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1. 发明申请

WO2012053669A1 CONCRETE PANEL FOR ROAD PAVEMENT USING EXPANSION BAG, PAVING METHOD AND REPAIRING METHOD FOR THE SAME 审中-公开
标题翻译：使用膨胀袋进行道路铺设的混凝土面板，铺设方法及其修复方法
公开(公告)号：WO2012053669A1
公开(公告)日：2012-04-26
申请号：PCT/KR2010/007147
申请日：2010-10-19
申请人： HYUNDAI ENGINEERING CO.,LTD. , KOREA RAILROAD RESEARCH INSTITUTE , YOON, Heetaek , PARK, Youngkon , MOK, Jaikyun , BAE, Eulho , KIM, Ryanggyun , LEE, Yonggi , KIM, Kyungman
发明人： YOON, Heetaek , PARK, Youngkon , MOK, Jaikyun , BAE, Eulho , KIM, Ryanggyun , LEE, Yonggi , KIM, Kyungman
IPC分类号： E01C23/10
CPC分类号： E01C15/00 , E01C5/003 , E01C5/06 , E01C2201/16 , E01C2201/167
摘要： The present invention relates to a concrete panel using an expansion bag, a road paving method and a road repairing method, wherein, in paving a road by connecting with two or more concrete panels each other, According to the present invention, it is possible to easily adjust the horizontal height of the concrete panel, and to adjust the horizontal height of a concrete panel by correct data not by an experience of a constructor. In addition, According to the present invention, it is possible to construct the road at a low price.
摘要翻译：本发明涉及一种使用膨胀袋，道路铺路方法和道路修复方法的混凝土面板，其中，通过与两个或更多个混凝土板彼此连接来铺设道路。根据本发明，可以轻松调整混凝土面板的水平高度，并通过正确的数据调整混凝土面板的水平高度，而不是建构者的经验。此外，根据本发明，可以以低价格构建道路。

2. 发明申请

WO2011049301A3 HIGH-STRENGTH SAPO-34 MICROSPHERE CATALYST, METHOD FOR PREPARING SAME, AND METHOD FOR PREPARING LIGHT OLEFINS USING SAME 审中-公开
标题翻译：高强度SAPO-34微球催化剂，其制备方法及使用该催化剂制备轻质烯烃的方法
公开(公告)号：WO2011049301A3
公开(公告)日：2011-09-09
申请号：PCT/KR2010006753
申请日：2010-10-04
申请人： KOREA RES INST CHEM TECH , HYUNDAI ENGINEERING CO LTD , CHAE HO JEONG , JEONG SOON YONG , KIM CHUL UNG , JEONG KWANG EUN , KIM TAE WAN
发明人： CHAE HO JEONG , JEONG SOON YONG , KIM CHUL UNG , JEONG KWANG EUN , KIM TAE WAN
IPC分类号： B01J29/85 , C07C1/20 , C10G11/18
CPC分类号： B01J29/85 , B01J37/0045 , B01J2229/42 , C07C1/20 , C10G3/00 , C10G11/02 , C10G11/18 , C10G2400/20
摘要： The present invention relates to a high-strength silicoaluminophosphate-34 (SAPO-34) microsphere catalyst, to a method for preparing same, and to a method for preparing light olefins using same. In detail, the present invention relates to a method for preparing a SAPO-34 microsphere catalyst by spraying a slurry mixture containing a matrix, a binder, an additive, etc., onto the SAPO-34 slurry which is prepared by hydrothermal synthesis using various organic templates, such as tetraethylammonium hydroxide (TEAOH) or the like, wherein the organic templates are used alone or a mixture of the organic templates is used, drying the mixture slurry to obtain microspheres, and firing the microspheres. The present invention also relates to a SAPO-34 microsphere catalyst prepared by the method for a circulating fluidized bed reactor. The SAPO-34 microsphere catalyst of the present invention has a high strength and superior reaction activity, and therefore is suitable for use in a circulating fluidized bed reactor which requires a high strength catalyst. In addition, the SAPO-34 microsphere catalyst of the present invention has a long lifespan, and has a superior C1-C4 oxygenate conversion rate, and therefore is suitable for preparing light olefins such as ethylene, propylene, butane, and the like.
摘要翻译：本发明涉及高强度硅铝磷酸盐-34（SAPO-34）微球催化剂，其制备方法，以及使用该催化剂制备轻质烯烃的方法。具体而言，本发明涉及一种通过将含有基质，粘合剂，添加剂等的浆料混合物喷雾到通过水热合成制备的SAPO-34浆料上来制备SAPO-34微球催化剂的方法，所述浆料使用各种有机模板例如四乙基氢氧化铵（TEAOH）等，其中单独使用有机模板或使用有机模板的混合物，干燥混合物浆料以获得微球体，并烧制微球体。本发明还涉及通过用于循环流化床反应器的方法制备的SAPO-34微球催化剂。本发明的SAPO-34微球催化剂具有高强度和优异的反应活性，因此适用于需要高强度催化剂的循环流化床反应器。另外，本发明的SAPO-34微球催化剂寿命长，具有优良的C1-C4含氧化合物转化率，因此适用于制备乙烯，丙烯，丁烷等轻质烯烃。

3. 发明申请

WO2010035961A2 PREPARATION METHODS FOR LIQUID HYDROCARBONS BY FISCHER-TROPSCH SYNTHESIS THROUGH SLURRY REACTION 审中-公开
标题翻译：液相反应法合成Fischer-TrOPSCH法制备液态烃
公开(公告)号：WO2010035961A2
公开(公告)日：2010-04-01
申请号：PCT/KR2009/004851
申请日：2009-08-28
申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY , DAELIM INDUSTRIAL CO., LTD. , DOOSAN MECATEC CO., LTD. , KOREA NATIONAL OIL CORPORATION , HYUNDAI ENGINEERING CO., LTD , SK ENERGY CO., LTD. , OH, Jong-Hyeok , BAE, Jong-Wook , PARK, Sun Ju , LEE, Yun-Jo , JUN, Ki-won
发明人： OH, Jong-Hyeok , BAE, Jong-Wook , PARK, Sun Ju , LEE, Yun-Jo , JUN, Ki-won
IPC分类号： B01J23/75 , C07C1/04
CPC分类号： B01J23/75 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , C10G2/32 , C10G2/332 , C10G2/342 , C10G2300/4081
摘要： The present invention relates to a method for preparing liquid hydrocarbons via a slurry phase Fischer-Tropsch (F-T) synthesis. In particular, the present invention relates to a method for preparing liquid hydrocarbons from syngas via slurry phase F-T synthesis using a catalyst, which can prevent the decrease in catalyst activity and filter clogging due to catalyst aggregation, simultaneously with improving selectivity for C 5 or higher hydrocarbons by using C 7 -C 12 alcohols having a high boiling point as an additive for a slurry reaction solvent or recycling the same alcohol separated from by-products that are generated during the F-T reaction. Since t he method of the present invention is more carbon-effective and shows improved long-term stability of a reactor, it can be effectively used in the preparation of liquid hydrocarbons.
摘要翻译：本发明涉及通过淤浆相费 - 托（F-T）合成制备液态烃的方法。具体而言，本发明涉及一种通过使用催化剂的淤浆相FT合成从合成气制备液体烃的方法，其可以防止由于催化剂聚集而导致催化剂活性降低和过滤器堵塞，通过使用具有高沸点的C 7 -C 12醇作为淤浆反应溶剂的添加剂或再循环从其中分离出的相同的醇 FT反应过程中产生的副产物。由于本发明的方法碳效率更高并且反应器的长期稳定性得到改善，所以它可以有效地用于制备液态烃。

4. 发明申请

WO2009014292A2 CATALYSTS FOR FISCHER-TROPSCH SYNTHESIS ON COBALT/PHOSPHORUS-ALUMINUM OXIDE AND PREPARATION METHODS THEREOF 审中-公开
标题翻译：用于钴/磷 - 氧化铝上费 - 托合成法合成的催化剂及其制备方法
公开(公告)号：WO2009014292A2
公开(公告)日：2009-01-29
申请号：PCT/KR2008/000549
申请日：2008-01-30
申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY , DAELIM INDUSTRIAL CO., LTD. , DOOSAN MECATEC CO., LTD. , KOREA NATIONAL OIL CORPORATION , HYUNDAI ENGINEERING CO., LTD , SK ENERGY CO., LTD , JUN, Ki-won , BAE, Jong-Wook , KIM, Seung-Moon , LEE, Yun-Jo
发明人： JUN, Ki-won , BAE, Jong-Wook , KIM, Seung-Moon , LEE, Yun-Jo
IPC分类号： B01J27/185 , B01J23/75 , C07C1/04
CPC分类号： B01J23/75 , B01J27/16 , B01J27/1853 , B01J35/10 , B01J35/1019 , B01J35/1023 , B01J35/109 , B01J37/0201 , B01J37/0207 , B01J37/033 , B01J37/18 , B01J37/28
摘要： The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.
摘要翻译：本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。特别是，当使用催化剂进行费 - 托（F-T）反应时，F-T反应过程中产生的失活被抑制，同时钴和其它活性组分的分散和还原性得到改善。因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液态烃的稳定选择性。

5. 发明申请

WO2008147014A2 SYNTHETIC METHODS FOR LIQUID HYDROCARBONS FROM SYNGAS OVER ALUMINA-SILICA BASED CATALYSTS AND PREPARATION METHODS THEREOF 审中-公开
标题翻译：基于氧化硅 - 二氧化硅的催化剂的合成液的合成方法及其制备方法
公开(公告)号：WO2008147014A2
公开(公告)日：2008-12-04
申请号：PCT/KR2008/000548
申请日：2008-01-30
申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY , DAELIM INDUSTRIAL CO., LTD. , DOOSAN MECATEC CO., LTD. , KOREA NATIONAL OIL CORPORATION , HYUNDAI ENGINEERING CO., LTD , SK ENERGY CO., LTD , JUN, Ki-won , BAE, Jong-Wook , KIM, Seung-Moon , LEE, Yun-Jo
发明人： JUN, Ki-won , BAE, Jong-Wook , KIM, Seung-Moon , LEE, Yun-Jo
IPC分类号： B01J21/12
CPC分类号： B01J35/109 , B01J21/12 , B01J23/75 , B01J23/8896 , B01J23/8913 , B01J35/1019 , B01J37/0201 , B01J37/0205 , B01J37/0207 , B01J37/033 , C10G2/332 , C10G2/333
摘要： The present invention relates to an alumina- silica support having a double-layered, bimodal pore structure with different pore sizes in which alumina is dispersed on silica surface, a catalyst using the support and a method for preparing liquid hydrocarbons in high yield by Fischer- Tropsch reaction of a syngas (CO/H2/CO2) in the presence of the catalyst.
摘要翻译：本发明涉及具有不同孔径的双层双峰孔结构的氧化铝 - 二氧化硅载体，其中氧化铝分散在二氧化硅表面上，使用该载体的催化剂和一种以高收率制备液体烃的方法，在催化剂存在下，合成气（CO / H 2 / CO 2）的反应。

6. 发明申请

WO2010035961A3 PREPARATION METHODS FOR LIQUID HYDROCARBONS BY FISCHER-TROPSCH SYNTHESIS THROUGH SLURRY REACTION 审中-公开
标题翻译：通过浆料反应合成的液体烃的制备方法
公开(公告)号：WO2010035961A3
公开(公告)日：2010-05-20
申请号：PCT/KR2009004851
申请日：2009-08-28
申请人： KOREA RES INST CHEM TECH , DAELIM IND CO LTD , DOOSAN MECATEC CO LTD , KOREA NAT OIL CORP , HYUNDAI ENGINEERING CO LTD , SK ENERGY CO LTD , OH JONG-HYEOK , BAE JONG-WOOK , PARK SUN JU , LEE YUN-JO , JUN KI-WON
发明人： OH JONG-HYEOK , BAE JONG-WOOK , PARK SUN JU , LEE YUN-JO , JUN KI-WON
IPC分类号： B01J23/75 , C07C1/04
CPC分类号： B01J23/75 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , C10G2/32 , C10G2/332 , C10G2/342 , C10G2300/4081
摘要： The present invention relates to a method for preparing liquid hydrocarbons via a slurry phase Fischer-Tropsch (F-T) synthesis. In particular, the present invention relates to a method for preparing liquid hydrocarbons from syngas via slurry phase F-T synthesis using a catalyst, which can prevent the decrease in catalyst activity and filter clogging due to catalyst aggregation, simultaneously with improving selectivity for C5 or higher hydrocarbons by using C7-C12 alcohols having a high boiling point as an additive for a slurry reaction solvent or recycling the same alcohol separated from by-products that are generated during the F-T reaction. Since t he method of the present invention is more carbon-effective and shows improved long-term stability of a reactor, it can be effectively used in the preparation of liquid hydrocarbons.
摘要翻译：本发明涉及一种通过浆料相费 - 托（F-T）合成制备液体烃的方法。特别地，本发明涉及一种通过使用催化剂的淤浆相FT合成从合成气制备液体烃的方法，其可以防止催化剂活性降低和由于催化剂聚集而过滤堵塞，同时提高对C5或更高级烃的选择性通过使用具有高沸点的C7-C12醇作为淤浆反应溶剂的添加剂或循环与在FT反应期间产生的副产物分离的相同的醇。由于本发明的方法更有效且反应器的长期稳定性提高，因此可有效地用于制备液体烃。

7. 发明申请

WO2009119977A3 COBALT/ZIRCONIUM-PHOSPHORUS/SILICA CATALYST FOR FISCHER-TROPSCH SYNTHESIS AND METHOD OF PREPARING THE SAME 审中-公开
标题翻译：用于FISCHER-TROPSCH合成的COBALT / ZIRCONIUM-PHOSPHORUS / SILICA催化剂及其制备方法
公开(公告)号：WO2009119977A3
公开(公告)日：2010-04-01
申请号：PCT/KR2009000734
申请日：2009-02-16
申请人： KOREA RES INST CHEM TECH , DAELIM IND CO LTD , DOOSAN MECATEC CO LTD , KOREA NAT OIL CORP , HYUNDAI ENGINEERING CO LTD , SK ENERGY CO LTD , KIM SEUNG-MOON , BAE JONG-WOOK , OH JONG-HYEOK , LEE YUN-JO , JUN KI-WON
发明人： KIM SEUNG-MOON , BAE JONG-WOOK , OH JONG-HYEOK , LEE YUN-JO , JUN KI-WON
IPC分类号： B01J23/75 , B01J21/08 , B01J27/182 , C07C1/04
CPC分类号： B01J27/1856 , B01J23/002 , B01J27/1853 , B01J35/002 , B01J35/1019 , B01J35/1023 , B01J37/0201 , B01J37/03 , B01J2523/00 , C10G2/332 , B01J2523/41 , B01J2523/48 , B01J2523/51 , B01J2523/821 , B01J2523/845
摘要： The present invention relates to a cobalt/zirconium-phosphorus/silica catalyst in which cobalt, as an active ingredient, is impregnated on a zirconium-phosphorus/silica support prepared by treating the surface of silica with zirconium and phosphorus, and a method of preparing the catalyst. The catalyst has excellent reactivity since it has excellent heat and mass transfer properties due to a large pore structure of silica and increased reducibility of cobalt; excellent dispersion of cobalt and other activation substances during Fischer-Tropsch (F-T) reaction; and reduced sintering of cobalt particles during the reaction, and thus high CO conversion and stable selectivity for liquid hydrocarbon can be obtained during the F-T reaction.
摘要翻译：本发明涉及一种钴/锆 - 磷/二氧化硅催化剂，其中钴作为活性成分浸渍在用锆和磷处理二氧化硅表面制备的锆 - 磷/二氧化硅载体上，以及制备方法催化剂。催化剂具有优异的反应性，因为由于二氧化硅的大孔结构和钴的还原性，它具有优异的热传质性能; 在费 - 托（F-T）反应中钴和其他活化物质的优异分散; 并且在反应期间减少了钴颗粒的烧结，因此在F-T反应期间可以获得高CO转化率和对液态烃的稳定选择性。

8. 发明申请

WO2009107927A1 METHOD AND APPARATUS FOR THE CONTINUOUS SEPERATION AND DISCHARGE OF SOLID CATALYSTS AND PRODUCTS FOR FISCHER-TROPSCH SYNTHESIS REACTIONS 审中-公开
标题翻译：固体催化剂和FISCHER-TROPSCH合成反应产物的连续分离和放电的方法和装置
公开(公告)号：WO2009107927A1
公开(公告)日：2009-09-03
申请号：PCT/KR2008/007250
申请日：2008-12-08
申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY , DAELIM INDUSTRIAL CO., LTD. , DOOSAN MECATEC CO., LTD. , KOREA NATIONAL OIL CORPORATION , HYUNDAI ENGINEERING CO., LTD , SK ENERGY CO., LTD. , WOO, Kwang Jae , JUN, Ki-won , KANG, Suk-Hwan , KIM, Seung-Moon , BAE, Jong-Wook
发明人： WOO, Kwang Jae , JUN, Ki-won , KANG, Suk-Hwan , KIM, Seung-Moon , BAE, Jong-Wook
IPC分类号： B01D53/00
CPC分类号： B01J8/22 , B01J8/006 , B01J8/1809 , B01J2208/00061 , B01J2208/0007 , B01J2208/0061 , B01J2219/002 , B01J2219/00213 , B01J2219/00236 , C10G2/342 , C10G2300/4056 , C10G2300/4081
摘要： The present invention relates to a continuous separation and discharge apparatus and method of solid catalysts and liquid products for Fischer-Tropsch synthesis reactions, and more particularly, to a continuous separation and discharge apparatus and method of solid catalysts and products for Fischer-Tropsch synthesis reactions involving the conversion of synthetic gas into synthetic oil, by which products of the Fischer-Tropsch synthesis including wax, as a long-chain hydrocarbon, can be stably obtained by continuously separating the products from a slurry comprising solid catalyst particles and the products using periodic pulses of a feeding gas and discharging the products through a lower portion of a reactor. Provided is a continuous separation and discharge apparatus of solid catalysts and products for Fischer-Tropsch synthesis reactions including: a level sensing device which is installed at an upper portion of a reactor and detects the slurry-level of reactants; a solid catalyst/ product separation device and a discharge device which are installed at a lower portion of the reactor and separate and discharge liquid products from a mixed slurry in the reactor; and a control unit which receives a signal from the level sensing device to open and close the discharge device, wherein the separation device filters the solid catalysts, and the discharge device continuously discharges the products separated from the solid catalysts through the lower portion of the reactor by the amount of the synthesized products measured by a level sensing device.
摘要翻译：本发明涉及用于费 - 托合成反应的固体催化剂和液体产品的连续分离和排出装置和方法，更具体地说，涉及用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置和方法包括将合成气转化为合成油，由此通过使包含固体催化剂颗粒和产物的浆料的产物通过使用周期性的方式连续分离，从而可稳定地获得包含蜡的费 - 托合成作为长链烃的产物进料气体的脉冲并将产物排出反应器的下部。提供了用于费 - 托合成反应的固体催化剂和产物的连续分离和排放装置，包括：液位传感装置，其安装在反应器的上部并检测反应物的浆料水平; 固体催化剂/产物分离装置和排出装置，其安装在反应器的下部，并将反应器中的混合浆料分离和排出液体产物; 以及控制单元，其接收来自液位感测装置的信号以打开和关闭排出装置，其中分离装置对固体催化剂进行过滤，并且排出装置连续排出与固体催化剂分离的产物通过反应器的下部通过液位感测装置测量的合成产品的量。

9. 发明申请

WO2009014292A3 CATALYSTS FOR FISCHER-TROPSCH SYNTHESIS ON COBALT/PHOSPHORUS-ALUMINUM OXIDE AND PREPARATION METHODS THEREOF 审中-公开
标题翻译：钴/磷 - 氧化铝合成催化剂及其制备方法
公开(公告)号：WO2009014292A3
公开(公告)日：2009-03-26
申请号：PCT/KR2008000549
申请日：2008-01-30
申请人： KOREA RES INST CHEM TECH , DAELIM IND CO LTD , DOOSAN MECATEC CO LTD , KOREA NAT OIL CORP , HYUNDAI ENGINEERING CO LTD , SK ENERGY CO LTD , JUN KI-WON , BAE JONG-WOOK , KIM SEUNG-MOON , LEE YUN-JO
发明人： JUN KI-WON , BAE JONG-WOOK , KIM SEUNG-MOON , LEE YUN-JO
IPC分类号： B01J27/185 , B01J23/75 , C07C1/04
CPC分类号： B01J23/75 , B01J27/16 , B01J27/1853 , B01J35/10 , B01J35/1019 , B01J35/1023 , B01J35/109 , B01J37/0201 , B01J37/0207 , B01J37/033 , B01J37/18 , B01J37/28
摘要： The present invention relates to a cobalt/phosphorus-alumina catalyst in which cobalt is supported as an active component on a phosphorus-alumina support wherein phosphorus is supported on alumina surface. With a bimodal pore structure of pores of relatively different pore sizes, the catalyst provides superior heat- and matter-transfer performance and excellent catalytic reactivity. Especially, when Fischer-Tropsch (F-T) reaction is performed using the catalyst, deactivation by the water produced during the F-T reaction is inhibited and, at the same time, the dispersion and reducing property of cobalt and other active component are improved. Therefore, the cobalt/phosphorus-alumina catalyst for F-T reaction in accordance with the present invention provides good carbon monoxide conversion and stable selectivity for liquid hydrocarbons.
摘要翻译：本发明涉及一种钴/磷 - 氧化铝催化剂，其中钴作为活性组分负载在磷 - 氧化铝载体上，其中磷负载在氧化铝表面上。具有相对不同孔径的孔的双峰孔结构，催化剂提供优异的热和物质转移性能和优异的催化反应性。特别是当使用催化剂进行费托（F-T）反应时，抑制了F-T反应期间产生的水的失活，同时改善了钴等活性成分的分散还原性。因此，根据本发明的用于F-T反应的钴/磷 - 氧化铝催化剂提供了良好的一氧化碳转化率和对液体烃的稳定选择性。

10. 发明申请

WO2009031760A1 PREPARING PHOSPHORUS CONTAINING ALUMINA SUPPORT BY SOL-GEL METHOD FOR FISCHER-TROPSCH SYNTHESIS AND CATALYST PREPARATION THEREOF 审中-公开
标题翻译：通过溶胶凝胶法制备含有氧化铝的磷化合物，用于FISCHER-TROPSCH合成及其催化剂的制备
公开(公告)号：WO2009031760A1
公开(公告)日：2009-03-12
申请号：PCT/KR2008/004569
申请日：2008-08-06
申请人： KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY , DAELIM INDUSTRIAL CO., LTD. , DOOSAN MECATEC CO., LTD. , KOREA NATIONAL OIL CORPORATION , HYUNDAI ENGINEERING CO., LTD. , SK ENERGY CO., LTD. , BAE, Jong-Wook , KIM, Seung-Moon , LEE, Yun-Jo , JUN, Ki-won
发明人： BAE, Jong-Wook , KIM, Seung-Moon , LEE, Yun-Jo , JUN, Ki-won
IPC分类号： B01J27/185 , B01J23/75 , C07C1/04
CPC分类号： B01J27/1853 , B01J21/04 , B01J23/75 , B01J27/16 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J35/109 , B01J37/033 , C10G2/33 , C10G2/332
摘要： The present invention relates to a process of preparing of a phosphorus-containing phosphorus-alumina support by a sol-gel method and a cobalt/phosphorus-alumina catalyst where cobalt is supported onto the phosphorus-alumina support as an active ingredient. The phosphorus-alumina support is prepared by a sol-gel method and has wide specific surface area with bimodal pore size distribution and high cobalt dispersion, thereby enabling to increase heat and mass transfer, stabilize the structure by modifying the surface property of alumina and decrease the deactivation rate due to the reduced oxidation of cobalt component during the F-T reaction. When Fischer-Tropsch reaction (F-T) is conducted on the catalyst, the catalyst maintains a superior thermal stability, inhibits the deactivation due to water generation during the F-T reaction and also causes relatively high conversion of carbon monoxide and stable selectivity of liquid hydrocarbons.
摘要翻译：本发明涉及一种通过溶胶 - 凝胶法制备含磷磷 - 氧化铝载体的方法和一种钴/磷 - 氧化铝催化剂，其中钴作为活性成分负载在磷 - 氧化铝载体上。磷 - 氧化铝载体通过溶胶 - 凝胶法制备，具有宽的比表面积，具有双峰孔径分布和高钴分散性，从而能够增加热和质量传递，通过改变氧化铝的表面性能来稳定结构，并减少由于在FT反应期间钴组分的氧化降低导致的失活速率。当在催化剂上进行费 - 托反应（F-T）时，催化剂保持优异的热稳定性，抑制在F-T反应期间由于水的产生而失活，并且还导致一氧化碳相对较高的转化率和液体烃的稳定选择性。

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