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    • 43. 发明申请
    • POLYPROPYLENE COMPOSITIONS CONTAINING GLASS FIBER FILLERS
    • 包含玻璃纤维填料的聚丙烯组合物
    • WO2015000738A1
    • 2015-01-08
    • PCT/EP2014/063236
    • 2014-06-24
    • BASELL POLIOLEFINE ITALIA S.R.L.
    • KÖHLER, RainerGRAZZI, MicheleROHRMANN, JürgenPELLEGATTI, Giampaolo
    • C08L23/00B29C45/00
    • C08L23/14C08K7/14C08L23/0815C08L23/10C08L23/16C08L51/06C08L2205/02C08L2205/025
    • Composition comprising (A) from 30 to 60 by weight, of a soft polyolefin composition comprising, 10-50 % by weight of a copolymer (a) of propylene, which copolymer contains from 1 to 8 % of comonomer content; 50-90 wt % of a copolymer (b) of ethylene and other alpha-olefin(s), containing from 57 to 80 % of ethylene; wherein the weight ratio of the content of copolymer component (b) to the fraction XS soluble in xylene at room temperature (about 25 °C), both (b and XS) referred to the total weight of (a) + (b), is of 1.5 or less, and the intrinsic viscosity [η] of the said XS fraction is of 3 dl/g or more; and the total quantity of copolymerized ethylene is preferably from 30 % to 65 % by weight; (B) from 5 to 30 wt % of a glass fiber filler; (C) from 0 to 5 % by weight of a compatibilizer; (D) from 10 to 40 by weight of a polypropylene component selected from propylene homopolymers, propylene copolymers containing up to 5 % by moles of ethylene and/or C 4 -C 10 α-olefin(s) and combinations of such homopolymers and copolymers, wherein the Melt Flow Rate, of the polypropylene component D) is generally from 0.3 to 2500 g/10 min.
    • 组合物,其包含(A)30至60重量%的软质聚烯烃组合物,其包含10-50重量%的丙烯共聚物(a),该共聚物含有1至8重量%的共聚单体含量; 50-90重量%的乙烯和其它α-烯烃的共聚物(b),其含有57-80%的乙烯; 其中共聚物组分(b)的含量与在室温(约25℃)下可溶于二甲苯的级分XS的重量比(b和XS)以(a)+(b)的总重量计, 为1.5以下,所述XS馏分的特性粘度[ηe]为3dl / g以上, 共聚乙烯的总量优选为30〜65重量%。 (B)5〜30重量%的玻璃纤维填料; (C)0〜5重量%的增容剂; (D)10至40重量份的选自丙烯均聚物的聚丙烯组分,含有至多5摩尔%乙烯和/或C 4 -C 10α-烯烃的丙烯共聚物以及这些均聚物和共聚物的组合,其中 聚丙烯组分D)的熔体流动速率通常为0.3至2500g / 10min。
    • 44. 发明申请
    • PROPYLENE-BASED TERPOLYMERS COMPOSITION FOR PIPES
    • 用于管道的丙烯基聚合物组合物
    • WO2013083617A1
    • 2013-06-13
    • PCT/EP2012/074477
    • 2012-12-05
    • BASELL POLIOLEFINE ITALIA S.R.L.
    • GALVAN, MonicaPELLEGATTI, GiampaoloTERWYEN, HerbertCAVALIERI, Claudio
    • C08L23/14B32B1/08F16L9/12B32B27/32
    • C08L23/18B32B1/08B32B27/32B32B2597/00C08L23/14C08L23/142C08L2203/18C08L2205/025C08L2207/02F16L9/127Y10T428/139Y10T428/1393C08L23/12
    • A polyolefin composition comprising: A) from 85.0 wt% to 99.5 wt%; A terpolymer containing propylene, ethylene and 1- hexene wherein: (i) the content of 1-hexene derived units ranges from 1.0 wt% to 5.0%; (ii) the content of ethylene derived units is comprised between 0.5 wt% and 10.0 wt% (iii) the melting temperature ranges from 130° C to 145° C; B) from 0.5 wt% to 10.0 wt%; of a propylene, ethylene copolymer composition comprising: b1) from 12 wt% to 52 wt%; of a propylene homopolymer or a propylene/ethylene copolymer having a content of ethylene derived units ranging from 0.1 wt% to 4.5 wt%; and having a xylene soluble content measured at 25°C lower than 10 wt%; b2) from 48 wt% to 88 wt% of a propylene ethylene copolymer having a content of ethylene derived units ranging from 15.0 wt% to wt% to 42.0 wt%; wherein the resulting polyolefin composition has an melt flow rate (230°C/5 kg..ISO 133) ranging from 0.2 g/10min to 4.0 g/10min; the sum A+B being 100 and the sum b1+b2 being 100.
    • 一种聚烯烃组合物,其包含:A)85.0重量%至99.5重量%; 含有丙烯,乙烯和1-己烯的三元共聚物,其中:(i)1-己烯衍生单元的含量为1.0wt%至5.0%; (ii)乙烯衍生单元的含量为0.5重量%至10.0重量%之间(iii)熔融温度为130℃至145℃; B)为0.5重量%〜10.0重量% 的丙烯,乙烯共聚物组合物,其包含:b1)12重量%至52重量%; 的丙烯均聚物或丙烯/乙烯共聚物,其乙烯衍生单元的含量范围为0.1重量%至4.5重量%; 并且在25℃下测量的二甲苯可溶物含量低于10重量%; b2)为48重量%至88重量%的乙烯衍生单元含量为15.0重量%至42重量%的丙烯乙烯共聚物; 其中所得的聚烯烃组合物具有0.2g / 10min至4.0g / 10min范围内的熔体流动速率(230℃/ 5kg.ISO 133) 总和A + B为100,总和b1 + b2为100。
    • 49. 发明申请
    • POLYPROPYLENE COMPOSITION
    • 聚丙烯组合物
    • WO2005044911A1
    • 2005-05-19
    • PCT/IB2004/003584
    • 2004-11-03
    • BASELL POLIOLEFINE ITALIA S.p.A.BERTA, Dominic, A.PELLEGATTI, Giampaolo
    • BERTA, Dominic, A.PELLEGATTI, Giampaolo
    • C08L23/10
    • C08L23/10C08L23/0815C08L23/14C08L23/16C08L2205/02C08L2205/03C08L2666/04C08L2666/02
    • A propylene polymer composition comprising the following components: a) from 50% to 90% by weight of a propylene homopolymer or a propylene copolymer containing up to 5% by mol of derived units of C2-C20 alpha-olefins, having the following features: (i) a polydispersity index PI>3; (ii) melt flow rate (MFR), as measured at 230°C under a load of 2.16 kg, MFR>1 dg/min; and (iii) fraction soluble in xylene at 25°C (XSRT)>1% b) from 5% to 25% by weight a copolymer of ethylene and one or more derived units of C4-C20 alpha-olefins having the following features: (i) content of ethylene derived units higher than 50% by mol and lower than 92% by mol; (ii) intrinsic viscosity (IV) higher than 1.2 dL/g and lower than 6 dL/g; (iii) density ranging from 0.850 to 0.890 g/cm 3 ; and (iv) a crystallinity content, expressed as the enthalpy of fusion, lower than 62 J/g c) from 5% to 25% by weight of a copolymer of propylene and ethylene having the following features: (i) content of propylene derived units higher than 50% by mol and lower than 92% by mol; (ii) intrinsic viscosity (IV) higher than 2 dL/g and lower than 6 dL/g; (iii) density ranging from 0.850 to 0.890 g/cm3; (iv) the value of the product of reactivity ratios rlxr2 lower than 2; and (v) a crystallinity content, expressed as the enthalpy of fusion, lower than 45 J/g wherein the weight ratio between the ethylene copolymer (component b) and the sum of component b) and component c) is equal to or higher than 0.5 and less than or equal to 0.9.
    • 包含以下组分的丙烯聚合物组合物:a)50重量%至90重量%的丙烯均聚物或含有至多5摩尔%的C2-C20α-烯烃衍生单元的丙烯共聚物,具有以下特征: (i)多分散指数PI> 3; (ii)熔体流动速率(MFR),在230℃,2.16kg负荷下测量,MFR> 1dg / min; 和(iii)25℃下可溶于二甲苯的馏分(XSRT)> 1%b)5重量%至25重量%的乙烯与一种或多种C4-C20α-烯烃衍生单元的共聚物具有以下特征: (i)乙烯衍生单元含量高于50摩尔%且低于92摩尔% (ii)高于1.2dL / g且小于6dL / g的特性粘度(Ⅳ); (iii)密度范围为0.850至0.890g / cm 3; 丙烯和乙烯的共聚物的重量比为5%至25%,具有以下特征:(i)丙烯衍生单元的含量 高于50摩尔%,低于92摩尔% (ii)高于2dL / g且低于6dL / g的特性粘度(IV); (iii)密度范围为0.850至0.890g / cm3; (iv)反应性比率rlxr2的值低于2的值; 和(v)以熔融焓表示的结晶度含量低于45J / g,其中乙烯共聚物(组分b)与组分b)和组分c)之和的重量比等于或高于 0.5且小于或等于0.9。