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    • 55. 发明申请
    • DEMINERALIZATION OF COAL
    • 煤的脱矿化
    • WO1987005621A1
    • 1987-09-24
    • PCT/AU1987000080
    • 1987-03-23
    • COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ...WAUGH, Allan, BruceBOWLING, Keith, McGregor
    • COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ...
    • C10L09/02
    • C10L9/02
    • A process for demineralizing coal comprising the steps of: forming a slurry of coal particles, preferably at least 50% by weight of which particles have a maximum dimension of at least 0.5mm, with aqueous solutions of an alkali which solution has an alkali content of from 5 to 30% by weight, such that the slurry has an alkali solution to coal ratio on a weight basis of at least 1:1; maintaining the slurry at a temperature of from 150 DEG C to 300 DEG C, preferably 170 DEG C to 230 DEG C, for a period of from 2 to 20 minutes substantially under autogenous hydrothermal pressure and rapidly cooling the slurry to a temperature of less than 100 DEG C; separating the slurry into alkalize coal and a spent alkali leachant solution; regenerating the alkali leachant solution for reuse in step (a) above by the addition of calcium or magnesium oxide or hydroxide thereto to precipitate minerals therefrom; acidifying the alkalize coal by treatment with an aqueous solution of sulphuric or sulphurous acid to yield a slurry having a pH of from 0.5 to 1.5 and a conductivity of from 10,000 to 100,000 us; separating te slurry into acidified coal and a spent acid leachant solution; and washing the acidified coal.
    • 一种用于使煤脱矿的方法,包括以下步骤:用优选至少50重量%的颗粒的最大尺寸至少为0.5mm的煤颗粒形成浆料,该水溶液的碱含量为 5至30重量%,使得浆料的碱溶液与煤的重量比至少为1:1; 基本上在自生水热压力下将浆料保持在150℃至300℃,优选170℃至230℃的温度下2至20分钟的时间,并迅速将浆料冷却至小于 100℃; 将浆料分离成碱煤和废碱浸出剂溶液; 在上述步骤(a)中再生碱浸出剂溶液以通过加入钙或氧化镁或氢氧化物以从其中沉淀出矿物质; 通过用硫酸或亚硫酸的水溶液处理酸化碱化煤,得到pH为0.5至1.5,电导率为10,000至100,000 us的浆料; 将浆料分离成酸化煤和废酸浸出液; 并洗涤酸化的煤。