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    • 61. 发明申请
    • TRIAZINYLAMINOSTILBENE DERIVATIVE AS FLUORESCENT WHITENING AGENTS
    • 三亚氨基苯甲酸衍生物作为荧光白剂
    • WO01019804A1
    • 2001-03-22
    • PCT/EP2000/008621
    • 2000-09-04
    • G03C1/815C07D251/68C07D251/70C09B57/00C11D3/42D06L3/12D06P1/00D06P3/60D21H21/30
    • C07D251/68Y10S8/919
    • The present invention relates to compounds having formula (1): wherein each R1 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, -OCOM, -OCOC1-C4-alkyl, or an amino acid residue from which a hydrogen atom on the amino group has been removed; each R2 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, -OCOM, -OCOC1-C4-alkyl, -CO2M, CO2C1-C4-alkyl SO3M or phenoxy which is unsubstituted or substituted by halogen, C1-C4-alkyl or C1-C4-alkoxy, -CO2M or CO2C1-C4-alkyl, NH2 or mono- or disubstituted amino; or phenyl which is unsubstituted or substituted by 1 to 3 SO3M, SO2NHC1-C4-alkyl, -SO2NH2, -CO2M, -CO2C1-C4-alkyl, -CONH2, -CONHC1-C4-alkyl, -NHCOC1-C4-alkyl or mono- or disubstituted amino groups; each R3 represents independently, hydrogen, C1-C4-alkyl, halogen, cyano, SO3M, -SO2NH2, SO2NHC1-C4-alkyl, -CO2M, -CO2C1-C4-alkyl, -CONH2, -CONHC1-C4-alkyl, or -NHCOC1-C4-alkyl; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine and m is an integer of 1 to 3, a process for their preparation and use of the compounds as optical brightening agents for synthetic or natural organic materials or for removing stain in photographic materials.
    • 本发明涉及具有式(1)的化合物:其中每个R 1独立地表示未被取代或被羟基,C 1 -C 4烷基,C 1 -C 4 - 烷氧基,C 1 -C 4烷基取代的直链C 1 -C 4亚烷基 - 羟基 - 或烷氧基 - 烷氧基,-OCOM,-OCOC1-C4-烷基或氨基上的氢原子已被除去的氨基酸残基; 每个R 2独立地表示未被取代或被羟基,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 羟基 - 或烷氧基 - 烷氧基,-OCOM,-OCOC 1取代的直链C 1 -C 4亚烷基 -C 1-4烷基,-CO 2 M,CO 2 C 1 -C 4 - 烷基SO 3 M或苯氧基,其未被取代或被卤素,C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基,-CO 2 M或CO 2 C 1 -C 4 - 烷基,NH 2或单或 二取代氨基; 或未取代或被1至3个SO 3 M,SO 2 NHC 1 -C 4烷基,-SO 2 NH 2,-CO 2 M,-CO 2 C 1 -C 4 - 烷基,-CONH 2,-CONHC 1 -C 4 - 烷基,-NHCOC 1 -C 4 - 烷基或单 - 或二取代的氨基; 每个R 3独立地表示氢,C 1 -C 4 - 烷基,卤素,氰基,SO 3 M,-SO 2 NH 2,SO 2 NHC 1 -C 4 - 烷基,-CO 2 M,-CO 2 C 1 -C 4烷基,-CONH 2,-CONHC 1 -C 4烷基或 - NHCOC1-C4-烷基; M是氢,碱金属原子,铵或由胺形成的阳离子,m是1至3的整数,其制备和使用该化合物作为合成或天然有机材料的荧光增白剂或除去的方法 照相材料染色。
    • 62. 发明申请
    • FORMAZANE COMPOUNDS AND METHODS OF DYEING WITH THE SAME
    • 芳香化合物及其染色方法
    • WO00046308A1
    • 2000-08-10
    • PCT/JP2000/000555
    • 2000-02-02
    • C09B50/06C09B50/00C09B62/04D06P1/38D06P3/60
    • C09B50/06
    • Novel blue dyes which can be prepared without using dianisidine compounds as the raw material, exhibit high color values, and are excellent in build-up properties and various fastnesses and suitable for dyeing cellulosic polymer materials; methods of dyeing cellulosic polymer materials with the same; and cellulosic polymer materials dyed therewith. The above blue dyes are formazane compounds represented by general formula (1) or salts thereof: wherein R1 is hydrogen, a sulfonic acid group, hydroxyl, chloro, methoxy, carbonyl or alkyl; either of R2 and R3 is hydrogen and the other thereof is a sulfonic acid group; X is morpholino, 2-hydroxyethylamino or bis(2-hydroxyethyl)amino; and Y is a group represented by general formula (2) (wherein R4 is a sulfonic acid group or carboxyl).
    • 新型蓝色染料可以在不使用二茴香胺化合物作为原料的情况下制备,颜色值高,并且具有优异的聚集性能和各种牢度,适用于染色纤维素聚合物材料; 染色纤维素聚合物材料的方法相同; 和用其染色的纤维素聚合物材料。 上述蓝色染料是由通式(1)表示的甲
      烷化合物或其盐:其中R 1是氢,磺酸基,羟基,氯,甲氧基,羰基或烷基; R2和R3中的任一个是氢,另一个是磺酸基; X是吗啉代,2-羟基乙基氨基或双(2-羟乙基)氨基; Y是由通式(2)表示的基团(其中R 4是磺酸基或羧基)。
    • 63. 发明申请
    • AGENT AND METHOD FOR DYEING FIBRES
    • 手段与方法于对纤维着色
    • WO00021496A1
    • 2000-04-20
    • PCT/EP1999/006601
    • 1999-09-08
    • A61K8/00A61K8/41A61K8/49A61Q5/06A61Q5/10C09B51/00D06P3/04D06P3/08D06P3/18D06P3/60D06P3/62A61K7/13
    • A61K8/418A61Q5/065A61Q5/10
    • The present invention relates to an agent for dying fibres, containing compounds of formula (I), whereby said compounds represent, independently from each other, the following: R1 is hydrogen or a straight-chain or branched chain alkyl group with 1-4 carbon atoms and Y is a heterocyclic ring of formula (II) wherein X is nitrogen or oxygen and m is the same as 1, 2, 3 and n is the same as 0 or 1, a cycloalkyl group with 1-6 carbon atoms, a (CH2)zOR group wherein z is 1, 2, 3, 4, 5 or 6 and R4 is a straight-chain or branched chain alkyl group with 1-4 carbon atoms, or an amino group NR2R3 wherein R2 and R3 represent, independently from each other, hydrogen (whereby R2 and R3 cannot simultaneously represent hydrogen). The invention also relates to a method for dyeing fibres, using said agent.
    • 本发明涉及含有式(I),其中独立地,R 1是氢或碳原子数为1〜4的直链或支链烷基,和Y是下式的杂环化合物的着色纤维的试剂(II) ,其中X是氮或氧,且m为1,2或3,n为0或1,具有1至6个碳原子,一个(CH 2)ZOR <4>基,具有Z等于1,2,3,4的环烷基 ,5或6,R 4为具有1至4个碳原子,或与R 2和R 3的氨基NR2R3的直链或支链的烷基独立地为氢(其中R2和R3nicht同时表示氢)基团; 和使用该着色剂的纤维的方法。
    • 70. 发明申请
    • ECOLOGICAL AND SUSTAINABLE INDIGO DYEING PROCESS WITH LESS WATER
    • WO2019045660A3
    • 2019-03-07
    • PCT/TR2017/050702
    • 2017-12-27
    • ORTA ANADOLU TICARET VE SANAYI İŞLETMESI TÜRK A.Ş.
    • CIFCI, AliKILIC, Umit CanCAM, Fatih
    • D06P1/22D06P3/60D06P1/673D06P1/651D06P1/52D06P5/20
    • The invention is an indigo dyeing process; of which harms to environment are reduced and rendered with lower costs in comparison to traditional applications; in order to reduce water consumption and prevent undesired salt formation when dyeing warps, used in denim production; and includes the steps of pre-wetting warp yarns in the form of a rope, prior to indigo dyeing; by making use of solution containing 1-5 cc/L sodium hydroxide (Caustic), 5-8 gr/L wetting agent and 1-5 gr/L ion immobilizer; washing at least 1 time with water at 20-70°C, with the purpose of removal of wetting agent used at pre-wetting step; reduction of indigo coloring agent, resorting to acetol (hydroxyacetone) at the temperature of 27 °C for a period of 10 to 15 minutes, for that water insoluble indigo is made soluble; checking solution's color to check whether the reduction of indigo coloring agent is completed; passing yarns in the form of a rope through vessels, containing dye solution at 27 °C with a pH value of 11 to 13 pH, in which the obtained indigo dye is discharged/put for successive 3 vessels at least, ensuring oxidation of reduced indigo coming out of dye vessel with oxygen in the air, in other words, making it contact with air, with the purpose of stabilizing dye on yarns by rendering it insoluble in water; dipping yarns in the form of a rope, on which oxidized indigo coloring agent there is into solution at 70-75°C with a pH value of 4 to 5, containing 10-20 gr/L polyamine polymer and 5-15 gr/L acetic acid.