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1. 发明申请

WO2013112969A3 INTEGRATED HYDROTREATING AND STEAM PYROLYSIS PROCESS INCLUDING HYDROGEN REDISTRIBUTION FOR DIRECT PROCESSING OF A CRUDE OIL 审中-公开
标题翻译：集成加氢处理和蒸汽热解过程，包括直接加工原油的氢再分配
公开(公告)号：WO2013112969A3
公开(公告)日：2013-11-07
申请号：PCT/US2013023336
申请日：2013-01-27
申请人： SAUDI ARABIAN OIL CO , ARAMCO SERVICES CO , SHAFI RAHEEL , BOURANE ABDENNOUR , ABBA IBRAHIM A , AKHRAS ABDUL RAHMAN ZAFER
发明人： SHAFI RAHEEL , BOURANE ABDENNOUR , ABBA IBRAHIM A , AKHRAS ABDUL RAHMAN ZAFER
IPC分类号： C10G69/06 , C10G9/36
CPC分类号： C10G69/06 , C10G9/36
摘要： A process is provided that is directed to a steam pyrolysis zone integrated with a hydroprocessing zone including hydrogen redistribution to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals process comprises separating the crude oil into light components and heavy components; charging the heavy components and hydrogen to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; charging the hydroprocessed effluent and steam to a convection section of a steam pyrolysis zone; d. heating the mixture from the convection section of a steam pyrolysis zone and passing it to a vapor- liquid separation section; removing from the steam pyrolysis zone a residual portion from the vapor-liquid separation section; charging light components from the initial separation step, a light portion from the vapor-liquid separation section, and steam to a pyrolysis section of the steam pyrolysis zone; recovering a mixed product stream from the steam pyrolysis zone; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; and recovering olefins and aromatics from the separated mixed product stream.
摘要翻译：提供了涉及与加氢处理区整合的蒸汽热解区的方法，所述加氢处理区包括氢再分配以允许原油原料的直接加工以生产包括烯烃和芳族化合物的石化产品。用于直接处理原油以生产烯烃和芳族石化产品方法的整合加氢处理和蒸汽热解方法包括将原油分离成轻质组分和重质组分; 将重组分和氢气装入加氢处理区，该加氢区在有效产生加氢处理的流出物的条件下操作，所述加氢处理的流出物具有降低的污染物含量，增加的链烷烃含量，减少矿业局相关指数，并增加美国石油学会重力; 将加氢处理的流出物和蒸汽装入蒸汽热解区的对流区段; d。加热来自蒸汽热解区的对流区的混合物并将其传递到蒸汽 - 液体分离区段; 从蒸汽热解区中除去汽 - 液分离区的剩余部分; 将来自所述初始分离步骤的轻组分，来自所述气液分离部的轻组分以及蒸汽充入所述蒸汽热解区的热解部; 从蒸汽热解区回收混合产物流; 分离混合的产物流; 纯化从混合产物流中回收的氢并将其循环至加氢处理区; 并从分离的混合产物流中回收烯烃和芳族化合物。

2. 发明申请

WO2013142620A1 INTEGRATED SLURRY HYDROPROCESSING AND STEAM PYROLYSIS OF CRUDE OIL TO PRODUCE PETROCHEMICALS 审中-公开
标题翻译：原油生产石油化学的综合浆液加氢和蒸汽热解
公开(公告)号：WO2013142620A1
公开(公告)日：2013-09-26
申请号：PCT/US2013/033185
申请日：2013-03-20
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY , SAYED, Essam , SHAFI, Raheel , AKHRAS, Abdul Rahman, Zafer , BOURANE, Abdennour , ABBA, Ibrahim, A.
发明人： SAYED, Essam , SHAFI, Raheel , AKHRAS, Abdul Rahman, Zafer , BOURANE, Abdennour , ABBA, Ibrahim, A.
IPC分类号： C10G69/06 , C10G9/16 , C10G47/26 , C10G49/12 , B01D17/02 , B01D19/00
CPC分类号： C10G69/06 , C10G9/16 , C10G47/26 , C10G49/007 , C10G49/12 , C10G67/10 , C10G2400/20 , C10G2400/22 , C10G2400/30
摘要： An integrated slurry hydroprocessing and steam pyrolosyis process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil, a steam pyrolysis residual liquid fraction and slurry reside are combined and treated in a hydroprocessing zone in the presence of hydrogen under conditions effective to produce an effluent having an increased hydrogen content. The effluent is thermally cracked with steam under conditions effective to produce a mixed product stream and steam pyrolysis residual liquid fraction. The mixed product stream is separated and olefins and aromatics are recovered and hydrogen is purified and recycled.
摘要翻译：提供了一种用于从原油原料生产烯烃和芳族石油化学品的综合浆料加氢处理和蒸汽热解法。将原油，蒸气热解残余液体馏分和淤浆存在下，在氢气存在下，在加氢处理区域中有效地生成具有增加的氢含量的流出物的条件下进行处理。在有效产生混合产物流和蒸气热解残留液体馏分的条件下，流出物用蒸汽热裂解。分离混合的产物流，回收烯烃和芳族化合物，纯化和回收氢气。

3. 发明申请

WO2013142609A1 INTEGRATED HYDROPROCESSING, STEAM PYROLYSIS CATALYTIC CRACKING PROCESS TO PRODUCE PETROCHEMICALS FROM CRUDE OIL 审中-公开
标题翻译：一体化水解，蒸汽热解催化裂化工艺从原油生产石油化工
公开(公告)号：WO2013142609A1
公开(公告)日：2013-09-26
申请号：PCT/US2013/033165
申请日：2013-03-20
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY , ABBA, Ibrahim, A. , SHAFI, Raheel , BOURANE, Abdennour , SAYED, Essam , AKHRAS, Abdul Rahman, Zafer
发明人： ABBA, Ibrahim, A. , SHAFI, Raheel , BOURANE, Abdennour , SAYED, Essam , AKHRAS, Abdul Rahman, Zafer
IPC分类号： C10G69/06 , C10G69/04 , C10G9/16 , C10G55/04 , C10G55/06 , C10G51/02 , C10G51/06 , B01D17/02 , B01D19/00 , B01D53/24 , C10G47/00 , C10G45/00
CPC分类号： C10G69/06 , C10G9/16 , C10G11/00 , C10G45/00 , C10G47/00 , C10G49/007 , C10G51/02 , C10G51/04 , C10G51/06 , C10G55/04 , C10G55/06 , C10G67/10 , C10G69/00 , C10G69/04 , C10G2300/201 , C10G2300/308 , C10G2400/20 , C10G2400/22 , C10G2400/30
摘要： An integrated hydrotreating, steam pyrolysis and catalytic cracking process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil and hydrogen are charged to a hydroprocessing zone under conditions effective to produce a hydroprocessed effluent, which is thermally cracked in the presence of steam in a steam pyrolysis zone to produce a mixed product stream. Heavy components are catalytically cracked, which are derived from one or more of the hydroprocessed effluent, a heated stream within the steam pyrolysis zone, or the mixed product stream catalytically cracking. Catalytically cracked products are produced, which are combined with the mixed product stream and the combined stream is separated, and olefins and aromatics are recovered as product streams.
摘要翻译：提供了一种用于从原油原料生产烯烃和芳族石油化工的综合加氢处理，蒸汽热解和催化裂化方法。在有效地产生加氢处理的流出物的条件下，将原油和氢气加入加氢处理区，该加氢处理流出物在蒸汽热解区的蒸汽存在下被热裂解以产生混合产物流。重组分被催化裂解，其衍生自一种或多种加氢处理的流出物，蒸汽热解区内的加热流，或混合产物流催化裂解。产生催化裂化产物，将其与混合产物流混合，并将合并的流分离，并将烯烃和芳族化合物作为产物流回收。

4. 发明申请

WO2013142605A1 INTEGRATED HYDROPROCESSING AND STEAM PYROLYSIS OF CRUDE OIL TO PRODUCE LIGHT OLEFINS AND COKE 审中-公开
标题翻译：原油的氢化和蒸汽热解产生光油和焦炭
公开(公告)号：WO2013142605A1
公开(公告)日：2013-09-26
申请号：PCT/US2013/033156
申请日：2013-03-20
申请人： SAUDI ARABIAN OIL COMPANY , ARAMCO SERVICES COMPANY , SHAFI, Raheel , BOURANE, Abdennour , AKHRAS, Abdul, Rahman, Zafer , SAYED, Essam , ABBA, Ibrahim, A.
发明人： SHAFI, Raheel , BOURANE, Abdennour , AKHRAS, Abdul, Rahman, Zafer , SAYED, Essam , ABBA, Ibrahim, A.
IPC分类号： C10G9/16 , C10G51/02 , C10G69/06 , C10G9/00 , C10G55/04 , B01D17/02 , B01D53/24 , B01D19/00
CPC分类号： C10G69/06 , C10B57/045 , C10G9/005 , C10G9/16 , C10G49/007 , C10G51/06 , C10G69/00 , C10G2300/201 , C10G2300/308 , C10G2400/20 , C10G2400/22 , C10G2400/30 , Y02P20/132
摘要： An integrated hydrotreating, steam pyrolysis and coker process for the direct processing of a crude oil is provided to produce olefinic and aromatic petrochemicals, and petroleum coke. Crude oil and recycled coker liquid product are charged to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent which is thermally cracked in the presence of steam to produce a mixed product stream. The residual liquid fraction recovered upstream of the thermal cracking unit or within the thermal cracking unit is thermally cracked under conditions effective to produce coke and coker liquid product. The coker liquid product is recycled to the step of hydroprocessing while the petroleum coke is recovered. Hydrogen from the mixed product stream is purified and recycled to the hydroprocessing zone, and olefins, aromatics and pyrolysis fuel oil are recovered from the separated mixed product stream.
摘要翻译：提供了一种用于直接加工原油的综合加氢处理，蒸汽热解和焦化工艺，以生产烯烃和芳香族石油化学品和石油焦炭。将原油和再循环焦化液体产物装入加氢处理区，该加氢处理区在有效地产生加氢处理流出物的条件下运行，该加氢处理流出物在蒸汽存在下被热裂解以产生混合产物流。在热裂解单元上游或在热裂解装置中回收的剩余液体馏分在有效生产焦炭和焦化液体产物的条件下被热裂解。在回收石油焦时，将焦化液体产物再循环至加氢处理步骤。将来自混合产物流的氢气纯化并再循环至加氢处理区，并从分离的混合产物流中回收烯烃，芳烃和热解燃料油。

5. 发明申请

WO2013116338A1 MILD HYDRODESULFURIZATION INTEGRATING GAS PHASE CATALYTIC OXIDATION TO PRODUCE FUELS HAVING AN ULTRA-LOW LEVEL OF ORGANOSULFUR COMPOUNDS 审中-公开
标题翻译：气相加氢合成气相催化氧化生产具有超低浓度有机化合物的燃料
公开(公告)号：WO2013116338A1
公开(公告)日：2013-08-08
申请号：PCT/US2013/023848
申请日：2013-01-30
申请人： SAUDI ARABIAN OIL COMPANY , BORESKOV INSTITUTE OF CATALYSIS , BOURANE, Abdennour , KOSEOGLU, Omer, Refa , ISMAGILOV, Zinfer , YASHNIK, Svetlana , KERZHENTSEV, Mikhail , PARMON, Valentin
发明人： BOURANE, Abdennour , KOSEOGLU, Omer, Refa , ISMAGILOV, Zinfer , YASHNIK, Svetlana , KERZHENTSEV, Mikhail , PARMON, Valentin
IPC分类号： C10G27/04 , B01J23/00 , B01J23/06 , B01J23/80 , C10G45/02 , C10G67/12
CPC分类号： C10G67/12 , B01J23/002 , B01J23/005 , B01J23/80 , B01J23/83 , B01J35/0006 , B01J35/006 , B01J35/023 , B01J35/026 , B01J35/08 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J37/009 , B01J37/031 , B01J2523/00 , C10G27/04 , C10G45/02 , B01J2523/17 , B01J2523/27 , B01J2523/31
摘要： Desulfurization of hydrocarbonfeedsis achieved by first contacting the entire feed with a hydrodesulfurization catalyst in a hydrodesulfurization reaction zone operating under mild conditions to remove the labile organosulfur compounds. A flashing column downstream of the hydrodesulfurization reaction zone fractionates the effluent at a target cut point temperature to obtain two hydrocarbon fuel fractions. A first fraction boiling at or above the target cut point temperature contains the remaining refractory organosulfur compounds. A second fraction boiling below the target cut point temperature is substantially free of organosulfur compounds, since the organosulfur compounds boiling in the range of this fraction were the labile organosulfur compounds which were initially removed by mild hydrodesulfurization. The first fraction is contacted with a gaseous oxidizing agent over an oxidation catalyst having a formula Cu x Zn 1-x A1 2 O 4 in a gas phasecatalytic oxidation reaction zone to convert the refractory organosulfur compounds to SO x and low sulfur hydrocarbons. The by-product SO x is subsequently removed, producing a stream containing a reduced level of organosulfur compounds.
摘要翻译：通过在温和条件下操作的加氢脱硫反应区中首先使整个进料与加氢脱硫催化剂接触，以除去不稳定的有机硫化合物，从而实现烃源脱硫。在加氢脱硫反应区下游的闪烁塔在目标切割点温度下对流出物进行分馏以获得两个烃燃料馏分。在目标切割点温度以上沸腾的第一馏分含有剩余的难熔有机硫化合物。沸点低于目标切割点温度的第二部分基本上不含有机硫化合物，因为在该馏分范围内沸腾的有机硫化合物是最初通过温和加氢脱硫而去除的不稳定的有机硫化合物。将第一级分与气体氧化反应区中的具有式CuxZn1-xA12O4的氧化催化剂接触，将难熔有机硫化合物转化为SO x和低硫烃。随后除去副产物SOx，产生含有降低水平的有机硫化合物的物流。

6. 发明申请

WO2013019513A1 PROCESS FOR OXIDATIVE DESULFURIZATION WITH INTEGRATED SULFONE DECOMPOSITION 审中-公开
标题翻译：具有综合磺化分解的氧化脱硫方法
公开(公告)号：WO2013019513A1
公开(公告)日：2013-02-07
申请号：PCT/US2012/048167
申请日：2012-07-25
申请人： SAUDI ARABIAN OIL COMPANY , KOSEOGLU, Omer, Refa , BOURANE, Abdennour
发明人： KOSEOGLU, Omer, Refa , BOURANE, Abdennour
IPC分类号： C07C7/00
CPC分类号： B01J23/06 , B01J21/04 , B01J23/007 , B01J37/06 , B01J37/08 , C10G29/04 , C10G29/16
摘要： The process provided herein is concerned with disposal of oxidized sulfur compounds formed by oxidative desulfurization. The process uses solid base catalyst in the presence of a caustic solution or solid base catalyst pretreated with a base and eliminates the need to separate the sulfones from the hydrocarbon streams and recover the hydrocarbons.
摘要翻译：本文提供的方法涉及通过氧化脱硫形成的氧化硫化合物的处理。该方法在用碱处理的苛性碱溶液或固体碱催化剂存在下使用固体碱催化剂，并且不需要将烃与烃流分离并回收烃。

7. 发明申请

WO2013019509A1 INTEGRATED PROCESS TO PRODUCE ASPHALT AND DESULFURIZED OIL 审中-公开
标题翻译：一体化方法生产沥青和脱硫油
公开(公告)号：WO2013019509A1
公开(公告)日：2013-02-07
申请号：PCT/US2012/048145
申请日：2012-07-25
申请人： SAUDI ARABIAN OIL COMPANY , KOSEOGLU, Omer, Refa , BOURANE, Abdennour
发明人： KOSEOGLU, Omer, Refa , BOURANE, Abdennour
IPC分类号： C10G1/00
CPC分类号： C10G1/00 , C10G2300/202 , C10G2300/4006 , C10G2300/4012 , C10G2300/44
摘要： An integrated process is provided to produce asphalt and desulfurized oil. Sulfur molecules contained in heavy petroleum fractions, including organosulfur molecules, and in certain embodiments organonitrogen molecules are oxidized. The polar oxidized sulfur compounds shift from the oil phase to the asphalt phase.
摘要翻译：提供了生产沥青和脱硫油的综合工艺。包含在重质石油馏分中的硫分子，包括有机硫分子，在某些实施方案中，有机硫分子被氧化。极性氧化硫化合物从油相转变为沥青相。

8. 发明申请

WO2012050692A1 INTEGRATED DEASPHALTING AND OXIDATIVE REMOVAL OF HETEROATOM HYDROCARBON COMPOUNDS FROM LIQUID HYDROCARBON FEEDSTOCKS 审中-公开
标题翻译：来自液体烃的异源烃化合物的一体化去除和氧化除去
公开(公告)号：WO2012050692A1
公开(公告)日：2012-04-19
申请号：PCT/US2011/050990
申请日：2011-09-09
申请人： SAUDI ARABIAN OIL COMPANY , KOSEOGLU, Omer, Refa , BOURANE, Abdennour
发明人： KOSEOGLU, Omer, Refa , BOURANE, Abdennour
IPC分类号： C10G61/00
CPC分类号： C10G27/12 , B01J21/063 , B01J23/22 , B01J23/28 , B01J23/30 , C10G2300/202 , C10G2300/206 , C10G2300/44
摘要： A system and process are provided for integrated deasphalting and desulfurization of hydrocarbon feedstock in which the hydrocarbon feedstock, an oxidant, and an oxidation catalyst are mixed prior to passage into a primary settler of a solvent deasphalting unit. Oxidation products, including oxidized organosulfur compounds, are discharged with the asphalt phase.
摘要翻译：提供了一种用于烃原料的综合脱沥青和脱硫的系统和方法，其中烃原料，氧化剂和氧化催化剂在通入溶剂脱沥青装置的初级沉降器之前混合。包括氧化有机硫化合物在内的氧化产物用沥青相排出。

9. 发明申请

WO2012082685A3 INTEGRATED DESULFURIZATION AND DENITRIFICATION PROCESS INCLUDING MILD HYDROTREATING AND OXIDATION OF AROMATIC-RICH HYDROTREATED PRODUCTS 审中-公开
标题翻译：综合脱硫和脱硫工艺，包括加氢处理和氧化芳香族氢化产物的加氢脱硫
公开(公告)号：WO2012082685A3
公开(公告)日：2014-01-03
申请号：PCT/US2011064543
申请日：2011-12-13
申请人： SAUDI ARABIAN OIL CO , KOSEOGLU OMER REFA , BOURANE ABDENNOUR , AL-SHAHRANI FARHAN M , AL-SHAFI EMAD
发明人： KOSEOGLU OMER REFA , BOURANE ABDENNOUR , AL-SHAHRANI FARHAN M , AL-SHAFI EMAD
IPC分类号： C10G45/00
CPC分类号： C10G45/22 , B01J19/006 , B01J19/18 , B01J2219/00768 , B01J2219/00777 , C10G21/00 , C10G21/16 , C10G21/20 , C10G21/27 , C10G27/04 , C10G27/12 , C10G27/14 , C10G45/02 , C10G53/04 , C10G53/14 , C10G67/04 , C10G67/0418 , C10G67/12 , C10G67/14 , C10G2300/1096 , C10G2300/202 , C10G2300/44
摘要： Reduction of sulfur-containing and nitrogen-containing compounds from hydrocarbon feeds is achieved by first contacting the entire feed with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. An extraction zone downstream of the hydrotreating reaction zone separates an aromatic-rich fraction that contains a substantial amount of the remaining refractory organosulfur and organonitrogen compounds. The aromatic-lean fraction is substantially free of organosulfur and organonitrogen compounds, since the non-aromatic organosulfur and organonitrogen compounds were the labile organosulfur and organonitrogen compounds which were initially removed by mild hydrotreating. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized sulfur- containing and nitrogen-containing hydrocarbon compounds. These oxidized organosulfur and organonitrogen compounds are subsequently removed.
摘要翻译：通过在温和条件下操作的加氢处理反应区中首先使整个进料与加氢处理催化剂接触，以使不稳定的有机硫和有机氮化合物转化，从而进一步从烃进料中还原含硫和含氮化合物。在加氢处理反应区下游的萃取区分离富含芳烃的级分，其中含有大量剩余的难熔有机硫和有机氮化合物。芳香族贫馏分基本上不含有机硫和有机氮化合物，因为非芳族有机硫和有机氮化合物是不稳定的有机硫和有机氮化合物，最初通过轻度加氢处理除去。将富含芳烃的馏分氧化，将难熔有机硫和有机氮化合物转化为氧化的含硫和含氮烃化合物。随后除去这些氧化的有机硫和有机氮化合物。

10. 发明申请

WO2013115840A1 CATALYTIC REFORMING PROCESS AND SYSTEM FOR PRODUCING REDUCED BENZENE GASOLINE 审中-公开
标题翻译：催化改性工艺和生产降低苯酚汽油的方法
公开(公告)号：WO2013115840A1
公开(公告)日：2013-08-08
申请号：PCT/US2012/046150
申请日：2012-07-11
申请人： SAUDI ARABIAN OIL COMPANY , BOURANE, Abdennour , KOSEOGLU, Omer, Refa
发明人： BOURANE, Abdennour , KOSEOGLU, Omer, Refa
IPC分类号： C10G35/04 , C10G45/44 , C10G63/02 , C01B3/24 , C07C13/18
CPC分类号： C10G69/08 , C01B3/26 , C01B2203/0277 , C01B2203/1047 , C01B2203/1235 , C01B2203/1258 , C07C5/10 , C07C13/18 , C07C2521/04 , C07C2523/42 , C07C2601/14 , C10G35/04 , C10G45/44 , C10G63/02
摘要： A catalytic reforming process for producing gasoline of reduced benzene content includes the steps of reforming a reformer feedstock that includes a naphtha stream to produce a gasoline reformate product stream; splitting the gasoline reformate product stream into one or more relatively benzene-rich fractions and one or more relatively benzene-lean fractions; and hydrogenating the one or more relatively benzene-rich fractions to produce a cyclohexane-rich effluent, at least a portion of which cyclohexane-rich effluent is recycled to constitute a portion of the reformer feedstock.
摘要翻译：用于生产苯含量降低的汽油的催化重整方法包括重整包含石脑油流的重整器原料以产生汽油重整产物流的步骤; 将汽油重整产物流分成一个或多个相对富含苯的馏分和一种或多种相对苯稀馏的馏分; 并且使所述一种或多种相对富含苯的馏分氢化以产生富环己烷的流出物，其中至少一部分富含环己烷的流出物被再循环以构成重整器原料的一部分。

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