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61. 发明申请

WO2005037768A1 VERFAHREN ZUR HERSTELLUNG VON AMINEN 审中-公开
标题翻译：用于生产AMINES
公开(公告)号：WO2005037768A1
公开(公告)日：2005-04-28
申请号：PCT/EP2004/011642
申请日：2004-10-15
申请人： BASF Aktiengesellschaft , VAN LAAR, Frederik , SCHWAB, Ekkehard , OEHLENSCHLÄGER, Steffen , VOSS, Hartwig , MACKENROTH, Wolfgang , MORGENSCHWEIS, Konrad , PENZEL, Ulrich , WEIDNER, Bernd
发明人： VAN LAAR, Frederik , SCHWAB, Ekkehard , OEHLENSCHLÄGER, Steffen , VOSS, Hartwig , MACKENROTH, Wolfgang , MORGENSCHWEIS, Konrad , PENZEL, Ulrich , WEIDNER, Bernd
IPC分类号： C07C209/36
CPC分类号： C07C209/36 , B01J21/18 , B01J23/892 , B01J37/03 , B01J37/14 , B01J37/18 , C07C211/51
摘要： Gegenstand der Erfindung ist ein Verfahren zur Herstellung von aromatischen Nitroverbindungen zu den entsprechenden Aminen in Gegenwart von Hydrierkatalysatoren, dadurch gekennzeichnet, dass Hydrierkatalysatoren eingesetzt werden, bei denen Nickel und Platin auf einem Träger in Form einer Legierung mit einem Atomverhältnis von Nickel zu Platin in der Legierung zwischen 30:70 und 70:30 vorliegen.
摘要翻译：本发明涉及一种用于生产芳族硝基化合物在氢化催化剂的存在下，相应的胺的方法，其特征在于氢化催化剂，其中镍和铂上的合金的形式的支撑与铂合金中的镍的原子比可用的30:70至70:30。

62. 发明申请

WO2004052834A8 PROCESS FOR PREPARING 4-AMINODIPHENYLAMINE INTERMEDIATES 审中-公开
标题翻译：制备4-氨基二苯胺中间体的方法
公开(公告)号：WO2004052834A8
公开(公告)日：2005-03-31
申请号：PCT/IB0306492
申请日：2003-12-04
申请人： FLEXSYS AMERICA LP , TRIPLETT II RALPH DALE , RAINS ROGER KERANEN
发明人： TRIPLETT II RALPH DALE , RAINS ROGER KERANEN
IPC分类号： C07C209/36 , C07C209/68 , C07C211/55 , C07C211/56
CPC分类号： C07C209/68 , C07C209/36 , C07C211/55 , C07C211/56
摘要： The invention is directed to a method of producing 4-aminodiphenylamine comprising the steps of: (a)reacting an aniline or derivative thereof and nitrobenzene in a confined zone in the presence of a mixture comprising a base and an oxidant comprising hydrogen peroxide in an amount of from about 0.01 to about 0.60 moles of hydrogen peroxide to moles of nitrobenzene to obtain at least one 4-aminodiphenylamine intermediate; and (b) reducing the intermediate to 4-aminodiphenylamine, and (c) optionally, reductively alkylating 4-aminodiphenylamine to an alkylated derivative of the 4-aminodiphenylamine. The invention further pertains to a method of producing a 4-aminodiphenylamine intermediate as obtained in the above reaction.
摘要翻译：本发明涉及一种生产4-氨基二苯胺的方法，包括以下步骤：（a）在限制区内使苯胺或其衍生物与硝基苯在含有碱和氧化剂存在下反应，所述混合物包含一定量的过氧化氢约0.01至约0.60摩尔过氧化氢至硝基苯的摩尔数，以获得至少一种4-氨基二苯胺中间体; 和（b）将中间体还原成4-氨基二苯胺，和（c）任选地将4-氨基二苯胺还原烷基化为4-氨基二苯胺的烷基化衍生物。本发明还涉及上述反应得到的4-氨基二苯胺中间体的制造方法。

63. 发明申请

WO0200598A8 PROCESS FOR THE PRODUCTION OF AROMATIC AMINES 审中-公开
标题翻译：生产芳族氨基酸的方法
公开(公告)号：WO0200598A8
公开(公告)日：2003-06-19
申请号：PCT/EP0107478
申请日：2001-06-29
申请人： DOW GLOBAL TECHNOLOGIES INC , FORLIN ANNA , BECCARI ANTONIO
发明人： FORLIN ANNA , BECCARI ANTONIO
IPC分类号： C08G18/66 , C07B61/00 , C07C209/36 , C07C211/50 , C07C211/51 , C08G18/32
CPC分类号： C08G18/3243 , C07C209/36 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C07C211/51
摘要： A process for the production of an aromatic amine which comprises the reduction of an aromatic compound containing at least two nitro groups with hydrogen in the presence of a catalyst comprising a metal of Group VIII, wherein the reaction is carried out so as to maintain 30 % or less by weight of reaction intermediates and wherein the solution produced is treated to recover the aromatic amine with a purity of over 99 % and a mixture comprising aromatic amine and a reaction intermediate which is recycled to the reduction step.
摘要翻译：一种制备芳族胺的方法，其包括在包含第VIII族金属的催化剂存在下，用氢还原含有至少两个硝基的芳族化合物，其中反应进行以保持30％或更少的反应中间体，并且其中处理所产生的溶液以回收纯度超过99％的芳族胺和包含芳族胺和反应中间体的混合物，其被再循环到还原步骤。

64. 发明申请

WO02048075A1 PROCESS FOR SEPARATING MIXTURES OF MATERIALS HAVING DIFFERENT BOILING POINTS 审中-公开
标题翻译：分离具有不同沸点的材料混合物的方法
公开(公告)号：WO02048075A1
公开(公告)日：2002-06-20
申请号：PCT/US2001/047907
申请日：2001-12-12
IPC分类号： B01D3/00 , C07C209/36 , C07C209/86 , C07C211/50 , C07B63/00
CPC分类号： C07C209/86 , C07C211/50
摘要： A mixture of materials having different boiling points is separated into fractions having different boiling points. The separated fraction containing the desired product is stripped using the vapors of a lower boiling fraction. The process of the present invention is particularly useful for recovering a desired isomer or isomer mixture from a technical mixture obtained during production of an aromatic amine such as toluenediamine. Little or no unwanted isomer or by-product is present in the isomer or isomer or isomer mixture product of this process.
摘要翻译：具有不同沸点的材料的混合物被分离成具有不同沸点的级分。使用较低沸点馏分的蒸汽汽提含有所需产物的分离馏分。本发明的方法特别可用于从芳族胺如甲苯二胺制备期间获得的技术混合物中回收所需的异构体或异构体混合物。在该方法的异构体或异构体或异构体混合物产物中不存在或不存在不需要的异构体或副产物。

65. 发明申请

WO2002000598A3 PROCESS FOR THE PRODUCTION OF AROMATIC AMINES 审中-公开
公开(公告)号：WO2002000598A3
公开(公告)日：2002-01-03
申请号：PCT/EP2001/007478
申请日：2001-06-29
申请人： DOW GLOBAL TECHNOLOGIES INC. , FORLIN, Anna , BECCARI, Antonio
发明人： FORLIN, Anna , BECCARI, Antonio
IPC分类号： C07C209/36
摘要： A process for the production of an aromatic amine which comprises the reduction of an aromatic compound containing at least two nitro groups with hydrogen in the presence of a catalyst comprising a metal of Group VIII, wherein the reaction is carried out so as to maintain 30 % or less by weight of reaction intermediates and wherein the solution produced is treated to recover the aromatic amine with a purity of over 99 % and a mixture comprising aromatic amine and a reaction intermediate which is recycled to the reduction step.

66. 发明申请

WO01051452A1 IMPROVED SYNTHESIS OF N,N-DISUBSTITUTED-p-PHENYLENEDIAMINE 审中-公开
标题翻译： N，N-取代对苯二胺的改进合成
公开(公告)号：WO01051452A1
公开(公告)日：2001-07-19
申请号：PCT/US2001/001191
申请日：2001-01-12
IPC分类号： C07C209/86 , C07C209/10 , C07C209/36 , C07C211/50 , C07C211/53 , C07C209/68 , C07C209/82 , C07C211/51
CPC分类号： C07C209/10 , C07C209/36 , C07C211/53
摘要： An improved synthesis of N,N-disubstituted-p-phenylene-diamine (DSPDA) preferably di-n-butyl-p-phenylenediamine is disclosed. The improvement rests on the discovery that DSPDA and its salts are extremely sensitive to oxygen so that once the product DSPDA or its salt is formed, oxygen must be excluded from all manipulations.
摘要翻译：公开了N，N-二取代对苯二胺（DSPDA），优选二正丁基对苯二胺的改进合成。该改进取决于DSPDA及其盐对氧气非常敏感的发现，因此一旦形成产物DSPDA或其盐，必须从所有操作中排除氧气。

67. 发明申请

WO01036373A1 MANUFACTURING METHOD FOR 4-NITROSOANILINE FROM UREA AND NITROBENZENE 审中-公开
标题翻译：尿素和硝基苯的4-硝基苯胺的制备方法
公开(公告)号：WO01036373A1
公开(公告)日：2001-05-25
申请号：PCT/KR2000/000205
申请日：2000-03-15
IPC分类号： C07C209/02 , C07B61/00 , C07C209/00 , C07C211/52 , C07C209/36
CPC分类号： C07C209/00 , C07C211/52
摘要： Disclosed herein is a method for preparing 4-nitrosoaniline, comprising reacting urea and nitrobenzene in a polar organic solvent in the presence of a base at a temperature of room temperature to 150 DEG C. The method uses a relatively cheap urea and nitrobenzene as the raw materials, and also a relatively cheap base, thereby decreasing the manufacturing cost. Urea used as an amine donor is excellent in a reactivity to nitrobenzene, and a reaction intermediate is unstable as compared with 4-(4-nitrophenyl)benzamide to easily decompose into 4-nitroaniline and 4-nitrosoaniline. This allows a reaction time and a process time to be shortened. Moreover, the method is advantageous in that waste hazardous to the environment is not produced as a byproduct.
摘要翻译：本文公开了一种制备4-亚硝基苯胺的方法，其包括在碱存在下，在室温至150℃的温度下，在极性有机溶剂中使脲和硝基苯反应。该方法使用相对便宜的尿素和硝基苯作为原料材料，也是相对便宜的基础，从而降低制造成本。作为胺供体的尿素与硝基苯的反应性优异，与4-（4-硝基苯基）苯甲酰胺相比，反应中间体不容易分解成4-硝基苯胺和4-亚硝基苯胺。这允许缩短反应时间和处理时间。此外，该方法的优点在于，不会产生对环境有害的废物作为副产物。

68. 发明申请

WO00035853A1 METHOD OF PREPARATION OF 4-AMINODIPHENYLAMINE 审中-公开
标题翻译： 4-氨基二苯胺的制备方法
公开(公告)号：WO00035853A1
公开(公告)日：2000-06-22
申请号：PCT/SK1999/000010
申请日：1999-04-29
IPC分类号： C07B61/00 , C07C209/02 , C07C209/36 , C07C209/38 , C07C209/60 , C07C209/68 , C07C211/50 , C07C211/52 , C07C211/55 , C07C211/56
CPC分类号： C07C209/38 , C07C209/36 , C07C209/68 , C07C211/55 , C07C211/56
摘要： The solution relates to a method of preparation of 4-aminodiphenylamine through an intermediate preparation of 4-nitrodiphenylamine and/or 4-nitrosodiphenylamine and/or their salts by the reaction of aniline with nitrobenzene in a liquid medium at a temperature of 50 to 130 DEG C, under normal or reduced pressure, in an inert atmosphere or in the presence of air oxygen, with subsequent hydrogenation of an intermediate of 4-nitrodiphenylamine and/or nitrosodiphenylamine and side products, and by isolation of 4-aminodiphenylamine and the side products and recirculation of unconverted raw materials. The reaction of aniline with nitrobenzene, with selectivity of at least 50 % of 4-nitrodiphenylamine and nitrosodiphenylamine, is performed in a reaction system, consisting of a true zwitterion salt solution with hydroxides of a general formula HO /(R R R )N -CHR -(CH2)x-Y /Z where R and R means methyl to dodecyl, R means methyl, ethyl, phenyl, benzyl, R means hydrogen or methyl, x means an integer of 0 to 5, Y means CO2 , SO3 and Z means a cation of an alkali metal Li, Na, K, Cs or a tetrasubstituted quaternary ammonium cation, like tetramethylammonium, or their mutual combinations, wherein 4-nitrosophenylamine and/or 4-nitrodiphenylamine and/or their salts arise which yield, after hydrogenation, 4-ADFA, and after the reaction at least a half of the reaction system is used again for the next reaction and/or it is recycled. The reaction medium is formed separately and/or it will be formed in situ in the reaction system from raw materials. The liquid medium for the reaction of aniline with nitrobenzene is formed of water and/or at least one organic compound, chosen from among aniline, pyridine, toluene, xylene, cyclohexane and aliphatic alcohols having the number of carbons in the molecule of 1 to 4.
摘要翻译：该方法涉及通过苯胺与硝基苯在液体介质中在50〜130℃的温度下通过4-硝基二苯胺和/或4-亚硝基二苯胺和/或其盐的中间体制备方法制备的方法。在正常或减压下，在惰性气氛中或在空气氧的存在下，随后氢化4-硝基二苯胺和/或亚硝基二苯胺和副产物的中间体，并通过分离4-氨基二苯胺和副产物和未转化原料的再循环。在具有至少50％的4-硝基二苯胺和亚硝基二苯胺的选择性的苯胺与硝基苯的反应在由通式为HO 1 /（R 1）的氢氧化物的真正的两性离子盐溶液组成的反应体系中进行 R 2 R 3）N + CHR 4 - （CH 2）x Y - / Z +其中R 1和R 2表示甲基至十二烷基，R 3 >表示甲基，乙基，苯基，苄基，R 4表示氢或甲基，x表示0〜5的整数，Y表示二氧化碳，SO 3 - ，Z +表示阳离子的碱金属Li，Na，K，Cs或四取代的季铵阳离子，如四甲基铵或它们的相互组合，其中产生4-亚硝基苯胺和/或4-硝基二苯胺和/或其盐，其在氢化后产生4- 在反应后，反应体系的至少一半再次用于下一反应和/或其被再循环。反应介质分开形成和/或在反应体系中原位形成原料。用于苯胺与硝基苯反应的液体介质由水和/或至少一种选自苯胺，吡啶，甲苯，二甲苯，环己烷和分子中碳数为1至4的脂肪族醇的有机化合物形成。

69. 发明申请

WO1998013331A1 PROCESS FOR THE PREPARATION OF SUBSTITUTED AROMATIC AMINO COMPOUNDS 审中-公开
标题翻译：制备取代的芳族氨基化合物的方法
公开(公告)号：WO1998013331A1
公开(公告)日：1998-04-02
申请号：PCT/EP1997005151
申请日：1997-09-19
申请人： NOVARTIS AG , BAUMEISTER, Peter , SIEGRIST, Urs , STUDER, Martin
发明人： NOVARTIS AG
IPC分类号： C07C209/36
CPC分类号： C07C221/00 , C07C209/36 , C07C227/04 , C07C211/45 , C07C225/22 , C07C229/44 , C07C229/60
摘要： The present invention relates to a hydrogenation process for the preparation of aromatic amino compounds containing directly on the aryl ring or in a side chain one or more entities that may also undergo hydrogenation, such as carbon multiple bonds, nitrile groups, imino groups or carbonyl groups. The preparation is carried out by catalytic hydrogenation of the corresponding aromatic nitro compounds in the presence of a phosphorus-modified noble metal catalyst. The invention relates also to the use of modified noble metal catalysts for the hydrogenation of aromatic nitro compounds containing carbon multiple bonds and/or substituted by nitrile, imino or carbonyl groups.
摘要翻译：本发明涉及一种用于制备直接在芳环或侧链上的芳族氨基化合物的氢化方法，一个或多个也可能进行氢化的实体，如碳多重键，腈基，亚氨基或羰基。在磷改性贵金属催化剂存在下，通过相应的芳族硝基化合物的催化氢化进行制备。本发明还涉及改性贵金属催化剂用于氢化包含碳多重键和/或被腈，亚氨基或羰基取代的芳族硝基化合物的用途。

70. 发明申请

WO1997030967A1 HYDROGENATION OF AROMATIC NITROCOMPOUNDS TO AROMATIC AMINES 审中-公开
标题翻译：将芳族硝酸盐氢化成芳族氨基酸
公开(公告)号：WO1997030967A1
公开(公告)日：1997-08-28
申请号：PCT/FI1997000099
申请日：1997-02-18
申请人： VALTION TEKNILLINEN TUTKIMUSKESKUS , LAITINEN, Antero
发明人： VALTION TEKNILLINEN TUTKIMUSKESKUS
IPC分类号： C07C209/36
CPC分类号： C07B43/04 , C07C209/36 , Y02P20/544
摘要： This invention concerns a method for catalytic hydrogenation of aromatic nitrocompounds to aromatic amines by applying a supercritical or near-critical state solvent. The aromatic nitro compound, hydrogen gas and the solvent are mixed together under elevated pressure and temperature, so that a homogenous mixture which is in supercritical or near-critical state is formed. The resulting mixture is brought into contact with the catalyst and the reaction product is formed. The method has applicability to industrial processes for producing aromatic amines.
摘要翻译：本发明涉及通过应用超临界或近临界状态溶剂将芳族硝基化合物催化氢化成芳族胺的方法。芳香硝基化合物，氢气和溶剂在升高的压力和温度下混合在一起，从而形成处于超临界状态或近临界状态的均匀混合物。使所得混合物与催化剂接触，形成反应产物。该方法适用于生产芳族胺的工业过程。

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