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71. 发明申请

WO01077199A1 CATALYST COMPOSITION AND PROCESS FOR PRODUCING COPOLYMER 审中-公开
标题翻译：催化剂组合物和生产共聚物的方法
公开(公告)号：WO01077199A1
公开(公告)日：2001-10-18
申请号：PCT/JP2001/002947
申请日：2001-04-05
IPC分类号： C08F4/54 , C08F4/60 , C08F10/00 , C08F295/00 , C08F297/00 , C08F297/02 , C08F297/04 , C08F297/06 , C08F36/04
CPC分类号： C08F297/06 , C08F10/00 , C08F295/00 , C08F297/00 , C08F297/02 , C08F297/04 , C08F4/52 , C08F36/04 , C08F4/545
摘要： A method of polymerizing a conjugated diene with an aromatic vinyl compound by block copolymerization, characterized by homopolymerizing the conjugated diene in the presence of a catalyst composition which comprises (A) a metallocene-form complex of a rare earth metal compound and (B) an ionic compound consisting of a non-coordinating anion and a cation and/or an aluminoxane and then adding the aromatic vinyl compound; and a catalyst composition for use in the polymerization of a conjugated diene or the copolymerization of a conjugated diene with an aromatic vinyl compound, which comprises (D) a neodymium complex and (B) an ionic compound consisting of a non-coordinating anion and a cation and/or an aluminoxane.
摘要翻译：一种通过嵌段共聚合使芳香族乙烯基化合物共轭二烯聚合的方法，其特征在于在催化剂组合物存在下使共轭二烯均聚，所述催化剂组合物包含（A）稀土金属化合物的茂金属络合物和（B）由非配位阴离子和阳离子和/或铝氧烷组成的离子化合物，然后加入芳族乙烯基化合物; 和共轭二烯与芳族乙烯基化合物的共聚合的催化剂组合物，其包含（D）钕络合物和（B）由非配位阴离子和阳离子和/或铝氧烷。

72. 发明申请

WO01062849A1 BLOCK COPOLYMER COMPOSITION 审中-公开
标题翻译：嵌段共聚物组合物
公开(公告)号：WO01062849A1
公开(公告)日：2001-08-30
申请号：PCT/JP2001/001317
申请日：2001-02-22
IPC分类号： C08F297/04 , C08K5/13 , C08L53/02 , C08L53/00
CPC分类号： C08L53/02 , C08F297/04 , C08L2666/14 , C08L2666/02
摘要： A thermally stabilized block copolymer composition comprising: a block copolymer which comprises at least one polymer block derived mainly from a monoalkenyl aromatic compound and at least one polymer block derived mainly from a conjugated diene compound and in which the content of units derived from the monoalkenyl aromatic compound is 5 to 95 wt.% based on the block copolymer; and phenolic stabilizers. Due to the incorporation of the two or more specific phenolic stabilizers in the block copolymer of a monoalkenyl aromatic compound and a conjugated diene compound, the block copolymer composition has excellent thermal stability even at high temperatures, is highly inhibited from generating a gel, and has an excellent color tone.
摘要翻译：一种热稳定嵌段共聚物组合物，其包括：嵌段共聚物，其包含至少一种主要由单链烯基芳族化合物衍生的聚合物嵌段和至少一种主要由共轭二烯化合物衍生的聚合物嵌段，其中衍生自单链烯基芳族化合物的单元含量化合物为5〜95重量％，基于嵌段共聚物; 和酚类稳定剂。由于在单链烯基芳香族化合物和共轭二烯化合物的嵌段共聚物中并入两种以上的特定的酚类稳定剂，因此嵌段共聚物组合物即使在高温下也具有优异的热稳定性，高度抑制凝胶的生成，并且具有色调很好。

73. 发明申请

WO01042353A1 FREE FLOWING POWDER 审中-公开
标题翻译：免费流动粉
公开(公告)号：WO01042353A1
公开(公告)日：2001-06-14
申请号：PCT/EP2000/012400
申请日：2000-12-06
IPC分类号： C08J3/12 , B29B13/10 , C08F297/04 , C08J5/00 , C08K5/00 , C08L53/02 , C08L101/00
CPC分类号： C08L53/025 , C08L53/02 , Y10S524/904 , C08L2666/24 , C08L2666/02
摘要： The present invention relates to a free flowing powder composition with a particle size at most 800 mu m comprising: (a) 100 parts by weight of one or more styrenic block copolymers, at least one of which being a block copolymer (a1) comprising at least one block S having a glass transition temperature Tg above 25 DEG C, which contains polymerized units of a vinylaromatic monomer and at least one elastomeric block B/S having a Tg below 25 DEG C, which contains polymerized units of both a vinylaromatic monomer and a conjugated diene in random sequence, wherein the ratio of block S to block B/S is from 1 to 40 % by volume and wherein the amount of the conjugated diene is less than 50 % by weight on the whole of the copolymer; optionally (b) 0 to 200 parts by weight of plasticizing oil; optionally (c) 0 to 200 parts by weight of a compatibilising resin; and optionally (d) a dusting agent in an amount of from 0 to 10 % by weight based on total weight of composition. It also relates to a process for the preparation thereof and to homogeneous layers derived therefrom.
摘要翻译：本发明涉及一种粒度至多为800μm的自由流动的粉末组合物，其包含：（a）100重量份的一种或多种苯乙烯类嵌段共聚物，其中至少一种是嵌段共聚物（a1），其包含玻璃化转变温度Tg高于25℃的至少一个嵌段S，其含有乙烯基芳族单体的聚合单元和至少一种Tg低于25℃的弹性体嵌段B / S，其含有乙烯基芳族单体和共轭二烯，其中嵌段S与嵌段B / S的比例为1〜40体积％，共轭二烯的量相对于全部共聚物为50重量％以下。任选地（b）0至200重量份的增塑油; 任选地（c）0至200重量份的增容树脂; 和任选地（d）占组合物总重量的0至10重量％的除尘剂。它还涉及其制备方法和由其衍生的均匀层。

74. 发明申请

WO01030859A1 METHOD FOR REMOVING HYDROCARBON SOLVENT FROM SOLUTION OF HYDROGENATED BLOCK COPOLYMER IN HYDROCARBON SOLVENT 审中-公开
标题翻译：在烃溶剂中从氢化嵌段共聚物溶液中除去烃溶剂的方法
公开(公告)号：WO01030859A1
公开(公告)日：2001-05-03
申请号：PCT/JP2000/007607
申请日：2000-10-27
IPC分类号： C08F6/12 , C08F8/04 , C08F297/04 , C08L53/02
CPC分类号： C08F8/04 , C08F6/12 , C08F297/04 , C08L53/02 , C08L53/025 , C08L2666/02
摘要： A method for removing a solvent from a hydrocarbon solvent solution of a hydrogenated block copolymer (a hydrogenation degree for double bonds of conjugated diene monomer units: 30 % or more) obtained by hydrogenating a block copolymer comprising a polymer block containing a vinyl aromatic monomer unit as a main component and a polymer block containing a conjugated diene monomer unit as another main component (vinyl aromatic monomer unit/ conjugated diene monomer unit, in weight ratio: 5/95 to 95/5), characterized as comprising (1) admixing the hydrocarbon solvent solution of a hydrogenated block copolymer with hot water to produce a dispersion comprising the solution dispersed in the hot water, and (2) introducing the dispersion to a steam stripping vessel by spraying the dispersion toward the surface of the hot water under a condition wherein the vapor pressure P1 of the dispersion and the pressure P2 of the gas phase satisfy the relationship: P1 >/= P2 , to remove the solvent through steam stripping, thereby preparing a porous crumb.
摘要翻译：通过氢化包含含有乙烯基芳族单体单元的聚合物嵌段的嵌段共聚物获得的氢化嵌段共聚物的烃溶剂溶液（共轭二烯单体单元的双键氢化度：30％以上）除去溶剂的方法作为主要成分和含有共轭二烯单体单元作为主要成分（乙烯基芳香族单体单元/共轭二烯单体单元，重量比：5/95〜95/5）的聚合物嵌段，其特征在于，含有（1）氢化嵌段共聚物与热水的烃溶剂溶液以产生包含分散在热水中的溶液的分散体，和（2）通过将分散体喷射到热水表面的条件下将分散体引入蒸汽汽提容器其中分散体的蒸汽压P1和气相的压力P2满足关系：P1> / = P2，以除去溶剂通道 h蒸汽汽提，从而制备多孔屑。

75. 发明申请

WO01010919A1 TAPERED AROMATIC-VINYL/CONJUGATED-DIENE COPOLYMER RUBBER, PROCESS FOR PRODUCING THE SAME, AND RUBBER COMPOSITION 审中-公开
标题翻译：接触式芳香 - 乙烯/共轭二烯共聚物橡胶，其生产方法和橡胶组合物
公开(公告)号：WO01010919A1
公开(公告)日：2001-02-15
申请号：PCT/JP2000/005333
申请日：2000-08-09
IPC分类号： C08F236/10 , C08F297/04 , C08L9/06 , C08L53/02
CPC分类号： C08L9/06 , C08F236/10 , C08F297/04 , C08F297/044 , C08L7/00 , C08L9/00 , C08L53/02 , C08L2666/02
摘要： A tapered aromatic-vinyl-monomer/conjugated-diene-monomer copolymer rubber in which the ratio of the content by weight of aromatic vinyl monomer units in the polymer molecules having a molecular weight which is 60 % of Mp, W0.6Mp, to that of aromatic vinyl monomer units in the polymer molecules having a molecular weight of Mp, WMp, is from 0.65 to 0.9 or from 1.1 to 1.3 provided that Mp is the molecular weight corresponding to the peak of a molecular weight distribution curve obtained by gel permeation chromatography, or a coupling type rubber obtained by linking polymer molecules of the copolymer rubber to one another at terminals thereof; and a rubber composition comprising either the copolymer rubber or the coupling type rubber and either natural rubber or a synthetic isoprene rubber. This rubber composition is reduced in heat build-up and excellent in resistance to wet skidding, strength properties, and wearing resistance.
摘要翻译：一种渐缩的芳族 - 乙烯基单体/共轭二烯 - 单体共聚物橡胶，其中分子量为Mp的60％，W0.6Mp的聚合物分子中的芳族乙烯基单体单元的重量比与的分子量为Mp，WMp的聚合物分子中的芳族乙烯基单体单元为0.65至0.9或1.1至1.3，条件是Mp是通过凝胶渗透色谱法获得的分子量分布曲线的峰的分子量或通过将共聚物橡胶的聚合物分子彼此连接而获得的偶联型橡胶; 以及包含共聚物橡胶或偶联型橡胶以及天然橡胶或合成异戊二烯橡胶的橡胶组合物。该橡胶组合物的发热减少，耐湿滑性，强度性能和耐磨性优异。

76. 发明申请

WO01009212A1 BUTADIENE/ISOPRENE/AROMATIC VINYL HYDROCARBON SEVENBLOCK COPOLYMER AND THE PREPARING METHOD THEREOF 审中-公开
公开(公告)号：WO01009212A1
公开(公告)日：2001-02-08
申请号：PCT/CN2000/000214
申请日：2000-07-28
IPC分类号： C08F297/04 , C08F297/00 , C08F297/02
CPC分类号： C08F297/046
摘要： The present invention relates to a butadiene/isoprene/aromatic vinyl hydrocarbon sevenblock copolymer and the process to prepare the copolymer. Said block copolymer have the following structure: Z-XZ-X-Y-X-XZ-Z, wherein Z is aromatic vinyl hydrocarbon polymer block, X and Y are selected from butadiene and isoprene polymer block, but they are different from each other, XZ is tapered copolymer block of aromatic vinyl hydrocarbon and butadiene or isoprene, aromatic vinyl hydrocarbon repeated units are 10-50 wt.% of the block copolymer, butadiene repeated units are 10-75 wt.% of the block copolymer, isoprene repeated units are 10-75 wt.% of the block copolymer.

77. 发明申请

WO00064948A1 A METHOD OF ANIONICALLY POLYMERIZING MONOMERS BY CONTACTING THE MONOMERS WITH A MONOFUNCTIONAL ANIONIC POLYMERIZATION INITIATOR 审中-公开
标题翻译：通过与单功能的阴离子聚合引发剂接触单体来进行单体聚合单体的方法
公开(公告)号：WO00064948A1
公开(公告)日：2000-11-02
申请号：PCT/EP2000/003732
申请日：2000-04-20
IPC分类号： C08F4/46 , C08F4/50 , C08F4/52 , C08F12/04 , C08F12/08 , C08F36/04 , C08F297/04 , C08C19/44
CPC分类号： C08F297/04 , C08F4/46 , C08F4/50 , C08F4/52 , C08F12/04 , C08F12/08 , C08F36/04 , C08F4/48
摘要： The present invention relates to a method of anionically polymerizing monomers by contacting the monomers with a monofunctional anionic polymerization initiator which is an organo-substituted alkali metal compound other than a silicon-based protected functional initiator in a suitable solvent to form a living polymer cement, the improvement which comprises reducing the viscosity of the polymer cement by adding to the cement during, before or after polymerization at least 0.01 equivalents of a metal alkyl compound per equivalent of living polymer chain ends wherein the alkyl groups of the metal alkyl compound are chosen so that they will not exchange with the living polymer chain ends.
摘要翻译：本发明涉及一种阴离子聚合单体的方法，该方法是在合适的溶剂中使单体与单官能阴离子聚合引发剂接触，该单官能阴离子聚合引发剂是硅基保护的官能引发剂以外的有机取代的碱金属化合物，以形成活性聚合物粘合剂，改进之处包括通过在聚合期间，聚合前或聚合后添加至少0.01当量的金属烷基化合物，每当量的活性聚合物链末端降低聚合物粘合剂的粘度，其中金属烷基化合物的烷基被选择为他们不会与活性聚合物链末端交换。

78. 发明申请

WO00042086A1 PROCESS FOR PRODUCING TAPERED BLOCK COPOLYMERS 审中-公开
标题翻译：生产嵌段嵌段共聚物的方法
公开(公告)号：WO00042086A1
公开(公告)日：2000-07-20
申请号：PCT/EP2000/000301
申请日：2000-01-14
IPC分类号： C08F297/04
CPC分类号： C08F297/046 , C08F297/04
摘要： The present invention is a process for producing a tapered block polymer which comprises optionally anionically polymerizing styrene to form a homopolymer block of polystyrene, anionically polymerizing isoprene to form a homopolymer block of polyisoprene, and anionically copolymerizing a mixture of styrene and isoprene to form a tapered copolymer block wherein each of the monomers styrene and isoprene is introduced at a rate of 15 % to 75 % by weight of the total tapered block monomer charge per minute and the weight ratio of the styrene to the isoprene is from 0.5:1 to 1.5:1. The process produces a unique polymer containing a tapered polymer block of styrene and isoprene which has a specific taper structure consisting of small segments of variable size of styrene monomers and isoprene monomers.
摘要翻译：本发明是一种制备锥形嵌段聚合物的方法，其包括任选地阴离子聚合苯乙烯以形成聚苯乙烯均聚物嵌段，阴离子聚合异戊二烯以形成聚异戊二烯的均聚物嵌段，并阴离子共聚苯乙烯和异戊二烯的混合物以形成锥形共聚物嵌段，其中单体苯乙烯和异戊二烯以每分钟总锥形嵌段单体电荷的15重量％至75重量％的速率引入，苯乙烯与异戊二烯的重量比为0.5:1至1.5:1。 1。该方法产生独特的聚合物，其含有苯乙烯和异戊二烯的锥形聚合物嵌段，其具有由可变尺寸的苯乙烯单体和异戊二烯单体的小段组成的特定锥形结构。

79. 发明申请

WO00008069A1 PROCESS FOR HYDROGENATING A CONJUGATED DIENE POLYMER 审中-公开
标题翻译：氢化联用二烯聚合物的方法
公开(公告)号：WO00008069A1
公开(公告)日：2000-02-17
申请号：PCT/KR1998/000440
申请日：1998-12-18
IPC分类号： C08F2/38 , C08C19/02 , C08F4/46 , C08F8/04 , C08F297/04 , C07F17/00 , C08F36/04
CPC分类号： C08F297/04 , C08C19/02 , C08F8/04
摘要： This invention relates to a process for selectively hydrogenating the unsaturated double bonds of conjugated diene units of a homopolymer or copolymer. By using a highly active novel homogeneous organo titanium catalyst represented by formula (I) and lithium hydride (LiH) prepared in solution of organo lithium compound and hydrogen as a reducing agent, a polymer could be hydrogenated with significantly high yield and good reproducibility. In addition, this invention is characterized by a novel method in that when a copolymer containing a conjugated diene and vinyl-substituted aromatic hydrocarbon, the unsatured double bonds of conjugated diene units are selectively hydrogenated. In said formula where, Cp is a cyclopentadienyl group (C5H5); R1 and R2 are the same or different and are selected from halogen atom; R3 and R4 are the same of different and are selected from hydrogen atoms, alkyl or alkoxy group containing 1 to 12 carbon atoms, aryl or aryloxy groups containing 6 to 20 carbon atoms and cycloalkyl groups containing 6 to 20 carbon atoms.
摘要翻译：本发明涉及选择性氢化均聚物或共聚物的共轭二烯单元的不饱和双键的方法。通过使用在有机锂化合物和氢作为还原剂的溶液中制备的高活性的由式（I）表示的均相有机钛催化剂和氢化锂（LiH），可以以高产率和良好的再现性氢化聚合物。此外，本发明的特征在于，当含有共轭二烯和乙烯基取代的芳族烃的共聚物时，共轭二烯单元的未成型双键被选择性氢化的新方法。在所述式中，Cp是环戊二烯基（C 5 H 5）; R1和R2相同或不同，选自卤素原子; R3和R4相同，选自氢原子，含有1至12个碳原子的烷基或烷氧基，含有6至20个碳原子的芳基或芳氧基以及含有6至20个碳原子的环烷基。

80. 发明申请

WO99005185A1 ENHANCED HYDROGENATION CATALYST REMOVAL FROM BLOCK COPOLYMERS BY REDUCTION IN POLYMER CEMENT VISCOSITY BY INCREASING THE VINYL CONTENT OF THE BLOCK COPOLYMERS 审中-公开
标题翻译：通过增加嵌段共聚物的乙烯含量，通过聚合物水泥粘度降低从嵌段共聚物中去除增强的氢化催化剂
公开(公告)号：WO99005185A1
公开(公告)日：1999-02-04
申请号：PCT/EP1998/004981
申请日：1998-07-20
IPC分类号： C08F2/06 , C08F2/44 , C08F6/02 , C08F6/08 , C08F8/04 , C08F297/04
CPC分类号： C08F297/04 , C08F6/02 , C08F8/04
摘要： In a process for producing hydrogenated block copolymers of conjugated dienes and/or vinyl aromatic hydrocarbons which comprises anionically polymerizing the monomers in an inert hydrocarbon solvent in the presence of an alkali metal initiator whereby a polymer cement is produced, contacting the cement with hydrogen under hydrogenation conditions in the presence of a hydrogenation catalyst, and then removing the hydrogenation catalyst residue by washing the polymer cement with water or an aqueous acid, the improvement which comprises reducing the viscosity of the polymer cement by polymerizing the block copolymer under conditions such that the vinyl content of the polymer produced in the polymerization step is in the range from 45 to 80 per cent by weight.
摘要翻译：在制备共轭二烯和/或乙烯基芳族烃的氢化嵌段共聚物的方法中，其包括在碱金属引发剂存在下在惰性烃溶剂中阴离子聚合单体，由此制备聚合物粘合剂，在氢化下使水泥与氢气接触在氢化催化剂存在下的条件，然后通过用水或酸性水洗涤聚合物粘合剂来除去氢化催化剂残余物，其改进包括通过在嵌段共聚物中聚合嵌段共聚物来降低聚合物粘合剂的粘度，在聚合步骤中生产的聚合物的含量在45至80重量％的范围内。

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