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    • 3. 发明申请
    • HERBICIDAL PYRAZOLE-(THIO)-CARBOXAMIDES
    • 除草剂吡唑(THIO)-CARBOXAMIDES
    • WO1993025535A1
    • 1993-12-23
    • PCT/EP1993001466
    • 1993-06-09
    • RHONE POULENC AGRICULTURE LTD.RAPHY, GillesGINGELL, MichaëlHAWKINS, David, WilliamRICHARDS, Raymond, David
    • RHONE POULENC AGRICULTURE LTD.
    • C07D231/18
    • C07D401/12A01N43/56C07D231/20C07D231/22C07D231/36
    • N-substituted pyrazole derivatives of formula (I) wherein R represents optionally substituted alkyl or cycloalkyl; optionally substituted phenyl or benzyl; optionally substituted alkenyl or alkynyl; or a group selected from -SO2NR R , -SO2R and -CONR R ; R represents -X-R ; R represents hydrogen, halogen, optionally substituted alkyl or cycloalkyl, cyano, nitro, -S(O)mR , optionally substituted phenyl or -CO2R ; R represents optionally substituted phenyl or pyridyl; R represents hydrogen or alkyl; Y represents oxygen or sulphur; R represents alkyl or haloalkyl; R and R independently represent alkyl or haloalkyl; R represents alkyl or haloalkyl; R represents alkyl, haloalkyl or optionally substituted phenyl; R and R independently represent hydrogen, alkyl or haloalkyl; R represents optionally substituted phenyl or pyridyl; or optionally substituted alkyl, alkenyl or alkynyl; X represents oxygen atom, -NR - or -S(O)p-; R represents hydrogen, alkyl or haloalkyl; m and p independently represent 0, 1 or 2; and their herbicidal properties are described.
    • 式(I)的N-取代的吡唑衍生物,其中R 1表示任选取代的烷基或环烷基; 任选取代的苯基或苄基; 任选取代的烯基或炔基; 或选自-SO 2 NR 61,-SO 2 R 71和-CONR 61 R 62的基团。 R 2表示-X-R 10; R 3表示氢,卤素,任选取代的烷基或环烷基,氰基,硝基,-S(O)m R 6,任选取代的苯基或-CO 2 R 6; R 4表示任选取代的苯基或吡啶基; R 5表示氢或烷基; Y表示氧或硫; R 6表示烷基或卤代烷基; R 61和R 62独立地表示烷基或卤代烷基; R 7表示烷基或卤代烷基; R 71表示烷基,卤代烷基或任选取代的苯基; R 8和R 9独立地表示氢,烷基或卤代烷基; R 10表示任选取代的苯基或吡啶基; 或任选取代的烷基,烯基或炔基; X表示氧原子,-NR 11 - 或-S(O)p-; R 11表示氢,烷基或卤代烷基; m和p独立地表示0,1或2; 并描述了它们的除草性质。
    • 5. 发明申请
    • ISOXAZOLE DERIVATIVES AND THEIR USE AS HERBICIDES
    • 异佛唑衍生物及其作为除草剂的用途
    • WO1995025105A1
    • 1995-09-21
    • PCT/EP1995000951
    • 1995-03-14
    • RHONE-POULENC AGRICULTURE LTDGEACH, NeilHAWKINS, David, WilliamPEARSON, Christopher, JohnSMITH, Philip, Henry, GauntWHITE, Nicolas
    • RHONE-POULENC AGRICULTURE LTD
    • C07D413/04
    • C07D413/04A01N43/80
    • The invention relates to isoxazoles of formula (I) wherein: Ar represents a monocyclic or fused bicyclic heterocyclic system Het having a non-pyridyl heterocyclic first ring and an optional second heterocyclic or carbocyclic ring, the second ring when present being fused to the first ring, the first ring having from 1 to 4 hetero ring atoms and from 4 to 7 total ring atoms, the first ring being aromatic or non-aromatic and being optionally substituted by from 1 to 4R groups which may be the same or different, the second ring being optionally substituted by from 1 to 4 R groups which may be the same or different; R represents the hydrogen atom or a group -CO2R ; R represents: a straight- or branched- chain alkyl group containing from one to six carbon atoms which is optionally substituted by one or more halogen atoms; or a cycloalkyl group containing from three to six carbon atoms optionally substituted by one or more groups selected from R , -CO2R , -SR , halogen and -OR ; R represents: a halogen atom; a straight- or branched-chain alkyl group containing from one to six carbon atoms which is substituted by a group -OR ; or a group selected from -OH, R , -SR , -SOR , -SO2R , -O-SO2R , -CO2R , -COR , -OR , -NR R , -N(R )SO2R , nitro, cyano, -O(CH2)m-OR , -(-CR R -)t-S(O)pR and -NR R ; and to their use as herbicides.
    • 本发明涉及式(I)的异恶唑,其中:Ar表示具有非吡啶基杂环第一环和任选的第二杂环或碳环的单环或稠合双环杂环体系Het,当存在时与第一环稠合的第二环 ,第一个环具有1至4个杂环原子和4至7个总环原子,第一个环是芳族或非芳族的,并且任选被1至4R 2个基团取代,该基团可以相同或不同 第二个环任选被1至4个可以相同或不同的R 2基团取代; R表示氢原子或基团-CO 2 R 3; R 1表示:任选被一个或多个卤素原子取代的含有1至6个碳原子的直链或支链烷基; 或任选被一个或多个选自R 4,-CO 2 R 4,-SR 4,卤素和-OR 4的基团取代的含有3至6个碳原子的环烷基; R 2表示:卤素原子; 含有1-6个碳原子的直链或支链烷基,被-OR 4取代; 或选自-OH,R 4,-SR 5,-SOR 5,-SO 2 R 5,-O-SO 2 R 5,-CO 2 R 4,-COR 4, ,-OR 5,-NR 6 R 7,-N(R 8)SO 2 R 5,硝基,氰基,-O(CH 2)m -OR 4, - ( - CR (R)R 10 - )t S(O)p R 5和-NR 11 R 12; 并用作除草剂。