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1. 发明申请

WO2006109057A1 FUEL CELL 审中-公开
标题翻译：燃料电池
公开(公告)号：WO2006109057A1
公开(公告)日：2006-10-19
申请号：PCT/GB2006/001333
申请日：2006-04-12
申请人： ISIS INNOVATION LIMITED , HUMBOLDT-UNIVERSITAT ZU BERLIN , ARMSTRONG, Fraser, Andrew , VINCENT, Kylie, Alison , LENZ, Oliver , FRIEDRICH, Baerbel
发明人： ARMSTRONG, Fraser, Andrew , VINCENT, Kylie, Alison , LENZ, Oliver , FRIEDRICH, Baerbel
IPC分类号： H01M8/16
CPC分类号： H01M8/16 , Y02E60/527
摘要： A fuel cell and a method of operating the fuel cell, which fuel cell comprises an anode at which hydrogen is oxidised and a cathode at which an oxidant is reduced. The anode has a hydrogenase catalyst adsorbed thereon. Typically, the cathode has a reductase catalyst adsorbed thereon, the reductase being capable of catalysing the reduction of the oxidant. The fuel cell can be operated in the absence of a membrane separating the anode and cathode.
摘要翻译：燃料电池和操作燃料电池的方法，该燃料电池包括氢氧化的阳极和氧化剂被还原的阴极。阳极具有吸附在其上的氢化酶催化剂。通常，阴极具有吸附在其上的还原酶催化剂，还原酶能够催化氧化剂的还原。燃料电池可以在没有隔离阳极和阴极的膜的情况下操作。

2. 发明申请

WO2006030196A1 BIOCHEMICAL FUEL CELL 审中-公开
标题翻译：生化燃料电池
公开(公告)号：WO2006030196A1
公开(公告)日：2006-03-23
申请号：PCT/GB2005/003526
申请日：2005-09-13
申请人： ISIS INNOVATION LIMITED , HUMBOLDT-UNIVERSITAT ZU BERLIN , ARMSTRONG, Fraser, Andrew , VINCENT, Kylie, Alison , FRIEDRICH, Baerbel , LENZ, Oliver
发明人： ARMSTRONG, Fraser, Andrew , VINCENT, Kylie, Alison , FRIEDRICH, Baerbel , LENZ, Oliver
IPC分类号： H01M8/16
CPC分类号： H01M8/16 , H01M4/90 , Y02E60/527
摘要： A fuel cell and a method of operating the fuel cell, which fuel cell comprises an anode having a catalyst adsorbed thereon, said catalyst comprising an oxygen tolerant hydrogenase enzyme, in particular a hydrogenase from Ralstonia eutropha . The hydrogenase enzyme is typically also tolerant to carbon monoxide.
摘要翻译：燃料电池和操作燃料电池的方法，该燃料电池包括其上吸附有催化剂的阳极，所述催化剂包含耐氧氢化酶，特别是来自Ralstonia eutropha的氢化酶。氢化酶通常也耐一氧化碳。

3. 发明申请

WO2008062216A1 ELECTRODE 审中-公开
标题翻译：电极
公开(公告)号：WO2008062216A1
公开(公告)日：2008-05-29
申请号：PCT/GB2007/004499
申请日：2007-11-26
申请人： ISIS INNOVATION LIMITED , ARMSTRONG, Fraser Andrew , BLANFORD, Christopher, Francis , HEATH, Rachel Sarah
发明人： ARMSTRONG, Fraser Andrew , BLANFORD, Christopher, Francis , HEATH, Rachel Sarah
IPC分类号： H01M8/16 , H01M4/88 , H01M4/90 , H01M4/86
CPC分类号： H01M8/16 , H01M4/8807 , H01M4/8817 , H01M4/9008 , H01M4/9075 , H01M2004/8689 , Y02E60/527
摘要： The invention provides a method of preparing an enzyme-modified electrode or enzyme- modified electrode precursor comprising: (i) contacting an electrode or electrode precursor with a diazonium salt in order to modify a surface of said electrode or electrode precursor with a residue R, residue R being an organic residue of the diazonium salt and wherein the diazonium salt comprises (a) an aromatic cation either comprising: i. from two to four aromatic rings which are fused together and/or bonded to each other either directly or via a -CR=CR-, -C≡C- or -N=N- linker where R represents hydrogen or C 1-4 alkyl, one of which rings bears a -N 2 + substituent, and wherein the aromatic rings are the same or different and are the same or different and are selected from unsubstituted or substituted phenyl and 5- or 6- membered heteroaryl rings, or ii. a monocyclic aromatic ring selected from an unsubstituted or substituted phenyl and 5- or 6-membered heteroaryl ring, said aromatic ring bearing a -N 2 + substituent and a further conjugated substituent selected from C 2-6 alkenyl and C 2-6 alkynyl; and (b) a counter ion; and (ii) exposing the modified carbon-containing surface to a blue copper oxidase enzyme such that the enzyme binds to the residue R. The invention also provides an enzyme-modified electrode or enzyme-modified electrode precursor.
摘要翻译：本发明提供了制备酶修饰电极或酶修饰电极前体的方法，其包括：（i）使电极或电极前体与重氮盐接触，以便用残基R修饰所述电极或电极前体的表面，残基R是重氮盐的有机残基，其中重氮盐包含（a）芳族阳离子，其包括：i。两个至四个芳环直接或通过-CR = CR-，-C = C-或-N = N-连接体彼此融合在一起和/或彼此键合，其中R表示氢或C 1 -4个烷基，其中一个环带有-N + 2 +取代基，并且其中芳环相同或不同并且相同或不同，并且选自未取代或取代的苯基和5-或6-元杂芳基环，或ii。选自未取代或取代的苯基和5-或6-元杂芳基环的单环芳族环，所述带有-N 2+取代基的芳族环和另外的共轭取代基选自C 2 -6个烯基和C 2-6个炔基; 和（b）抗衡离子; 和（ii）将经修饰的含碳表面暴露于蓝色铜氧化酶，使得酶结合残基R.本发明还提供了酶修饰的电极或酶修饰的电极前体。

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