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    • 6. 发明申请
    • PROCESS FOR THE PURIFICATION OF POLYCARBONATE
    • 聚碳酸酯的纯化方法
    • WO2015013639A1
    • 2015-01-29
    • PCT/US2014/048235
    • 2014-07-25
    • SABIC INNOVATIVE PLASTICS IP B.V.HOLLAR JR., William E.
    • HOLLAR JR., William E.GAUTAM, Pankaj SinghKHADILKAR, MohanKUZELJEVIC, Zeljko
    • C08G64/40
    • C08G64/406
    • In an embodiment, a process of purifying a polycarbonate from an interfacial polymerization product mixture comprising an aqueous phase and an organic phase comprising a first organic solvent, the polycarbonate, a catalyst, and ions, the process comprises: separating the aqueous phase and the organic phase to form a separated aqueous feed stream and a separated organic stream; extracting the catalyst and the ions from the separated organic stream to form a purified polycarbonate stream and an extracted aqueous feed stream, wherein at least one of the separated aqueous feed stream and the extracted aqueous feed stream comprise an organic portion and an aqueous portion; purifying an aqueous stream comprising one or both of the separated aqueous feed stream and the extracted aqueous feed stream by adjusting a viscosity of the organic portion to be less than or equal to 40 centipoise by adding a second organic solvent to the aqueous stream to form a combined stream; optionally, adjusting a ratio of the aqueous portion to the organic portion to 1.0 to 20.0 by adding an aqueous solution to the aqueous stream; and separating the combined stream to form a purified aqueous stream, wherein less than or equal to 3 vol% of the purified aqueous stream is the organic portion.
    • 在一个实施方案中,从包含水相和包含第一有机溶剂,聚碳酸酯,催化剂和离子的有机相的界面聚合产物混合物中纯化聚碳酸酯的方法包括:将水相和有机物 形成分离的含水进料流和分离的有机物流; 从分离的有机物流中提取催化剂和离子以形成纯化的聚碳酸酯流和提取的含水进料流,其中至少一种分离的含水进料流和萃取的含水进料流包含有机部分和水性部分; 通过向水流中加入第二有机溶剂,将含有一种或两种分离的含水进料流和萃取的含水进料流的水流通过将有机部分的粘度调节至小于或等于40厘泊来形成 组合流 任选地,通过向水流中加入水溶液将水性部分与有机部分的比例调节至1.0至20.0; 并分离合并的流以形成纯化的含水流,其中小于或等于3体积%的纯化的水流是有机部分。