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    • 54. 发明申请
    • PROCESS FOR PRODUCING POLYPROPYLENE FROM C3 OLEFINS SELECTIVELY PRODUCED BY A TWO STAGE FLUID CATALYTIC CRACKING PROCESS
    • 通过两级液体催化裂化工艺选择性选择性生产C3烯烃的聚丙烯生产工艺
    • WO01064762A2
    • 2001-09-07
    • PCT/US2001/006686
    • 2001-03-01
    • C07C4/06C07B61/00C07C11/06C08F2/00C08F4/18C08F10/00C08F10/06C10G11/05C10G11/08C10G11/18C10G51/02C10G57/02
    • C10G57/02C10G51/026C10G2400/20
    • A process for producing polymers from olefins selectively produced by a two stage process for selectively producing C2 to C4 olefins from a gas oil or resid is disclosed herein. The gas oil or resid is reacted in a first stage comprising a fluid catalytic cracking unit wherein it is converted in the presence of conventional large pore zeolitic catalyst to reaction products, including a naphtha boiling range stream. The naphtha boiling range stream is introduced into a second stage comprising a process unit containing a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feed is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt.% of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500 to 650 DEG C and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone.
    • 本文公开了一种通过二级方法选择性制备聚合物的方法,用于从瓦斯油或渣油中选择性地生产C2至C4烯烃。 瓦斯油或渣油在包括流化催化裂化装置的第一阶段中反应,其中在常规大孔沸石催化剂存在下将其转化为包括石脑油沸程的反应产物。 将石脑油沸程流引入包含含有反应区,汽提区,催化剂再生区和分馏区的处理单元的第二阶段。 石脑油进料在反应区中与催化剂接触,所述催化剂在约500至650℃的反应条件和约500至650℃的反应条件下,含有约10至50重量%的平均孔径小于约0.7纳米的结晶沸石,以及 烃分压为约10至40psia。 蒸气产物被顶部收集,催化剂颗粒在通向催化剂再生区的途中通过汽提区。 挥发物在汽提区中用蒸汽汽提,并将催化剂颗粒送入催化剂再生区,其中焦炭从催化剂燃烧,然后再循环到反应区。
    • 57. 发明申请
    • MOLECULAR SIEVES OF FAUJASITE STRUCTURE
    • FAUJASITE结构的分子筛
    • WO01012546A1
    • 2001-02-22
    • PCT/EP2000/007797
    • 2000-08-11
    • B01J29/08C01B39/24C10G11/05C10G49/08
    • C10G11/05B01J29/084C01B39/24C10G49/08
    • A process for preparing molecular sieves of type Y faujasite structure is described, as well as pre-shaped bodies of faujasite structure type Y molecular sieves. The process comprises preparing a precursor gel from a source of silica-alumina or a source of alumina and a source of silica with a template agent at a SiO2/Al2O3 suitable for forming a type Y zeolite, drying the precursor gel and contacting the dried precursor gel with steam, optionally followed by caustic washing, without the formation of crystalline phases other than type Y zeolite being observed. Advantageously, the pre-shaped bodies prepared with the precursor gel of Y zeolite, when subjected to the process of the invention, will have their outer surface covered by type Y zeolite crystals in a non-homogenous distribution. The molecular sieves so obtained may be employed as catalysts or adsorbents in various processes of the chemical or oil industry.
    • 描述了制备Y型八面沸石结构的分子筛的方法,以及Y型分子筛的八面沸石结构体的预制体。 该方法包括从适合于形成Y型沸石的SiO 2 / Al 2 O 3由二氧化硅 - 氧化铝源或氧化铝源和二氧化硅源与模板剂制备前体凝胶,干燥前体凝胶并使干燥的前体 凝胶,任选地随后进行苛性洗涤,而不形成不同于Y型沸石的结晶相。 有利地,当用Y沸石的前体凝胶制备的预制体在进行本发明的方法时,其外表面将以不均匀的分布被Y型沸石晶体覆盖。 如此获得的分子筛可用作化学或石油工业的各种方法中的催化剂或吸附剂。
    • 60. 发明申请
    • PRODUCTION OF OLEFINS
    • 生产油脂
    • WO00078894A1
    • 2000-12-28
    • PCT/EP2000/005402
    • 2000-06-08
    • C10G55/06B01J29/40C07C4/06C10G11/04C10G11/05C10G51/06
    • C10G51/06B01J29/40B01J2229/16B01J2229/36C07C4/06C09K2019/546C10G11/05C10G2400/20C07C11/02
    • A process for cracking an olefin-containing hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a reactor containing a crystalline silicate selected from an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio of from 150 to 800 which has been subjected to a steaming step, at an inlet temperature of from 500 to 600 DEG C, at an olefin partial pressure of from 0.1 to 2 bars and the feedstock being passed over the catalyst at an LHSV of from 5 to 30h to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, wherein the olefin-containing hydrocarbon feedstock includes a C5-containing overhead cut from a first fractionator which has been fed with a C5+ hydrocarbon feedstock, the bottom fraction from the first fractionator being a C6+ cut and the C5+ hydrocarbon feedstock comprises a bottom fraction from a second fractionator which has been fed with a feedstock having at least C4+ hydrocarbons, and the overhead from the second fractionator comprises a C4 containing cut, optionally further containing C3 hydrocarbons.
    • 一种用于裂解对流出物中的轻质烯烃具有选择性的含烯烃的烃原料的方法,该方法包括使含有一种或多种烯烃的烃原料通过含有选自具有硅的MFI型结晶硅酸盐的结晶硅酸盐的反应器 /铝原子比为180以上的硅/铝原子比为150〜800的MEL型结晶硅酸盐,其入口温度为500〜600℃,进行了蒸汽工序, 烯烃分压为0.1至2巴,原料以5至30小时的LHSV通过催化剂以产生具有比原料低的分子量的烯烃含量的流出物,其中烯烃 的含烃原料包括来自已经进料有C5 +烃原料的第一分馏塔的含C5塔顶馏分,来自第一分馏塔 催化剂是C6 +馏分,并且C5 +烃原料包含来自第二分馏塔的塔底馏分,其中第二分馏塔已经供给具有至少C4 +烃的原料,并且来自第二分馏塔的塔顶馏出物包含含C4馏分,任选地还含有C 3烃。