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41. 发明申请

WO2002100633A1 防曇素子及びその形成方法审中-公开
标题翻译：抗微生物元件及其形成方法
公开(公告)号：WO2002100633A1
公开(公告)日：2002-12-19
申请号：PCT/JP2001/004907
申请日：2001-06-11
申请人：株式会社村上開明堂 , 小林正樹 , 葛谷典彦
发明人：小林正樹 , 葛谷典彦
IPC分类号： B32B9/00
CPC分类号： B01J21/063 , A47G1/02 , B01J35/004 , C03C17/3411 , C03C17/3417 , C03C2217/425 , C03C2217/71 , C09D1/00 , G02B1/105 , G02B1/18
摘要： An antifogging element having a substrate, a film of a substance having a photocatalyst function formed on the surface thereof and, formed thereon so as to have porosity, a hydrophilic substance film and a method for forming the antifogging element, wherein the substance having a photocatalyst function is prepared from a titanium peroxide solution which can be obtained by reacting a titanium hydroxide gel (orthotitanic acid) with hydrogen peroxide. The use of a titanium peroxide solution for forming a film of a substance having a photocatalyst function allows the preparation of anatase−type titanium dioxide at a low treatment temperature, for example, of 200 ˚, which results in a fact that an alkali component in a glass substrate is less prone to diffuse into the film of a substance having a photocatalyst function during the formation of the anti−fogging element, leading to an advantage that a film for preventing the diffusion of an alkali is not required and the photocatalytic activity due to the absence of a film for preventing the diffusion of an alkali is not observed even when a soda−lime glass is used as the substrate. The low treatment temperature results also in energy savings and in shortening a cycle time, leading to further reduction in the production cost of an antifogging element.
摘要翻译：具有基材的防雾元件，在其表面上形成有光催化功能的物质的膜，并且在其上形成具有孔隙率的亲水性物质膜和形成防雾元件的方法，其中具有光催化剂的物质功能是由可以通过氢氧化钛凝胶（原钛酸）与过氧化氢反应获得的二氧化钛溶液制备的。通过使用二氧化钛溶液形成具有光催化剂功能的物质的膜，可以在200℃的低处理温度下制备锐钛矿型二氧化钛，这导致以下事实：在防雾元件形成期间，玻璃基板不太容易扩散到具有光催化剂功能的物质的膜中，从而具有不需要用于防止碱扩散的膜和光催化活性的优点即使使用钠钙玻璃作为基材，也没有观察到不存在用于防止碱扩散的膜。低处理温度也导致能量节省并缩短了循环时间，从而进一步降低了防雾元件的生产成本。

42. 发明申请

WO02006159A1 TITANIUM-CONTAINING MATERIALS 审中-公开
标题翻译：含钛材料
公开(公告)号：WO02006159A1
公开(公告)日：2002-01-24
申请号：PCT/NZ2001/000144
申请日：2001-07-17
IPC分类号： C01G23/00 , B01J21/06 , B01J23/42 , B01J23/50 , B01J35/00 , C01G23/053 , C03C17/25 , C04B35/46 , C04B35/624
CPC分类号： B82Y30/00 , B01J21/063 , B01J23/42 , B01J23/50 , B01J35/004 , C01G23/053 , C01P2002/72 , C01P2002/82 , C01P2002/88 , C01P2004/03 , C01P2004/84 , C01P2006/12 , C03C17/256 , C03C2204/02 , C03C2217/212 , C03C2217/213 , C03C2217/23 , C03C2217/71 , C04B35/46 , C04B35/624 , C04B2235/3231 , C04B2235/3232 , C04B2235/3281 , C04B2235/3418 , C04B2235/5454 , C04B2235/549
摘要： The invention relates to a method of preparing a solution containing particles which contain titanium ions wherein one or more hydrolysable titanium-containing compound(s) is stabilised by oxalic acid in a reaction medium. The reaction further relates to the preparation of titania materials (including particulate materials, coating solutions and films) which comprise or include anatase phase titania, and so are suitable in photocatalytic applications. The invention also deals with a method of preparing B-phase titania.
摘要翻译：本发明涉及一种制备含有钛离子的颗粒的溶液的方法，其中一种或多种可水解的含钛化合物在反应介质中被草酸稳定。该反应还涉及二氧化钛材料（包括颗粒材料，涂层溶液和薄膜）的制备，其包含或包括锐钛矿相二氧化钛，因此适用于光催化应用。本发明还涉及一种制备B相二氧化钛的方法。

43. 发明申请

WO00023528A1 STAINPROOF MATERIAL AND METHOD FOR MANUFACTURING THE SAME, AND COATING COMPOSITION AND APPARATUS THEREFOR 审中-公开
标题翻译：防锈材料及其制造方法及其涂料组合物及其装置
公开(公告)号：WO00023528A1
公开(公告)日：2000-04-27
申请号：PCT/JP1999/005766
申请日：1999-10-19
IPC分类号： B01J35/00 , B01J37/02 , C03C10/10 , C03C17/23 , C04B41/50 , C04B41/87 , C09D1/00 , C23C30/00 , C09D5/00
CPC分类号： C04B41/87 , B01J35/002 , B01J35/004 , B01J37/0215 , C03C17/23 , C03C2217/212 , C03C2217/229 , C03C2217/71 , C03C2218/32 , C04B41/5041 , C09D1/00 , C23C30/00 , Y10T428/25 , Y10T428/31678
摘要： A stainproof material which comprises a substrate and an inorganic film consisting substantially of a noncrystalline metal oxide, wherein the inorganic film contains an alkali metal and non-bridging oxygen in an amount effective to clean only by washing with water stains deposited on the surface thereof by an exhaust gas to such an extent as to recover a diffuse reflectance by 75 % or more and is fixed on the uppermost layer of the stainproof material; and a method for manufacturing the same; and a coating composition and an apparatus therefor. This stainproof material is excellent in resistance to stains in the surface of an article especially to those containing oily substances.
摘要翻译：一种防污材料，其包含基材和基本上由非结晶性金属氧化物组成的无机膜，其中所述无机膜包含碱金属和非桥连氧，所述碱金属和非桥连氧只有通过用表面上沉积的水渍进行清洗才能清洁废气到使漫反射率恢复75％以上并被固定在防污材料的最上层的程度; 及其制造方法。和涂料组合物及其装置。该防污材料对于制品表面的耐污性优异，特别是含有油性物质的物品。

44. 发明申请

WO99064357A1 APPARATUS FOR PHOTOCATALYTIC REACTION WITH AND METHOD FOR FIXING PHOTOCATALYST 审中-公开
标题翻译：用于光化学反应的装置和固定光催化剂的方法
公开(公告)号：WO99064357A1
公开(公告)日：1999-12-16
申请号：PCT/JP1999/003049
申请日：1999-06-07
IPC分类号： B01J21/06 , B01J35/00 , B01J37/02 , C02F1/30 , C02F1/32 , C02F1/72 , C03C17/00 , C03C17/25 , B01J35/02
CPC分类号： C02F1/32 , B01J21/063 , B01J35/002 , B01J35/004 , B01J37/0228 , C02F1/725 , C02F2101/16 , C02F2101/30 , C02F2305/10 , C03C17/007 , C03C17/256 , C03C2217/42 , C03C2217/71 , Y02W10/37
摘要： (1) A method which comprises fixing (coating) a photocatalyst on the surface of a support, and feeding continuously a thin film of a liquid to be treated to the surface of the fixed photocatalyst in a gaseous atmosphere and at the same time irradiating a light capable of causing a photocatalytic reaction toward the photocatalyst surface; and (2) a method for fixing a photocatalyst on a support using an alkali metal silicate as a binding agent which comprises a first step of coating an aqueous solution of an alkali metal silicate on a support to fix the silicate, a second step of coating, after the first step, a photocatalyst in a powder form on the above alkali metal silicate to fix the photocatalyst, and a third step of curing, after the second step, the above coated and fixed material. According to the above methods, an apparatus for a photocatalytic reaction can be provided which exhibits a high treatment efficiency and shows no reduction of treating ability even after the elapse of a long period of operating time can be provided, and a photocatalyst can be fixed with ease and efficiency.
摘要翻译：（1）一种方法，其包括将光催化剂固定（涂布）在支撑体的表面上，并将待处理液体的薄膜在气态气氛中连续供给到固定光催化剂的表面，并同时照射能够向光催化剂表面引起光催化反应的光; 和（2）使用碱金属硅酸盐作为粘合剂将光催化剂固定在载体上的方法，该方法包括在载体上涂覆碱金属硅酸盐水溶液以固定硅酸盐的第一步骤，第二步涂布在第一步骤之后，在上述碱金属硅酸盐上形成粉末形式的光催化剂以固定光催化剂，以及在第二步骤之后固化上述涂覆和固定的材料的第三步骤。根据上述方法，可以提供一种光催化反应装置，其表现出高的处理效率，即使经过长时间的操作时间也不会降低处理能力，光催化剂可以用轻松和高效。

45. 发明申请

WO9700134A8 PHOTOCATALYST-CARRYING STRUCTURE AND PHOTOCATALYST COATING MATERIAL 审中-公开
标题翻译：光催化运载结构和光催化涂层材料
公开(公告)号：WO9700134A8
公开(公告)日：1999-04-01
申请号：PCT/JP9601669
申请日：1996-06-18
申请人： NIPPON SODA CO , KIMURA NOBUO , ABE SHINJI , YOSHIMOTO TETSUO , FUKAYAMA SHIGEMICHI
发明人： KIMURA NOBUO , ABE SHINJI , YOSHIMOTO TETSUO , FUKAYAMA SHIGEMICHI
IPC分类号： B01J35/00 , B01J37/02 , B01J37/03 , C03C17/42 , B01J35/02
CPC分类号： B01J37/036 , B01J35/002 , B01J35/004 , B01J37/0219 , B01J37/0225 , C03C17/42 , C03C2217/445 , C03C2217/45 , C03C2217/477 , C03C2217/478 , C03C2217/71 , Y10T428/256 , Y10T428/257 , Y10T428/258 , Y10T428/259 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： A photocatalyst-carrying structure comprising a photocatalyst layer, a carrier and an adhesive layer present between the photocatalyst layer and the carrier, wherein the adhesive layer is made of a silicon-modified resin, a polysiloxane-containing resin or a colloidal silica-containing resin and the photocatalyst layer is made of a composite comprising a metal oxide or hydroxide gel and a photocatalyst; and a photocatalytic coating material for producing the above structure, comprising a silicon compound, at least one metal oxide or metal hydroxide sol, and at least one photocatalyst powder or sol.
摘要翻译：一种光催化剂载体结构，其包含存在于光催化剂层和载体之间的光催化剂层，载体和粘合剂层，其中粘合剂层由硅改性树脂，含聚硅氧烷的树脂或含胶体二氧化硅的树脂光催化剂层由包含金属氧化物或氢氧化物凝胶和光催化剂的复合材料制成; 以及用于制造上述结构的光催化涂层材料，其包含硅化合物，至少一种金属氧化物或金属氢氧化物溶胶，以及至少一种光催化剂粉末或溶胶。

46. 发明申请

WO1998025700A1 PHOTOCATALYST, LIGHT SOURCE AND LIGHTING DEVICE 审中-公开
标题翻译：光源，光源和照明设备
公开(公告)号：WO1998025700A1
公开(公告)日：1998-06-18
申请号：PCT/JP1997002828
申请日：1997-08-13
申请人： TOSHIBA LIGHTING & TECHNOLOGY CORPORATION , NIHON DORO KODAN-JAPAN HIGHWAY PUBLIC CORPORATION , SOMA, Ryuji , HONDA, Hisashi , ISHIZAKI, Ariyoshi , WATANABE, Tsutomu , KAMATA, Hiroshi , SAITOU, Akiko , ENDOU, Akimasa
发明人： TOSHIBA LIGHTING & TECHNOLOGY CORPORATION , NIHON DORO KODAN-JAPAN HIGHWAY PUBLIC CORPORATION
IPC分类号： B01J35/02
CPC分类号： B01J21/063 , B01J35/002 , B01J35/004 , B01J35/023 , C03C17/256 , C03C17/3417 , C03C2217/71 , C03C2218/111 , C03C2218/113 , C03C2218/365 , F21V3/04 , H01J61/35 , H01K1/32
摘要： A light-transmitting cover (9) is so provided as to cover a high voltage sodium lamp (11) which emits at least visible light and light whose wavelength ranges 300 nm - 400 nm. A photocatalyst film (13) is so formed at least on one of the inner and outer surfaces of the light-transmitting cover (9) in such a way that the visible light does not interfere with each other. The main component of the material of the photocatalyst film (13) is titania (TiO2) whose visible light transmissivity has its peak at a wavelength approximately equal to the peak wavelength of the visible light of the high voltage sodium lamp (11). Oxidation and decomposition of substances are accelerated by ultraviolet radiation emitted by the high voltage sodium lamp (11) with the photocatalyst film (13), and contamination of the light-transmitting cover (9) is avoided. Even if the thickness of the photocatalyst film (13) is increased in order to improve the photocatalytic action, the peak wavelength of visible light emitted by the high voltage sodium lamp (11) is transmitted through the photocatalyst film (13) efficiently and the degradation of the lighting efficiency is suppressed.
摘要翻译：透光罩（9）设置成覆盖至少发射可见光的高压钠灯（11），波长范围为300nm〜400nm。光透过膜（9）的内表面和外表面的至少一个上以可见光不彼此干涉的方式形成光催化剂膜（13）。光催化膜（13）的材料的主要成分是氧化钛（TiO 2），其可见光透过率在与高压钠灯（11）的可见光的峰值波长大致相等的波长处具有峰值。通过高电压钠灯（11）与光催化膜（13）发射的紫外线辐射物质的氧化和分解加速，避免了透光罩（9）的污染。即使光催化剂膜（13）的厚度增加以改善光催化作用，高压钠灯（11）发射的可见光的峰值波长也有效地透过光催化膜（13）并降解的照明效率被抑制。

47. 发明申请

WO1998003607A1 PHOTOCATALYTIC HYDROPHILIC COATING COMPOSITION 审中-公开
标题翻译：光化学水解涂料组合物
公开(公告)号：WO1998003607A1
公开(公告)日：1998-01-29
申请号：PCT/JP1997002467
申请日：1997-07-16
申请人： TOTO LTD. , HAYAKAWA, Makoto , KANNO, Mitsuyoshi
发明人： TOTO LTD.
IPC分类号： C09K03/18
CPC分类号： C09D5/021 , B01J31/0272 , B01J35/002 , B01J35/004 , B01J37/0219 , C03C17/007 , C03C2217/45 , C03C2217/477 , C03C2217/478 , C03C2217/71 , C03C2217/75 , C09D1/00 , C09D5/00 , C09D183/02 , C09D183/04 , F21S41/37 , F21V7/22 , C08L2666/54
摘要： A composition which can make the surface of a member hydrophilic to impart anti-fogging properties thereto. This composition comprises (a) photocatalyst particles made of a metal oxide, (b) at least one component selected from the group consisting of particulate silica, precursors capable of forming silicone resin films, and precursors capable of forming silica films, and (c) a solvent, with the total content of solid components of the components (a) and (b) in the composition being 0.01 to 5 % by weight. The composition can impart hydrophilicity to a member by an extremely simple means of applying the composition to the member and drying or heating it. The hydrophilic thin film thus formed is transparent and therefore does not impair the transparency and appearance of the member, even when the member is essentially required to be transparent. The surface of a member having a film formed from the composition thereon has properties such that waterdrops adhering to the surface are immediately evaporated and that the surface is little stained and can be easily rid of stains even if stained.
摘要翻译：可以使构件的表面具有亲水性赋予防雾性的组合物。该组合物包含（a）由金属氧化物制成的光催化剂颗粒，（b）至少一种选自颗粒二氧化硅，能够形成有机硅树脂膜的前体和能够形成二氧化硅膜的前体的组分，和（c）溶剂，组合物中组分（a）和（b）的固体组分的总含量为0.01至5重量％。组合物可以通过将组合物施加到构件上并将其干燥或加热的极其简单的方法赋予构件亲水性。这样形成的亲水性薄膜是透明的，因此即使当该部件基本上是透明的时，也不会损害部件的透明度和外观。具有由其组合物形成的膜的部件的表面具有使表面附着的水滴立即蒸发，并且表面几乎被污染并且即使染色也容易除去污渍的性质。

48. 发明申请

WO1997023572A1 PHOTOCATALYTIC PROCESS FOR MAKING SURFACE HYDROPHILIC AND COMPOSITE MATERIAL HAVING PHOTOCATALYTICALLY HYDROPHILIC SURFACE 审中-公开
标题翻译：用于制备具有光催化表面活性剂的表面亲水和复合材料的光致变色工艺
公开(公告)号：WO1997023572A1
公开(公告)日：1997-07-03
申请号：PCT/JP1996003684
申请日：1996-12-18
申请人： TOTO LTD. , HAYAKAWA, Makoto , KOJIMA, Eiichi , NORIMOTO, Keiichiro , MACHIDA, Mitsuyoshi , KITAMURA, Atsushi , WATANABE, Toshiya , CHIKUNI, Makoto , FUJISHIMA, Akira , HASHIMOTO, Kazuhito
发明人： TOTO LTD.
IPC分类号： C09D05/00
CPC分类号： G02B1/18 , C03C17/23 , C03C17/256 , C03C17/3417 , C03C2217/212 , C03C2217/71 , C03C2218/113 , C03C2218/32 , C09K3/18 , G02B1/105
摘要： A process of making the surface of a substrate hydrophilic by photocatalysis. A substrate is covered with a photocatalytic titania coating (10) which carries on its surface a solid acid increasing the hydrogen bond component ( gamma s ) of the surface energy at the solid-liquid boundary. On photoexcitation of the photocatalyst, the hydrogen bond component ( gamma s ) is increased by photocatalysis to thereby accelerate the physical adsorption of atmospheric water molecules on the hydrogen atoms of terminal OH groups (12) bonded to titanium atoms present on the surface and bridging OH groups (14) through hydrogen bonds (16). As a result of the adsorption, a high-density physically adsorbed water layer (18) is formed on the surface of the photocatalytic coating (10) to thereby facilitate making the surface hydrophilic. This process is effective in the protection of articles from fogging or staining and the (self)cleaning of articles.
摘要翻译：通过光催化使基材表面亲水的方法。用光催化二氧化钛涂层（10）覆盖基底，其上表面具有增加固液界面处的表面能的氢键分量（γs ）的固体酸。在光催化剂的光激发下，通过光催化增加氢键成分（γs h），从而加速大气水分子在与表面上存在的钛原子键合的末端OH基团（12）的氢原子上的物理吸附并通过氢键桥接OH基团（14）（16）。作为吸附的结果，在光催化涂层（10）的表面上形成高密度物理吸附水层（18），从而有助于使表面亲水。这个过程对物品防止起雾或染色以及物品的（自）清洁是有效的。

49. 发明申请

WO1997000134A1 PHOTOCATALYST-CARRYING STRUCTURE AND PHOTOCATALYST COATING MATERIAL 审中-公开
标题翻译：光催化运载结构和光催化涂层材料
公开(公告)号：WO1997000134A1
公开(公告)日：1997-01-03
申请号：PCT/JP1996001669
申请日：1996-06-18
申请人： NIPPON SODA CO., LTD. , KIMURA, Nobuo , ABE, Shinji , YOSHIMOTO, Tetsuo , FUKAYAMA, Shigemichi
发明人： NIPPON SODA CO., LTD.
IPC分类号： B01J35/02
CPC分类号： B01J37/036 , B01J35/002 , B01J35/004 , B01J37/0219 , B01J37/0225 , C03C17/42 , C03C2217/445 , C03C2217/45 , C03C2217/477 , C03C2217/478 , C03C2217/71 , Y10T428/256 , Y10T428/257 , Y10T428/258 , Y10T428/259 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： A photocatalyst-carrying structure comprising a photocatalyst layer, a carrier and an adhesive layer present between the photocatalyst layer and the carrier, wherein the adhesive layer is made of a silicon-modified resin, a polysiloxane-containing resin or a colloidal silica-containing resin and the photocatalyst layer is made of a composite comprising a metal oxide or hydroxide gel and a photocatalyst; and a photocatalytic coating material for producing the above structure, comprising a silicon compound, at least one metal oxide or metal hydroxide sol, and at least one photocatalyst powder or sol.
摘要翻译：一种光催化剂载体结构，其包含存在于光催化剂层和载体之间的光催化剂层，载体和粘合剂层，其中粘合剂层由硅改性树脂，含聚硅氧烷的树脂或含胶体二氧化硅的树脂光催化剂层由包含金属氧化物或氢氧化物凝胶和光催化剂的复合材料制成; 以及用于制造上述结构的光催化涂层材料，其包含硅化合物，至少一种金属氧化物或金属氢氧化物溶胶，以及至少一种光催化剂粉末或溶胶。

50. 发明申请

WO1995011751A1 PHOTOCATALYST-BINDER COMPOSITIONS 审中-公开
标题翻译：光催化淀粉组合物
公开(公告)号：WO1995011751A1
公开(公告)日：1995-05-04
申请号：PCT/US1994012185
申请日：1994-10-21
申请人： E. HELLER & COMPANY
发明人： E. HELLER & COMPANY , HELLER, Ephraim , HELLER, Adam , PISHKO, Michael, V.
IPC分类号： B01J21/06
CPC分类号： B01J35/004 , B01J35/002 , B01J37/0215 , C02F1/32 , C02F1/725 , C02F2305/10 , C03C17/007 , C03C2217/45 , C03C2217/475 , C03C2217/71
摘要： A photocatalytic composition containing a substantially non-oxidizable binder, such as silicone, which allows large amounts of photocatalytic particles, such as titanium dioxide or zinc oxide, t o be adhered to a surface. Upon application to a surface, the composition dries or cures to form an adherent, abrasion-resistant, thermostable photocatalytic coating. The binder transmits a substantial proportion of incident ultraviolet light to activate the photocatalytic particles to produce a cleaning effect. The binder, preferably polysilicone, renders the surface hydrophobic. The coated surface can be used to degrade organic contaminants in air or in an aqueous stream, and can act as a biocidal agent under the application of ultraviolet light. When an organic reaction is to be catalyzed under the ultraviolet light, such coated particulate materials can be used as photocatalysts in a fluidized bed reactor, or a packed bed reactor. The photocatalytic composition is used in a photoreactor (14) containing a packed bed (6) packed with glass spheres (2), optionally with a silicone coating only at the points of contact (4), within a conduit (8) which surrounds a source of ultraviolet light (10). Preferably a silicone film (12) is placed between the conduit (8) and the glass spheres.
摘要翻译：包含基本上不可氧化的粘合剂如硅氧烷的光催化组合物，其允许大量的光催化颗粒如二氧化钛或氧化锌粘附到表面。当施用于表面时，组合物干燥或固化以形成粘附的耐磨损的热稳定的光催化涂层。粘合剂传输相当大比例的入射紫外光以活化光催化颗粒以产生清洁效果。粘合剂，优选多硅氧烷，使表面疏水。涂覆表面可用于降解空气或水流中的有机污染物，并可在紫外线下作为杀生物剂。当有机反应在紫外光下催化时，这种涂覆的颗粒物质可以用作流化床反应器或填充床反应器中的光催化剂。光催化组合物用于含有填充有玻璃球（2）的填充床（6）的光反应器（14），任选地仅在接触点（4）处的硅氧烷涂层内，在围绕着紫外光源（10）。优选地，硅胶膜（12）被放置在导管（8）和玻璃球之间。

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