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    • 62. 发明申请
    • PROCESS FOR PRODUCING HETEROPHASIC COPOLYMERS OF PROPYLENE
    • 生产丙烯的异构共聚物的方法
    • WO2016131907A1
    • 2016-08-25
    • PCT/EP2016/053430
    • 2016-02-18
    • BOREALIS AG
    • LESKINEN, PauliLILJA, JohannaWANG, JingboGAHLEITNER, Markus
    • C08L23/14C08F210/06C08F4/651
    • C08L23/142C08F210/06C08L2203/18C08F4/651C08F2/001C08L23/16C08F4/6492C08F210/16C08F2500/12C08F2500/17
    • The present invention provides a process for producing a heterophasic copolymer composition. The polymerisation is conducted in the presence of an olefin polymerisation catalyst comprising a solid catalyst component further comprising titanium, magnesium, halogen and an internal donor, and a cocatalyst, the process comprising the steps of: (1) introducing streams of the solid catalyst component, the cocatalyst, propylene monomer and hydrogen into a first polymerisation reactor; (2) producing a first polymer of propylene in the first polymerisation reactor, the first polymer of propylene having a first melt flow rate MFR 2 of from 0.1 to 2.0 g/10 min; (3) withdrawing a stream comprising the first polymer of propylene from the first polymerisation reactor and passing it to a second polymerisation reactor; (4) introducing a stream of propylene monomer into the second polymerisation reactor; (5) producing a first polymer mixture comprising the first polymer of propylene and a second polymer of propylene in the second polymerisation reactor, the first polymer mixture having a second melt flow rate MFR 2 of from 0.05 to 1.0 g/10 min and which second melt flow rate is less than the first melt flow rate; (6) withdrawing a stream comprising the first polymer mixture from the second polymerisation reactor and passing it to a third polymerisation reactor; (7) introducing streams of propylene monomer and the comonomer into the third polymerisation reactor; (8) producing the heterophasic copolymer composition comprising the first polymer mixture and a third copolymer of propylene in the third polymerisation reactor, the heterophasic copolymer composition having a third melt flow rate MFR 2 of from 0.05 to 1.0 g/10 min, said heterophasic copolymer having a content of comonomer units of from 5 to 25 % by mole; wherein the amount of xylene soluble fraction in the heterophasic copolymer determined according to ISO 16152 is from 14 to 35 % by weight and intrinsic viscosity measured from the amorphous polymer (AM) of the heterophasic copolymer is from 1.5 to 4.4 dl/g; and (9) recovering the heterophasic copolymer composition from the third polymerisation reactor; characterised in that the internal donor is a compound having the structure according to formula (I); wherein R 1 and R 2 are the same or different being a linear or branched C 1 -C 12 -alkyl group and R is hydrogen or a linear, branched or cyclic C 1 to C 12 -alkyl.
    • 本发明提供了一种制备多相共聚物组合物的方法。 聚合反应在含有进一步包含钛,镁,卤素和内部供体的固体催化剂组分的烯烃聚合催化剂和助催化剂的存在下进行,该方法包括以下步骤:(1)将固体催化剂组分 ,助催化剂,丙烯单体和氢气进入第一聚合反应器; (2)在第一聚合反应器中制备丙烯的第一聚合物,所述丙烯的第一聚合物的第一熔体流动速率MFR 2为0.1至2.0g / 10min; (3)从第一聚合反应器中取出包含丙烯的第一聚合物的物流并将其送至第二聚合反应器; (4)将丙烯单体流引入第二聚合反应器中; (5)在第二聚合反应器中产生包含丙烯的第一聚合物和丙烯的第二聚合物的第一聚合物混合物,第一聚合物混合物的第二熔体流动速率MFR 2为0.05-1.0g / 10min,第二熔体 流量小于第一熔体流动速率; (6)从第二聚合反应器中取出包含第一聚合物混合物的料流并将其送至第三聚合反应器; (7)将丙烯单体和共聚单体流引入第三聚合反应器中; (8)在第三聚合反应器中产生包含第一聚合物混合物和丙烯的第三共聚物的多相共聚物组合物,所述多相共聚物组合物具有0.05至1.0g / 10min的第三熔体流动速率MFR 2,所述多相共聚物具有 共聚单体的含量为5〜25摩尔% 其中根据ISO 16152测定的多相共聚物中二甲苯可溶级分的量为14至35重量%,并且由多相共聚物的无定形聚合物(AM)测量的特性粘度为1.5至4.4dl / g; 和(9)从第三聚合反应器回收多相共聚物组合物; 其特征在于所述内给体是具有式(I)结构的化合物; 其中R1和R2相同或不同,为直链或支链C1-C12-烷基,R为氢或直链,支链或环状C1至C12烷基。
    • 66. 发明申请
    • LOOP REACTOR PROVIDING AN ADVANCED PRODUCTION SPLIT CONTROL
    • 提供高级生产分割控制的循环反应器
    • WO2013092342A1
    • 2013-06-27
    • PCT/EP2012/075222
    • 2012-12-12
    • BOREALIS AG
    • LESKINEN, PauliHAKOLA, SameliALASTALO, KaunoNYFORS, Klaus
    • C08F10/00C08F2/14B01J19/24
    • C08F110/06B01J19/0033B01J19/0053B01J19/2435B01J19/245B01J19/2455B01J2219/0004B01J2219/00049C08F10/00C08F210/06C08F2/14C08F2500/12C08F210/16
    • Method for preparing olefin polymer in a loop reactor, said loop reactor comprises a first outlet for withdrawing polymer slurry from the loop reactor, and a second outlet for withdrawing a polymer slurry from the loop reactor, wherein the first outlet is located such that polymer slurry is withdrawn having a concentration of polymer which is equal or higher than the average concentration of polymer in the loop reactor, and the second outlet is located such that polymer slurry is withdrawn having a concentration of polymer which is lower than the average concentration of polymer in the loop reactor, the method comprises the steps of supplying olefin monomers and a catalytic system to the loop reactor to form a polymer slurry in the loop reactor, and controlling the total amount of polymer and/or the total amount of polymer slurry withdrawn from the loop reactor by adjusting the ratio of polymer slurry withdrawn through the first outlet and polymer slurry withdrawn through the second outlet.
    • 在环管反应器中制备烯烃聚合物的方法,所述环管反应器包括用于从环管反应器中抽出聚合物浆料的第一出口和用于从环管反应器中抽出聚合物浆料的第二出口,其中第一出口定位成使得聚合物浆料 被取出,其聚合物的浓度等于或高于环管反应器中聚合物的平均浓度,并且第二出口被定位成使得聚合物浆料被取出,其聚合物的浓度低于聚合物的平均浓度 环路反应器,该方法包括以下步骤:将烯烃单体和催化体系供应到环管反应器中以在环管反应器中形成聚合物浆料,并控制聚合物浆料的总量和/或从 通过调节通过第一出口排出的聚合物浆料与通过第二个出口排出的聚合物浆料的比例 tlet。