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    • 50. 发明申请
    • CONDUCTING POLYMER SYNTHESIZED WITH PARTIALLY SUBSTITUTED POLYMERS AS A DOPANT
    • 与部分取代的聚合物合成的导电聚合物作为掺杂剂
    • WO2007013787A1
    • 2007-02-01
    • PCT/KR2006/003003
    • 2006-07-31
    • SUH, Kwang SuckKIM, Jong EunKIM, Tae Young
    • SUH, Kwang SuckKIM, Jong EunKIM, Tae Young
    • C08G73/02
    • C08G73/0266C08G61/124C08G61/126C08G2261/3223C08G2261/794C08L65/00H01B1/122C08L53/025
    • Disclosed herein is a method of synthesizing a conducting polymer using a polymer, having a substituent in a part thereof, as a dopant, in which a variety of polymers is substituted with a predetermined functional group to serve as a dopant such that the substituted functional group functions as the dopant of the conducting polymer, or a monomer having a substituent able to act as a dopant is copolymerized to prepare a polymer dopant having a substituent in a part thereof. The partially substituted polymer dopant used in this invention may serve as a dopant upon synthesis of the conducting polymer or upon additional doping of the synthesized polymer. Compared to a conventional monomer dopant, the polymer dopant does not emit low-molecular- weight material, and has higher solubility. Further, compared to a polymer dopant having a substituent such as a sulfonic acid group throughout, the synthesized conducting polymer can have superior mechanical properties and maximum conductivity amounting to 5 x 1 0"1 S/cm.
    • 本文公开了使用其部分中具有取代基的聚合物作为掺杂剂合成导电聚合物的方法,其中各种聚合物被预定官能团取代以用作掺杂剂,使得取代的官能团 作为导电性聚合物的掺杂剂或具有能够作为掺杂剂的取代基的单体进行共聚以制备其一部分具有取代基的聚合物掺杂剂。 用于本发明的部分取代的聚合物掺杂剂可以在合成导电聚合物时或在合成聚合物的额外掺杂时用作掺杂剂。 与常规单体掺杂剂相比,聚合物掺杂剂不会发射低分子量材料,并且具有较高的溶解度。 此外,与全部具有磺酸基的取代基的聚合物掺杂剂相比,合成的导电性聚合物可以具有优异的机械性能和最大导电率为5×10 11 S / cm 3。