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41. 发明申请

WO2006107485A3 ALKYLATION PROCESS WITH CATALYST TRANSFER 审中-公开
标题翻译：具有催化转移的烷基化方法
公开(公告)号：WO2006107485A3
公开(公告)日：2007-10-11
申请号：PCT/US2006007860
申请日：2006-03-06
申请人： CONOCOPHILLIPS CO , HOVIS KEITH W , IQBAL KHALID , CRAGUN MARK R
发明人： HOVIS KEITH W , IQBAL KHALID , CRAGUN MARK R
IPC分类号： C07C2/64 , C07C15/067
CPC分类号： C07C2/62 , B01J19/2465 , B01J2219/00006 , B01J2219/00162
摘要： A system and/or process for alkylating hydrocarbons which includes an improved method of safely handling alkylation catalyst is disclosed. The process includes passing the alkylation catalyst from a settler vessel to a catalyst receiving vessel, via a catalyst cooler, for containment therein in the presence of a condensible gas. Also disclosed is a method for controlling the pressure in the catalyst receiving vessel by controlling the rate of removal of vapors.
摘要翻译：公开了一种用于烷基化烃的系统和/或方法，其包括安全处理烷基化催化剂的改进方法。该方法包括通过催化剂冷却器将烷基化催化剂从沉降器容器传递到催化剂接收容器，以便在可冷凝气体存在下容纳其中。还公开了一种通过控制蒸汽除去速率来控制催化剂接收容器中的压力的方法。

42. 发明申请

WO2007081923A2 ZEOLITIC TRANSALKYLATION WITH ALUMINUM CHLORIDE ALKYLATION 审中-公开
标题翻译：与氯化铝烷基化反应的ZEOLITIC TRANSALKYLATION
公开(公告)号：WO2007081923A2
公开(公告)日：2007-07-19
申请号：PCT/US2007000479
申请日：2007-01-08
申请人： FINA TECHNOLOGY , BUTLER JAMES R , CARY JEAN-BERNARD
发明人： BUTLER JAMES R , CARY JEAN-BERNARD
IPC分类号： C07C15/067 , B01J8/04 , C07C2/64
CPC分类号： C07C6/126 , B01J27/125 , B01J29/084 , B01J29/7007 , B01J2219/00006 , C07C2/68 , C07C2527/126 , C07C2529/08 , C07C2529/70 , C07C15/073
摘要： Alkylation processes are described herein. The alkylation process generally includes contacting a first aromatic compound with an alkylation catalyst including a metal halide catalyst in the presence of an alkylating agent to form an alkylation output stream including a second aromatic compound and contacting at least a portion of the output stream with a transalkylation catalyst including a zeolite catalyst in the presence of the first aromatic compound to form a transalkylation output stream including the second aromatic compound.
摘要翻译：烷基化方法在本文中描述。烷基化方法通常包括在烷基化剂存在下使第一芳族化合物与包含金属卤化物催化剂的烷基化催化剂接触以形成包含第二芳族化合物的烷基化输出物流，并将至少一部分输出物流与烷基转移反应催化剂，其包括在第一芳族化合物存在下的沸石催化剂以形成包含第二芳族化合物的烷基转移输出物流。

43. 发明申请

WO2007019375A2 ZEOLITE CATALYST AND METHOD OF PREPARING AND USE OF ZEOLITE CATALYST 审中-公开
标题翻译：沸石催化剂及其制备和使用沸石催化剂的方法
公开(公告)号：WO2007019375A2
公开(公告)日：2007-02-15
申请号：PCT/US2006/030582
申请日：2006-08-03
申请人： SAUDI BASIC INDUSTRIES CORPORATION , GHOSH, Ashim, Kumar , KULKARNI, Neeta , HARVEY, Pamela
发明人： GHOSH, Ashim, Kumar , KULKARNI, Neeta , HARVEY, Pamela
IPC分类号： C07C15/067
CPC分类号： B01J29/40 , B01J2229/18 , B01J2229/37 , B01J2229/42 , C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： A zeolite catalyst is prepared by treating a zeolite with a phosphorus compound to form a phosphorus-treated zeolite. The phosphorus-treated zeolite is heated to a temperature of about 3000C or higher and combined with an inorganic oxide binder material to form a zeolite-binder mixture. The zeolite-binder mixture is heated to a temperature of about 4000C or higher to form a bound zeolite catalyst. The bound zeolite may exhibit at least two 31P MAS NMR peaks with maxima at from about 0 to about -55 ppm, with at least one peak having a maximum at from about -40 to about -50 ppm. Zeolites containing 10-oxygen ring pores that have been prepared in such a way may be used in aromatic . alkylation by contacting the bound zeolite catalyst with an aromatic alkylation feed of an aromatic compound and an alkylating agent under reaction conditions suitable for aromatic alkylation.
摘要翻译：通过用磷化合物处理沸石以形成磷处理的沸石来制备沸石催化剂。将磷处理的沸石加热至约300℃或更高的温度，并与无机氧化物粘合剂材料组合以形成沸石 - 粘合剂混合物。将沸石 - 粘合剂混合物加热至约40℃或更高的温度以形成结合的沸石催化剂。结合的沸石可以显示至少两个具有约0至约-55ppm的最大值的31P MAS NMR峰，其中至少一个峰在约-40至约-50ppm处具有最大值。含有以这种方式制备的10-氧环孔的沸石可以用于芳族化合物。通过使结合的沸石催化剂与芳族化合物和烷基化剂的芳族烷基化进料在适于芳族烷基化的反应条件下接触进行烷基化。

44. 发明申请

WO02032837A1 PROCESS FOR PRODUCING OLEFINS FROM OXYGENATE 审中-公开
标题翻译：从氧化剂生产烯烃的方法
公开(公告)号：WO02032837A1
公开(公告)日：2002-04-25
申请号：PCT/US2001/029520
申请日：2001-09-21
IPC分类号： C07C1/20 , C07C2/86 , C07C15/073 , C07C15/08 , C07C15/067
CPC分类号： C07C2/865 , C07C1/20 , C07C2/864 , C07C15/073 , C07C15/08 , C07C2521/02 , C07C2521/08 , C07C2521/10 , C07C2527/16 , C07C2529/40 , C07C2529/65 , C07C2529/70 , C07C2529/85 , Y02P30/42
摘要： There is provided a process for converting methanol and/or dimethyl ether to a product containing olefin, e.g., C2 to C4 olefins, C9+ aromatics and non-C9+ aromatics which comprises: (1) contacting a feed which contains methanol and/or dimethyl ether with a catalyst comprising a porous crystalline material, said contacting step being conducted in the presence of aromatics comprising C9 or C9+ aromatic compound produced in said process under conversion conditions including a temperature of 350 DEG C to 480 DEG C and a methanol partial pressure in excess of 10 psia (70 kPa), said porous crystalline material having a Diffusion Parameter for 2,2-dimethylbutane of about 0.1 sec to about 20 sec when measured at a temperature of 120 DEG C and a 2,2-dimethylbutane pressure of 60 torr (8 kPa), and the aromatics being capable of alkylation by the methanol and/or dimethyl ether under said conversion conditions to provide a stream which contains C2 to C4 olefins and C9 or C9+ aromatic compound; (2) separating said stream to form a substantially C2 to C4 olefin product stream and a substantially C9 or C9+ aromatic compound stream; and 3) recycling at least a portion of said substantially C9 or C9+ aromatic compound stream to step (1).
摘要翻译：提供了一种将甲醇和/或二甲醚转化为含有烯烃的产物，例如C 2 -C 4烯烃，C 9+芳族化合物和非C 9+芳族化合物的方法，其包括：（1）使含有甲醇和/或二甲醚的进料所述接触步骤在包含C9或C9 +芳族化合物的芳族化合物存在下进行，所述芳族化合物在所述方法中产生的转化条件包括350℃至480℃的温度和超过甲醇的分压为10psia（70kPa），当在120℃的温度下测量时，所述多孔结晶材料具有约0.1秒-1至约20秒-1的2,2-二甲基丁烷的扩散参数和2 2-二甲基丁烷压力为60托（8kPa），并且芳族化合物能够在所述转化条件下由甲醇和/或二甲醚进行烷基化以提供含有C 2至C 4烯烃和C 9或C 9 +芳族化合物 ound; （2）分离所述物流以形成基本上C2至C4烯烃产物流和基本上C9或C9 +芳族化合物流; 和3）将至少一部分所述基本上C9或C9 +芳族化合物流再循环到步骤（1）。

45. 发明申请

WO00009263A1 L-TYPE ZEOLITE CATALYST COMPRISING PLATINUM, HALOGEN AND GROUP IB METAL 审中-公开
标题翻译：包含铂，卤素和IB族金属的L型沸石催化剂
公开(公告)号：WO00009263A1
公开(公告)日：2000-02-24
申请号：PCT/JP1999/004298
申请日：1999-08-09
IPC分类号： B01J29/61 , B01J29/62 , B01J29/63 , C07B61/00 , C07C5/41 , C07C15/04 , C07C15/067 , C10G35/09 , C10G35/095
CPC分类号： C10G35/095 , B01J29/62 , B01J2229/42 , C07C5/415 , C07C5/417 , C07C2523/52 , C07C2529/62
摘要： There are herein disclosed an L-type zeolite catalyst which is obtainable by supporting a platinum component, one or more halogen components and one or more metal components selected from the group Ib of the periodic table on an L-type zeolite, the support amount of one or more metal components selected from the group Ib being in the range of 0.001 to 3 % by weight based on the total weight of the catalyst in terms of the metal, a molar ratio of one or more metal components selected from the group Ib/platinum being in the range of 0.01 to 1; and a method for producing aromatic hydrocarbons or a gasoline having a high octane number which comprises the step of bringing one or more fractions selected from a C6 fraction, a C7 fraction and a C8 fraction into contact with this catalyst. According to the present invention, there are provided a catalyst containing an L-type zeolite as a carrier which is desirable as a catalyst for the production of aromatic hydrocarbons or a gasoline having a high octane number and which can inhibit a cracking activity and the formation of coke and can improve an aromatic selectivity and a liquid yield.
摘要翻译：本文公开了一种L型沸石催化剂，其可以通过在L型沸石上负载铂组分，一种或多种卤素组分和选自元素周期表第1b族中的一种或多种金属组分，其支撑量选自Ib族中的一种或多种金属组分的含量相对于催化剂的总重量为0.001至3重量％，以金属计，一种或多种选自Ib / 铂在0.01至1的范围内; 以及用于生产芳族烃或具有高辛烷值的汽油的方法，其包括使从C6馏分，C7馏分和C8 +馏分中选出的一种或多种馏分与该催化剂接触的步骤。根据本发明，提供了含有L型沸石作为载体的催化剂，作为用于制备芳族烃的催化剂或具有高辛烷值的汽油并且可以抑制裂化活性和形成的催化剂的焦炭，并且可以提高芳族选择性和液体产率。

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