CELLULOSE SPENT PULPING LIQUOR
    • 纤维素稀释液的部分氧化
    • WO2006019342A1
    • 2006-02-23
    • PCT/SE2004/001398
    • 2004-10-01
    • KIRAM ABSTIGSSON, Lars
    • STIGSSON, Lars
    • D21C11/12
    • D21C11/12D21C3/02D21C11/04Y02P40/44
    • The present invention relate to a two-stage gasification process using a gas generator for the recovery of strongly alkaline chemicals and energy value from a cellulose spent liquor. The temperature in the first reaction zone of the gas generator is maintained between 1000 C. and 1400 C. by the controlled addition of an oxygen containing gas. A strongly alkaline smelt comprising alkali oxide, alkali hydroxide, alkali carbonate and alkali borate's corresponding to at least 75 % by weight of the smelt is recovered from below the first reaction zone of the gas generator. A gaseous components stream formed by exothermal reactions in the first reaction zone are directed to a second reaction or gas transfer zone of substantially of updraft or up-flow design, wherein the gaseous stream is cooled to a temperature below about 1000 C, said cooling preferably achieved by endothermal decomposition of cellulose spent liquor injected into the gaseous stream.
    • 本发明涉及使用气体发生器从纤维素废液中回收强碱性化学物质和能量值的两阶段气化方法。 通过控制加入含氧气体,将气体发生器的第一反应区中的温度保持在1000℃和1400℃之间。 从气体发生器的第一反应区的下方回收对应于至少75重量%的熔体的碱金属氧化物,碱金属氢氧化物,碱金属碳酸盐和碱金属硼酸盐的强碱性熔融物。 通过在第一反应区中的放热反应形成的气态组分流被引导到基本上升气流或上流设计的第二反应或气体转移区,其中气流被冷却到低于约1000℃的温度,所述冷却优选 通过注入到气流中的纤维素废液的吸热分解实现。
    • 5. 发明申请
    • THERMOCHEMICAL CONVERSION OF BIOMASS
    • WO2019093949A1
    • 2019-05-16
    • PCT/SE2018/051133
    • 2018-11-06
    • KIRAM AB
    • FURUSJÖ, ErikUMEKI, KentaroGEBART, Rikard
    • C10J3/06C10J3/60C10J3/62
    • 22 Abstract The present invention is directed to a process for the production of a syngas suited for further conversion to fine chemicals and/or automotive fuels from biomass by a thermochemical process conducted in a several steps procedure, said process comprising; a) Providing a stream of biomass material; b) Providing an aqueous alkaline catalyst stream comprising sodium and/or potassium compounds; c) Mixing comminuted biomass and alkaline catalyst and optional additives to form an alkaline biomass slurry or suspension; d) Treating alkaline biomass slurry or suspension in a hydrothermal treatment reactor at a temperature in the range of 200-400°C and a pressure from 10-500 bar, forming a bio- oil suspension comprising liquefied biomass and spent alkali catalyst; e) Directly or indirectly charging the bio-oil suspension from step d), after optional depressurization to a pressure in the range 10-100 bar, heat exchange and separation of gases, such as CO2, steam and aqueous spent catalyst into a gasification reactor operating in the temperature range of 600 – 1250°C thereby forming a syngas and alkali compounds; and f) Separating alkali compounds from a gasification reactor or from syngas and recycling alkali compounds directly or indirectly to be present to treat new biomass in the hydrothermal biomass treatment reactor of step d) and/or recycling aqueous alkali salts to a pulp mill chemicals recovery cycle. Elected for publication: fig. 1
    • 8. 发明申请
    • A METHOD FOR THE TREATMENT OF SPENT PULPING LIQUOR FOR THE REMOVAL AND PRODUCTION OF A LIGNIN CONTAINING PRODUCT
    • 一种用于处理含有液体的产品的方法,用于移除和生产含木质素的产品
    • WO2014193289A1
    • 2014-12-04
    • PCT/SE2014/050572
    • 2014-05-09
    • KIRAM AB
    • STIGSSON, LarsARKELL, AndersOLSSON, Johanna
    • D21C11/00D21C11/04C07G1/00C08H7/00
    • D21C11/0007C02F1/442C02F1/444C02F2103/28C07G1/00C08H6/00D21C11/04
    • The present invention describes a method for the treatment of spent pulping liquor for the removal and production of organic substances rich in lignin and recovering or recycling of aqueous cooking chemicals to pulp mill chemicals recovery cycle, said method comprising passing a spent pulping liquor flow from a digester or an evaporator, or from any other step in between the digester and the evaporator, through a filtration step in which the flow is separated into one aqueous stream comprising cooking chemicals being recovered or recycled and one stream concentrated with the respect of organic substances; passing the stream concentrated with respect of organic substances either to a lignin depolymerisation step for the production of liquid and pumpable depolymerised lignin or passing the stream concentrated with respect to organic substances to a subsequent filtration step in which an aqueous solution is added and further treatments in order to produce a solid lignin containing product.
    • 本发明描述了一种处理废浆液的方法,用于去除和生产富含木质素的有机物质,并将水性烹饪化学品回收或再循环到纸浆厂化学品回收循环中,所述方法包括将废制浆液从 蒸煮器或蒸发器,或从蒸煮器和蒸发器之间的任何其它步骤通过过滤步骤,其中将流分离成包含回收或再循环的烹饪化学品的一个含水流,并且一个与有机物质相关的一个物流; 将相对于有机物质浓缩的物流传递到用于生产液体和可泵送的解聚的木质素的木质素解聚步骤中,或使相对于有机物质浓缩的物流通过后续的过滤步骤,其中加入水溶液并进一步处理 以产生含木质素的固体产品。
    • 10. 发明申请
    • ALKALINE PROCESS FOR THE MANUFACTURING OF PULP USING ALKALI METABORATE AS BUFFERING ALKALI
    • 使用阿尔卡利代谢物作为缓冲碱生产浆液的碱性方法
    • WO2004025020A1
    • 2004-03-25
    • PCT/SE2003/001419
    • 2003-09-11
    • KIRAM ABSTIGSSON, Lars
    • STIGSSON, Lars
    • D21C11/00
    • D21C3/02D21C3/222D21C11/12
    • The present invention relates to a new and environmentally sound process for the manufacturing of a chemical pulp from lignocellulosic material with an integrated recovery system for recovery of pulping chemicals. The process is carried out in several stages involving a pre-treatment stage followed by one or more delignification stages using an alkaline buffer solution comprising alkali metaborate and sodium carbonate as major components. The alkaline components of the pulping liquor are recovered from a chemicals recovery furnace and at least a portion of the alkali is recycled and used for delignification without any prior reactions with lime or calcium compounds for generation of alkali hydroxide. A quinone based delignification catalyst may be added to be present during delignification. In a preferred embodiment of the invention the quinone pulping catalyst is added prior to alkaline delignification, said delignification conducted in the substantial absence of sulphide.
    • 本发明涉及一种用于从木质纤维素材料制造化学纸浆的新的和无害环境的方法,其具有用于回收制浆化学品的综合回收系统。 该方法在包括预处理阶段,然后使用包含偏硼酸钠和碳酸钠作为主要组分的碱性缓冲溶液的一个或多个脱木质阶段进行几个阶段。 制浆液的碱性成分从化学品回收炉回收,并且至少一部分碱被再循环并用于脱木质素,而与石灰或钙化合物没有任何预先的反应产生碱金属氢氧化物。 可以在脱木质素期间加入基于醌的脱木质素催化剂。 在本发明的优选实施方案中,在碱性脱木素之前加入醌制浆催化剂,所述脱木素基本上不存在硫化物。