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1. 发明申请

WO2010118853A1 PRODUCTION OF SATURATED AMMONIA STORAGE MATERIALS 审中-公开
标题翻译：生产饱和的氨氮储存材料
公开(公告)号：WO2010118853A1
公开(公告)日：2010-10-21
申请号：PCT/EP2010/002266
申请日：2010-04-13
申请人： AMMINEX A/S , JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik , SVAGIN, Jakob , JOHANNESSEN, Tue , QUAADE, Ulrich
发明人： JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik , SVAGIN, Jakob , JOHANNESSEN, Tue , QUAADE, Ulrich
IPC分类号： C01F5/30 , C01F11/24 , C09K5/04 , F25B15/04 , C01C1/00
CPC分类号： C09K5/04 , C01C1/006
摘要： A process for saturating a solid material capable of binding ammonia by ad- or absorption and initially free of ammonia or partially saturated with ammonia comprises treating said solid material under a pressure and associated temperature located on the vapor pressure curve of ammonia with an amount of liquid ammonia sufficient to saturate said solid material and an additional amount of a cooling agent selected from liquid ammonia, liquid or solid CO 2 , hydrocarbons and hydrohalocarbons that have a higher vapour pressure than ammonia, ethyl ether, methyl formate, methyl amine and ethyl amine, such that | Q abs | ≤ | Q evap | + Q ext , wherein Q abs is the amount of heat released from said solid material when it absorbs ammonia from the liquid phase thereof to the point where it is saturated with ammonia, Q evap is the amount of heat absorbed by said cooling agent when it evaporates, and Q ext is the amount of heat exchanged with the surroundings and is positive, if heat is removed from the process by external cooling, and negative, if heat is added to the process from the surroundings.
摘要翻译：使能够通过吸收和吸收结合氨并且最初不含氨或部分被氨饱和的固体材料饱和的方法包括在氨的蒸气压曲线下的压力和相关温度下处理所述固体材料，其量为液体足以使所述固体材料饱和的氨和额外量的选自液态氨，液体或固体CO 2，烃和氢卤素的冷却剂，其具有比氨，乙醚，甲酸甲酯，甲胺和乙胺更高的蒸气压，那个 Qabs | = | Qevap | + Qext，其中Q abs是当从其液相吸收氨到其被氨饱和的点时从所述固体材料释放的热量，Qevap是当所述冷却剂蒸发时吸收的热量，以及 Qext是与周围环境交换的热量，如果通过外部冷却从过程中除去热量，则为正，如果从周围环境中加热，则为负值。

2. 发明申请

WO2010025947A1 SATURATION OF AMMONIA STORAGE MATERIALS IN CONTAINERS 审中-公开
标题翻译：集装箱中的氨氮储存材料的饱和度
公开(公告)号：WO2010025947A1
公开(公告)日：2010-03-11
申请号：PCT/EP2009/006470
申请日：2009-09-07
申请人： AMMINEX A/S , SVAGIN, Jakob , QUAADE, Ulrich , BRADLEY, Ryan , JOHANSEN, Johnny , SCHMIDT, Henning , JOHANNESSEN, Tue
发明人： SVAGIN, Jakob , QUAADE, Ulrich , BRADLEY, Ryan , JOHANSEN, Johnny , SCHMIDT, Henning , JOHANNESSEN, Tue
IPC分类号： B01D53/14 , B01D53/90 , B01D53/94 , C01F11/24 , C09K5/04 , F25B17/08 , F25B35/04 , C01C1/00
CPC分类号： F17C11/00 , C01C1/006 , C01F11/24 , F25B17/08
摘要： A method of saturating reversible ammonia storage materials inside a container for the purpose of achieving high volumetric ammonia storage capacity and containers filled with the materials are disclosed.
摘要翻译：公开了一种使可逆氨储存材料在容器内饱和以达到高体积氨储存能力和装满材料的容器的方法。

3. 发明申请

WO2006034717A1 A PROCESS FOR THE PREPARATION OF AN ASYMMETRIC MEMBRANE COMPRISING A MESO- OR MACRO-POROUS SUBSTRATE AND A MICRO/MESO-POROUS LAYER DEPOSITED THEREON AND AN ASYMMETRIC MEMBRANE 审中-公开
标题翻译：一种制备包含MESO-或大孔多孔基底的非对称膜的方法及其沉积的微米/多孔层和非对称膜
公开(公告)号：WO2006034717A1
公开(公告)日：2006-04-06
申请号：PCT/DK2005/000620
申请日：2005-09-29
申请人： DANMARKS TEKNISKE UNIVERSITET , JOHANNESSEN, Tue , MOSLEH, Majid , JOHANSEN, Johnny , LIVBJERG, Hans
发明人： JOHANNESSEN, Tue , MOSLEH, Majid , JOHANSEN, Johnny , LIVBJERG, Hans
IPC分类号： B01D71/02 , B01D67/00 , C01B13/20 , B01J35/06 , B01J37/02
CPC分类号： B01D69/02 , B01D67/0004 , B01D67/0072 , B01D69/10 , B01D71/022 , B01D71/024 , B01D71/025 , B01D2325/022 , B01D2325/10 , B82Y30/00 , C01B13/20 , C01F7/304 , C01P2004/64 , C04B41/009 , C04B41/4582 , C04B2111/00801 , C23C16/045 , C23C16/44 , C23C16/453 , C04B41/5031 , C04B35/10 , C04B38/0051
摘要： The present invention relates to a process for the preparation of an asymmetric inorganic membrane comprising a meso- or macro-porous substrate and a micro/meso-porous layer deposited thereon. The present invention also relates to asymmetric membranes having a pore diameter in the one digit nanometer range.
摘要翻译：本发明涉及一种制备不对称无机膜的方法，所述不对称无机膜包含中孔或大孔底物和沉积在其上的微/中孔多孔层。本发明还涉及孔径在一位数纳米范围内的不对称膜。

4. 发明申请

WO2011038916A1 CONNECTED HEAT CONDUCTING STRUCTURES IN SOLID AMMONIA STORAGE SYSTEMS 审中-公开
标题翻译：固体阿姆斯壮储存系统中的连接导热结构
公开(公告)号：WO2011038916A1
公开(公告)日：2011-04-07
申请号：PCT/EP2010/005982
申请日：2010-09-30
申请人： AMMINEX A/S , SVAGIN, Jakob , QUAADE, Ulrich, J. , JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik , JOHANNESSEN, Tue
发明人： SVAGIN, Jakob , QUAADE, Ulrich, J. , JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik , JOHANNESSEN, Tue
IPC分类号： F01N3/20 , C01F11/24 , C01C1/00 , B01J20/04
CPC分类号： C01C1/006 , B01J20/0222 , B01J20/0288 , B01J20/046 , B01J20/2805 , F01N2610/02 , F01N2610/12
摘要： A compacted block of material constructed of one or more units consisting of matter comprising an ammonia-saturated material capable of reversibly desorbing and ad- or absorbing ammonia surrounded by a gas-permeableenclosure made of a flexible material having a thermal conductivity of at least about five times the thermal conductivity of said ammonia-saturated material at -70°C to 250°C and methods for producing the same are described.
摘要翻译：由一个或多个由包含氨饱和材料构成的材料构成的压实块材料，其能够可逆地解吸和吸附或吸收由气体可渗透的封闭体所包围的氨，所述气体可渗透的封闭体由具有至少约五的热导率的柔性材料制成将所述氨饱和材料的导热率乘以-70℃至250℃，并描述其制备方法。

5. 发明申请

WO2011103968A3 METHOD FOR DETERMINING THE DEGREE OF SATURATION OF SOLID AMMONIA STORAGE MATERIALS IN CONTAINERS 审中-公开
标题翻译：测定容器中固体氨储存材料饱和度的方法
公开(公告)号：WO2011103968A3
公开(公告)日：2011-09-01
申请号：PCT/EP2011/000674
申请日：2011-02-14
申请人： AMMINEX A/S , JOHANNESSEN, Tue , JOHANSEN, Johnny , ZEUTHEN, Jacob, Hjerrild , SCHMIDT, Henning , QUAADE, Ulrich, Joachim
发明人： JOHANNESSEN, Tue , JOHANSEN, Johnny , ZEUTHEN, Jacob, Hjerrild , SCHMIDT, Henning , QUAADE, Ulrich, Joachim
IPC分类号： C01C1/00 , F01N3/20
摘要： A method is provided for estimating the degree of saturation (S) of a reversible solid ammonia storage material (3) in a storage unit (1). The storage unit (1) is equipped with a heater (2) to release ammonia and a connected tube (4) for ammonia flow. The initial temperature (T INIT ) is measured with a sensor (9) in or around the storage unit (1) before any heating is initiated. Heating is initiated while recording the active time of heating (t) or the amount of energy (Q) released by the heater. The desorption pressure created by solid storage material in the storage unit (1) is measured via a pressure sensor (8) in fluid communication with the storage unit (1). The time (t TARGET ), or the heat (Q TARGET ) where the pressure reaches a certain target pressure (P TARGET ) is recorded. The values of the target-pressure time (t TARGET ), or the target-pressure heat (Q TARGET ), and the initial temperature (T INIT ) are used to compute an approximate degree of saturation (S).
摘要翻译：提供了一种用于估计存储单元（1）中的可逆固体氨储存材料（3）的饱和度（S）的方法。存储单元（1）配备有用于释放氨的加热器（2）和用于氨流动的连接管（4）。在任何加热开始之前，用存储单元（1）内或周围的传感器（9）测量初始温度（T INIT）。在记录加热的有效时间（t）或加热器释放的能量（Q）的同时开始加热。储存单元（1）中由固体储存材料产生的解吸压力经由与储存单元（1）流体连通的压力传感器（8）来测量。记录压力达到特定目标压力（P ）的时间（TARGET ）或热量（Q TARGET ）。目标压力时间（t TARGET）或目标压力热量（Q TARGET）的值以及初始温度（T INIT sub>）用于计算近似饱和度（S）。

6. 发明申请

WO2011103968A2 METHOD FOR DETERMINING THE DEGREE OF SATURATION OF SOLID AMMONIA STORAGE MATERIALS IN CONTAINERS 审中-公开
标题翻译：测定容器中固体氨储存材料饱和度的方法
公开(公告)号：WO2011103968A2
公开(公告)日：2011-09-01
申请号：PCT/EP2011000674
申请日：2011-02-14
申请人： AMMINEX AS , JOHANNESSEN TUE , JOHANSEN JOHNNY , ZEUTHEN JACOB HJERRILD , SCHMIDT HENNING , QUAADE ULRICH JOACHIM
发明人： JOHANNESSEN TUE , JOHANSEN JOHNNY , ZEUTHEN JACOB HJERRILD , SCHMIDT HENNING , QUAADE ULRICH JOACHIM
IPC分类号： C01C1/00 , F01N3/20
CPC分类号： B01D53/9495 , C01C1/006 , F01N3/208 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F01N2610/1406 , F01N2900/0408 , F01N2900/1808 , F01N2900/1811 , G01N7/16 , Y02A50/2325 , Y02T10/24
摘要： A method is provided for estimating the degree of saturation (S) of a reversible solid ammonia storage material (3) in a storage unit (1). The storage unit (1) is equipped with a heater (2) to release ammonia and a connected tube (4) for ammonia flow. The initial temperature (TINIT) is measured with a sensor (9) in or around the storage unit (1) before any heating is initiated. Heating is initiated while recording the active time of heating (t) or the amount of energy (Q) released by the heater. The desorption pressure created by solid storage material in the storage unit (1) is measured via a pressure sensor (8) in fluid communication with the storage unit (1). The time (t TARGET), or the heat (Q TARGET) where the pressure reaches a certain target pressure (PTARGET) is recorded. The values of the target-pressure time (t TARGET), or the target-pressure heat (Q TARGET), and the initial temperature (TINIT) are used to compute an approximate degree of saturation (S).
摘要翻译：提供了一种用于估计存储单元（1）中的可逆固体氨储存材料（3）的饱和度（S）的方法。存储单元（1）配备有用于释放氨的加热器（2）和用于氨流动的连接管（4）。初始温度（TINIT）在开始加热之前用存储单元（1）内或周围的传感器（9）测量。在记录加热的有效时间（t）或加热器释放的能量（Q）的同时开始加热。储存单元（1）中由固体储存材料产生的解吸压力经由与储存单元（1）流体连通的压力传感器（8）来测量。记录压力达到特定目标压力（PTARGET）的时间（t TARGET）或热量（Q TARGET）。使用目标压力时间（t TARGET）或目标压力热量（Q TARGET）和初始温度（TINIT）的值来计算近似饱和度（S）。

7. 发明申请

WO2010025948A1 ADDITIVES FOR HIGHLY COMPACTED AMMONIA STORAGE MATERIALS 审中-公开
标题翻译：高压阿姆斯特丹储存材料的添加剂
公开(公告)号：WO2010025948A1
公开(公告)日：2010-03-11
申请号：PCT/EP2009/006471
申请日：2009-09-07
申请人： AMMINEX A/S , QUAADE, Ulrich , SVAGIN, Jakob , JOHANSEN, Johnny , BRADLEY, Ryan
发明人： QUAADE, Ulrich , SVAGIN, Jakob , JOHANSEN, Johnny , BRADLEY, Ryan
IPC分类号： B01J20/02 , B01J20/04 , B01J20/20 , B01J20/30 , B01D53/94 , C01F11/24 , C09K5/04 , F25B17/08 , C01C1/00
CPC分类号： B01J20/30 , B01D53/9418 , B01D53/9481 , B01D2257/406 , B01J20/02 , B01J20/0214 , B01J20/0218 , B01J20/0222 , B01J20/0229 , B01J20/0237 , B01J20/0244 , B01J20/0248 , B01J20/0259 , B01J20/0281 , B01J20/0288 , B01J20/0292 , B01J20/0296 , B01J20/04 , B01J20/046 , B01J20/20 , B01J20/205 , B01J20/223 , B01J20/2803 , B01J20/28042 , B01J20/3007 , B01J20/3042 , B01J20/3092 , B01J2220/66 , C01C1/006 , F25B17/08
摘要： Disclosed is a self-supporting solid compacted composition of material comprising an ammonia storage material capable of reversibly absorbing and desorbing ammonia in its ammonia saturated state in admixture with one or more additives incapable of storing ammonia and having a thermal conductivity of at least five times the thermal conductivity of the ammonia storage material, as well as a process for preparing it.
摘要翻译：公开了一种自支撑固体压实组合物，其包含能够可逆地吸收和解吸其氨饱和状态的氨的氨储存材料，其与一种或多种不能储存氨并且具有至少五倍于氨储存材料的导热性，以及其制备方法。

8. 发明申请

WO2011144348A1 METHOD FOR SATURATING AND RE-SATURATING AMMONIA STORAGE MATERIAL IN CONTAINERS 审中-公开
标题翻译：容器中氨氮储存材料的再饱和和再饱和的方法
公开(公告)号：WO2011144348A1
公开(公告)日：2011-11-24
申请号：PCT/EP2011/002514
申请日：2011-05-19
申请人： AMMINEX A/S , JOHANNESSEN, Tue , QUAADE, Ulrich J. , JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik
发明人： JOHANNESSEN, Tue , QUAADE, Ulrich J. , JOHANSEN, Johnny , WAGNER-PEDERSEN, Henrik
IPC分类号： B01D53/04 , C01C1/00 , F17C11/00
CPC分类号： B01D53/0454 , B01D53/0438 , B01D2257/406 , B01D2259/4525 , C01C1/006 , F17C11/00
摘要： A method for saturating or re-saturating ammonia storage material (1) capable of reversibly absorbing and desorbing ammonia in one or more storage containers (2), wherein said material is partly or fully depleted of ammonia, with ammonia to a predetermined saturation degree comprises a. placing the storage container(s) (2) in direct or indirect contact with a thermostatting medium (4) at a temperature level T T ≤ about 65 °C; and b. connecting the storage container(s) (2) to a source of gaseous ammonia wherein at least during a part of the method the gaseous ammonia during saturating or re-saturation of the ammonia storage material (1) is at a pressure P S ≤ P T , wherein P S is the ammonia pressure during saturating or re-saturating of the ammonia storage material (1) and P T is the equilibrium vapor pressure of liquid ammonia at the temperature level T T .
摘要翻译：一种用于使氨储存材料（1）饱和或再饱和的方法，其能够在一个或多个储存容器（2）中可逆地吸收和解吸氨，其中所述材料部分或全部耗尽氨，氨与预定的饱和度包括一个。将储存容器（2）放置在温度等级TT =约65℃下与恒温介质（4）直接或间接接触; 和b。将所述储存容器（2）连接到气态氨源，其中至少在所述方法的一部分期间，所述氨储存材料（1）的饱和或再饱和期间的气态氨处于压力PS = PT，其中PS是在氨储存材料（1）的饱和或再饱和期间的氨压力，PT是在温度水平TT下液氨的平衡蒸气压。

9. 发明申请

WO2010040595A1 RELEASE OF STORED AMMONIA AT START-UP 审中-公开
标题翻译：在启动时释放存储的氨基酸
公开(公告)号：WO2010040595A1
公开(公告)日：2010-04-15
申请号：PCT/EP2009/060882
申请日：2009-08-24
申请人： AMMINEX A/S , JOHANSEN, Johnny , OECHSLE, Jan , SCHMIDT, Henning , JOHANNESSEN, Tue , SVAGIN, Jakob
发明人： JOHANSEN, Johnny , OECHSLE, Jan , SCHMIDT, Henning , JOHANNESSEN, Tue , SVAGIN, Jakob
IPC分类号： C01C1/00 , B01D53/94 , F01N3/20 , H01M8/04 , H01M8/06 , H01M8/22
CPC分类号： C01C1/006 , B01D2251/2062 , B01D2258/012 , B01D2258/014 , B01D2258/018 , F01N3/208 , F01N2610/02 , F01N2610/06 , F01N2610/10 , F01N2610/1406 , F01N2900/1808 , H01M8/04216 , H01M8/0606 , H01M8/222 , Y02T10/24
摘要： A system for storage and dosing of ammonia, including a solid ammonia storage material capable of binding and releasing ammonia reversibly by adsorption/absorption. The system is able to release ammonia gradually according to a demand that can vary over time with intermediate periods of no ammonia demand. A main storage unit and a start-up storage unit are provided. The storage units hold ammonia storage material. At least one one-way valve is provided via which the one main storage unit is in communication with the start-up storage unit. The one-way valve prevents any back-flow of ammonia from the start-up storage unit to the main storage unit. Heating devices are arranged to heat the main storage unit and the startup storage unit separately to generate gaseous ammonia by thermal desorption from the solid storage material. A controller controls the heating power of the main storage unit and the start-up storage unit, thereby enabling ammonia release from the start-up and/or the main storage units. A dosing valve controls ammonia flow from the storage units according to a demand.
摘要翻译：用于存储和计量氨的系统，包括能够通过吸附/吸收可逆地结合和释放氨的固体氨储存材料。该系统能够根据随时间变化的需求逐渐释放氨，而不需要氨中期。提供主存储单元和启动存储单元。储存装置容纳氨储存材料。提供至少一个单向阀，一个主存储单元通过该单向阀与启动存储单元连通。单向阀防止氨从启动存储单元向主存储单元的逆流。加热装置被布置成分开地加热主存储单元和启动存储单元，以通过从固体存储材料的热解吸产生气态氨。控制器控制主存储单元和启动存储单元的加热功率，从而使得能够从启动和/或主存储单元释放氨。计量阀根据需要控制存储单元的氨流量。

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