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71. 发明申请

WO02026381A2 IONIC LIQUIDS AND THEIR USE 审中-公开
标题翻译：离子液体及其使用
公开(公告)号：WO02026381A2
公开(公告)日：2002-04-04
申请号：PCT/GB2001/004306
申请日：2001-09-26
IPC分类号： B01J31/04 , B01J31/02 , B01J31/26 , B01J31/30 , B01J31/32 , B01J31/34 , C07B37/12 , C07B61/00 , C07C45/69 , C07C47/42 , C07C47/445 , C07C49/543 , C07C49/553 , C07C209/68 , C07C211/62 , C07C211/63 , C07C211/64 , C07C215/90 , C25D3/02 , C25D3/66 , C25D21/14 , C25F3/20 , C25F3/24 , H01M6/16 , H01M10/36 , B01J31/00
CPC分类号： B01J31/0284 , B01J31/006 , B01J31/0279 , B01J31/26 , B01J2231/125 , B01J2231/326 , C07B37/12 , C07C45/69 , C07C211/63 , C07C215/90 , C07C2601/16 , C07C2602/42 , C07C2602/44 , C25D3/02 , C25D3/665 , C25F3/20 , C25F3/24 , H01M6/164 , H01M6/166 , H01M10/36 , C07C47/42 , C07C49/543 , C07C49/553 , C07C47/445
摘要： Ionic compounds having a freezing point of no more than 50 DEG C, formed by the reaction of at least one amine salt of the formula R R R R N X (I) with at least one hydrated salts, which is a chloride, nitrate, sulphate or acetate of Li, Mg, Ca, Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd, Pb, Bi, La or Ce; wherein R , R and R are each independently a C1 to C5 alkyl or a C6 to C10 cycloalkyl group, or wherein R and R taken together represent a C4 to C10 alkylene group, thereby forming with the N atom of formula (I) a 5 to 11 membered heterocyclic ring, and wherein R is hydrogen, or phenyl, or C1 to C12 alkyl or cycloalkyl group, optionally substituted with at least one group selected from OH, Cl, Br, F, I, phenyl, NH2, CN, NO2, COOR , CHO, COR and OR , wherein R is a C1 to C10 alkyl or cycloalkyl group, and X is an anion capable of being complexed by the said hydrated salt. The compounds are useful as solvents, electrolytes, and catalyts, and have particular application in solvents/electrolytes for metal plating and electropolishing processes, in particular in chromium plating.
摘要翻译：通过至少一种式R 1 R 2 R 3，R 4，R 3，R 3，R 4，R 4，R 4，（I）与至少一种水合盐，其是Li，Mg，Ca，Cr，Mn，Fe，Co，Ni，Cu，Zn，Cd，Pb，Bi，La的氯化物，硝酸盐，硫酸盐或乙酸盐策; 其中R 1，R 2和R 3各自独立地为C 1至C 5烷基或C 6至C 10环烷基，或其中R 2和R 3一起表示C 4至C 10亚烷基由此与式（I）的N原子形成5至11元杂环，并且其中R 4是氢或苯基或C 1至C 12烷基或环烷基，任选被至少一个选自下的基团取代： OH，Cl，Br，F，I，苯基，NH 2，CN，NO 2，COOR 5，CHO，COR 5和OR 5，其中R 5是C 1至C 10烷基或环烷基 X - 是能够被所述水合盐络合的阴离子。该化合物可用作溶剂，电解质和催化剂，并且特别适用于用于金属电镀和电解抛光方法的溶剂/电解质，特别是在镀铬中。

72. 发明申请

WO0177053A3 CARBONYLATION CATALYST SUPPORTED ON A CARBONIZED POLYSULFONATED DIVINYLBENZENE-STYRENE COPOLYMER 审中-公开
标题翻译：碳化聚苯乙烯苯乙烯共聚物上的碳纳米管催化剂
公开(公告)号：WO0177053A3
公开(公告)日：2002-01-24
申请号：PCT/US0107818
申请日：2001-03-12
申请人： EASTMAN CHEM CO
发明人： ZOELLER JOSEPH ROBERT , SINGLETON ANDY HUGH , TRISTIN GERALD CHARLES , CARVER DONALD LEE
IPC分类号： B01J23/14 , B01J23/42 , B01J23/46 , B01J31/10 , B01J31/26 , B01J31/28 , B01J31/30 , B01J32/00 , C07B61/00 , C07C27/00 , C07C51/12 , C07C53/08 , C07C67/36 , C07C69/14 , B01J37/08 , B01J21/18
CPC分类号： C07C51/12 , B01J23/14 , B01J23/42 , B01J23/464 , B01J23/468 , B01J31/10 , B01J31/26 , B01J31/30 , C07C67/36 , C07C53/08 , C07C69/14
摘要： A catalyst in carbonylation processes for producing esters, carboxylic acids, and carboxylic acid anhydrides from lower alkyl alcohols, ethers, esters, alcohol producing derivatives. The catalyst includes a catalytically active metal selected from Group VIII metals, tin mixtures thereof associated with a carbonized polysulfonated divinylbenzene-styrene copolymer.
摘要翻译：用于从低级烷基醇，醚，酯，产醇衍生物生产酯，羧酸和羧酸酐的羰基化方法中的催化剂。催化剂包括选自VIII族金属的催化活性金属，其与碳化的多磺化二乙烯基苯 - 苯乙烯共聚物的锡混合物。

73. 发明申请

WO01074764A1 INTERMEDIATES FOR VITAMIN D AND PROCESSES FOR THE PREPARATION THEREOF 审中-公开
标题翻译：维生素D的中间体及其制备方法
公开(公告)号：WO01074764A1
公开(公告)日：2001-10-11
申请号：PCT/JP2000/002033
申请日：2000-03-30
IPC分类号： C07C309/65 , C07C401/00 , C07F7/18 , C07C317/20 , B01J31/24 , B01J31/30
CPC分类号： C07C401/00 , C07C309/65 , C07C2601/14 , C07C2601/16 , C07C2602/24 , C07F7/1856 , C07F7/1892
摘要： Intermediates for the synthesis of 1 alpha -hydroxyvitamin D derivatives useful as drugs; and processes for the preparation of the same. Specifically, a process for the preparation of a compound of the general formula (5), which comprises reacting compound (1) with a compound of the general formula (4) in the presence of a palladium catalyst to obtain a compound of the general formula (2), converting this compound (2) into a compound of the general formula (3) through the catalytic reduction of the compound (2) in the presence of a Lindlar catalyst and hydrogen gas and the heating of the obtained product, and oxidizing the compound (3) with an oxidizing agent; and compounds represented by the general formulae (1) to (3).
摘要翻译：用于合成用作药物的1α-羟基维生素D衍生物的中间体; 及其制备方法。具体而言，涉及制备通式（5）化合物的方法，该方法包括在钯催化剂存在下使化合物（1）与通式（4）的化合物反应，得到通式（2）中，在Lindlar催化剂和氢气的存在下，通过化合物（2）的催化还原将所得化合物（2）转化为通式（3）的化合物，加热得到的产物，氧化化合物（3）与氧化剂反应; 和由通式（1）至（3）表示的化合物。

74. 发明申请

WO0001486A3 P-ARAMID POLYMER CATALYST SUPPORTS 审中-公开
标题翻译： P-ARAMID聚合物催化剂支持
公开(公告)号：WO0001486A3
公开(公告)日：2001-10-11
申请号：PCT/US9914675
申请日：1999-06-30
申请人： DU PONT
发明人： KOCH THEODORE A , GABARA VLODEK , TOKARSKY EDWARD W , MCEVOY JOHN J
IPC分类号： B01J31/28 , B01J23/06 , B01J23/34 , B01J23/40 , B01J23/70 , B01J31/06 , B01J31/30 , B01J32/00 , B01J35/04 , B01J35/06
CPC分类号： B01J31/30 , B01J23/06 , B01J23/34 , B01J23/40 , B01J23/70 , B01J31/06 , B01J2231/641
摘要： A catalyst composition is disclosed which includes a p-aramid polymer supporting a catalyst agent. The composition exhibits improved catalytic activity when compared with a similar composition using m-aramid polymer as the support. The composition contemplates shaped and formed catalyst structures using p-aramid particles and fibers, as papers and fabrics, and as, for example, honeycomb and mats.
摘要翻译：公开了一种催化剂组合物，其包含支持催化剂的对位芳族聚酰胺聚合物。与使用间隔芳族聚酰胺聚合物作为载体的类似组合物相比，该组合物显示出改进的催化活性。该组合物考虑使用对芳族聚酰胺颗粒和纤维作为纸和织物以及例如蜂窝和垫子的成形和形成的催化剂结构。

75. 发明申请

WO00021662A1 PREPARATION OF AN ACTIVATED CATALYST USING AN INERT GAS IN THE ABSENCE OF HYDROGEN 审中-公开
标题翻译：在氢气不足下使用惰性气体制备活化催化剂
公开(公告)号：WO00021662A1
公开(公告)日：2000-04-20
申请号：PCT/EP1999/007398
申请日：1999-09-28
IPC分类号： B01J23/40 , B01J31/14 , B01J31/30 , C07C2/54 , C07C5/22 , C07C5/41 , C10G29/20 , C10G45/62
CPC分类号： B01J31/143 , B01J23/40 , B01J31/14 , B01J31/30 , B01J2231/52 , C07C2/54 , C07C5/228 , C07C5/417 , C07C2523/40 , C07C2531/14 , C07C2531/28
摘要： The invention pertains to a process for preparing an activated catalyst, to the activated catalyst composition and the use thereof in the conversion of hydrocarbon feedstocks, such as isomerisation. The catalyst composition comprising a Group VIII noble metal and a hydrocarbon-substituted aluminium compound on an alumina carrier is activated by contacting it with an inert gas in the absence of hydrogen at a temperature above 400 DEG C, wherein at least when the hydrocarbon-susbtituted aluminium compound is a non-halide hydrocarbon-substituted aluminium compound, the catalyst composition is contacted with a halogen-containing gas either prior to the treatment with the inert gas or during the treatment with the inert gas, and subsequently cooling down the activated catalyst to ambient temperature in an inert gas optionally containing hydrogen or containing, at a temperature below 400 DEG C, a halogen-containing gas; or if a halogen-containing gas is present during the treatment with the inert gas, alternatively cooling down in a mixture of an inert gas, a halogen-containing gas, and, optionally, hydrogen.
摘要翻译：本发明涉及制备活化催化剂，活化催化剂组合物的方法及其在烃原料转化如异构化中的应用。在氧化铝载体上包含VIII族贵金属和烃取代的铝化合物的催化剂组合物通过在高于400℃的温度下在不存在氢的情况下与惰性气体接触来活化，其中至少当烃 - 取代铝化合物是非卤化物烃取代的铝化合物，催化剂组合物在用惰性气体处理之前或在用惰性气体处理期间与含卤素气体接触，随后将活化的催化剂冷却至在惰性气体中，任选地含有氢气或在低于400℃的温度下含有含卤素的气体; 或者在用惰性气体处理期间存在含卤素的气体，或者在惰性气体，含卤素气体和任选的氢气的混合物中冷却。

76. 发明申请

WO98047616A1 CATALYST COMPRISING A BUFFERED IONIC LIQUID AND HYDROCARBON CONVERSION PROCESS, E.G. OLIGOMERISATION 审中-公开
标题翻译：包含缓冲液体和碳氢转化过程的催化剂，E.G. 低聚
公开(公告)号：WO98047616A1
公开(公告)日：1998-10-29
申请号：PCT/GB1998/000992
申请日：1998-04-03
IPC分类号： B01J31/02 , B01J31/12 , B01J31/14 , B01J31/22 , C07C2/32 , C10G50/00 , B01J31/30
CPC分类号： C10G50/00 , B01J31/0284 , B01J31/122 , B01J31/143 , B01J31/2234 , B01J31/2291 , B01J31/26 , B01J2231/20 , B01J2531/847 , C07C2/32 , C07C2531/22 , Y02P20/542
摘要： This invention relates to a buffered ionic liquid comprising: (A) a compound of the formula RnMX3-n or of the formula RmM2X6-m wherein M is a metal selected from aluminium, gallium, boron and iron (III) R is a C1-C6 alkyl radical, X is a halogen atom or an alkoxy group in which the alkyl group of said alkoxy group having 1-4 carbon atoms, n is 0, 1 or 2 and m is 1, 2 or 3; (B) an organic halide salt; and optionally, (C) an organic base wherein the relative mole-fractions of (A), (B) and (C) in the ionic liquid is within the ranges of 0.50-0.67 : 0.33-0.50 : 0.0-0.20. The ionic liquids can be used as a solvent or activator for hydrocarbon conversion catalyst such as e.g. during the oligomerisation of olefins with a nickel complex as catalyst.
摘要翻译：本发明涉及缓冲离子液体，其包含：（A）式RnMX3-n或式RmM2X6-m的化合物，其中M为选自铝，镓，硼和铁的金属（III），R为C1- C6烷基，X是卤素原子或烷氧基，其中所述烷氧基的烷基具有1-4个碳原子，n是0,1或2，m是1,2或3; （B）有机卤化物盐; 和（C）有机碱，其中离子液体中（A），（B）和（C）的相对摩尔分数在0.50-0.67:0.33-0.50:0.0-0.20的范围内。离子液体可以用作烃转化催化剂的溶剂或活化剂，例如在用镍络合物作为催化剂的烯烃低聚期间。

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