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41. 发明申请

WO2009021036A3 FLAME RETARDED FLEXIBLE POLYURETHANE FOAMS AND FLEXIBLE POLYURETHANE FOAM FORMULATIONS 审中-公开
公开(公告)号：WO2009021036A3
公开(公告)日：2009-02-12
申请号：PCT/US2008/072333
申请日：2008-08-06
申请人： ALBEMARLE CORPORATION , CHEW, Hoover, B. , JOSHI, Ravindra, R. , MACK, Arthur, G.
发明人： CHEW, Hoover, B. , JOSHI, Ravindra, R. , MACK, Arthur, G.
IPC分类号： C08K5/521 , C08K5/527
摘要： The present invention relates to flame retarded flexible polyurethane foam formulations, flame retardant additives suitable for use therein, and flame retarded foams made therefrom.

42. 发明申请

WO2009021035A1 FLAME RETARDED RIGID POLYURETHANE FOAMS AND RIGID POLYURETHANE FOAM FORMULATIONS 审中-公开
标题翻译：阻燃刚性聚氨酯泡沫塑料和刚性聚氨酯泡沫配方
公开(公告)号：WO2009021035A1
公开(公告)日：2009-02-12
申请号：PCT/US2008/072331
申请日：2008-08-06
申请人： ALBEMARLE CORPORATION , CHEW, Hoover, B. , JOSHI, Ravindra, R. , MACK, Arthur, G. , IBAY, Augusto
发明人： CHEW, Hoover, B. , JOSHI, Ravindra, R. , MACK, Arthur, G. , IBAY, Augusto
IPC分类号： C08J9/00 , C08K5/521 , C08K5/523 , C08K5/5357 , C08G101/00
CPC分类号： C08G18/4018 , C08G2101/0025 , C08G2101/005 , C08J9/0038 , C08J2375/04 , C08K5/005 , C08K5/51 , C08K5/523 , C08K2201/014 , C08L75/04 , C08L75/00
摘要： The present invention relates to flame retarded polyurethane or polyisocyanurate foam formulations, flame retardant additives suitable for use therein, and flame retarded foams made therefrom.
摘要翻译：本发明涉及阻燃聚氨酯或聚异氰尿酸酯泡沫制剂，适用于其中的阻燃添加剂和由其制成的阻燃泡沫。

43. 发明申请

WO2008118699A1 USE OF LOW TRIPHENYLPHOSPHATE, HIGH PHOSPHOROUS CONTENT ISOPROPYL PHENYL PHOSPHATES AS FLAME RETARDANTS IN POLYURETHANE OR POLYISOCYANURATE FOAMS 审中-公开
标题翻译：低磷酸三钙的使用，高磷酸内酯异丙基苯酚磷酸酯作为聚氨酯或聚异氰酸酯FOAMS中的阻燃剂
公开(公告)号：WO2008118699A1
公开(公告)日：2008-10-02
申请号：PCT/US2008/057402
申请日：2008-03-19
申请人： ALBEMARLE CORPORATION , LAYMAN, William, J. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, T. , CHEW, Hoover
发明人： LAYMAN, William, J. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, T. , CHEW, Hoover
IPC分类号： C08K5/523 , C07F9/12 , C08L75/04
CPC分类号： C08K5/521 , C08G2101/0008 , C08G2101/0025 , C08J9/0038 , C08J2375/04 , C08K5/523 , C08K2201/014 , C08L75/00
摘要： The present invention relates to the use of low triphenyl phosphate, high phosphorous content aryl phosphates with high ortho alkylation as flame retardants in polyurethane or polyisocyanurate foams or polyurethane or polyisocyanurate foam formulations.
摘要翻译：本发明涉及在聚氨酯或聚异氰脲酸酯泡沫或聚氨酯或聚异氰脲酸酯泡沫体制剂中使用低邻苯基磷酸盐，高磷含量的高邻位烷基化芳基磷酸酯作为阻燃剂。

44. 发明申请

WO2008082709A3 PREPARATION OF HIGH ASSAY DECABROMODIPHENYL OXIDE 审中-公开
公开(公告)号：WO2008082709A3
公开(公告)日：2008-07-10
申请号：PCT/US2007/076601
申请日：2007-08-23
申请人： ALBEMARLE CORPORATION , MACK, Arthur, G. , MCKINNIE, Bonnie, Gary
发明人： MACK, Arthur, G. , MCKINNIE, Bonnie, Gary
IPC分类号： C07C41/22
摘要： A process is described for producing a reaction-derived decabromodiphenyl oxide product of high purity. In a continuous bromination process, partially brominated diphenyl oxide and coproduct hydrogen bromide are formed by bringing together elemental bromine and diphenyl oxide continuously in a first reaction zone. The partially brominated diphenyl oxide formed has an average of about 2-6 bromine atoms per molecule. The vapor phase and the partially brominated diphenyl oxide are removed continuously from the first reaction zone as separate entities. Then, or after storage, partially brominated diphenyl oxide is fed to a second reaction zone. This zone contains a refluxing reaction mixture comprising (i) an excess of bromine and (ii) a catalytic quantity of Lewis acid bromination catalyst. As the reaction in this zone is taking place, hydrogen bromide coproduct is removed therefrom in a sufficient amount to form a reaction-derived decabromodiphenyl oxide product of high purity.

45. 发明申请

WO2008027779A1 PREPARATION OF DECABROMODIPHENYL OXIDE 审中-公开
标题翻译：十八烷基二氧化钛的制备
公开(公告)号：WO2008027779A1
公开(公告)日：2008-03-06
申请号：PCT/US2007/076606
申请日：2007-08-23
申请人： ALBEMARLE CORPORATION , MACK, Arthur, G. , RANKEN, Paul, F. , WILLIAMS, Robert, E.
发明人： MACK, Arthur, G. , RANKEN, Paul, F. , WILLIAMS, Robert, E.
IPC分类号： C07C41/22
CPC分类号： C07C41/22 , C07C43/29
摘要： This invention provides a process for producing decabromodiphenyl oxide from a liquid mixture. The liquid mixture is derived from bromine, a Lewis acid catalyst, and a diphenyl oxide species selected from the group consisting of (i) diphenyl oxide, (ii) partially brominated diphenyl oxide, (iii) decabromodiphenyl oxide having about 0.5% or more nonabromodiphenyl oxide, and (iv) any combination of (i)-(iii). The process comprises distilling bromine and hydrogen bromide from the liquid mixture while feeding bromine to the liquid mixture.
摘要翻译：本发明提供了从液体混合物制备十溴二苯醚的方法。液体混合物衍生自溴，路易斯酸催化剂和选自（i）二苯基氧化物，（ii）部分溴化二苯基氧化物，（iii）具有约0.5％或更多非溴二苯基的十溴二苯醚的二苯基氧化物氧化物，（iv）（i） - （iii）的任何组合。该方法包括从液体混合物中蒸馏溴和溴化氢，同时将溴输送到液体混合物中。

46. 发明申请

WO2006071217A1 FLAME RETARDANT POLYSTYRENE FOAM COMPOSITIONS 审中-公开
标题翻译：阻燃聚苯乙烯泡沫组合物
公开(公告)号：WO2006071217A1
公开(公告)日：2006-07-06
申请号：PCT/US2004/043448
申请日：2004-12-22
申请人： ALBEMARLE CORPORATION , MAXWELL, Kimberly, A. , GOOSSENS, Danielle, F. , MACK, Arthur, G.
发明人： MAXWELL, Kimberly, A. , GOOSSENS, Danielle, F. , MACK, Arthur, G.
IPC分类号： C08F12/08 , C08J9/00 , C08J9/16
CPC分类号： C08J9/0028 , C08F112/08 , C08J2325/06
摘要： Expandable polystyrene foam compositions having flame retardant properties, flame retardant expanded polystyrene foams, methods of making such foams, and products comprising such compositions and foams are provided. A flame-retarded expanded polystyrene foam contains a flame retardant compound having the structure: (I) wherein R is H or CH 3 .
摘要翻译：提供了具有阻燃性的可发泡聚苯乙烯泡沫组合物，阻燃发泡聚苯乙烯泡沫，制备这种泡沫的方法，以及包含这种组合物和泡沫的产品。阻燃发泡聚苯乙烯泡沫体含有具有以下结构的阻燃化合物：（I）其中R是H或CH 3。

47. 发明申请

WO2010065468A1 BROMINATED FLAME RETARDANTS AND PRECURSORS THEREFOR 审中-公开
标题翻译：火焰阻燃剂及其前驱物
公开(公告)号：WO2010065468A1
公开(公告)日：2010-06-10
申请号：PCT/US2009/066134
申请日：2009-11-30
申请人： ALBERMARLE CORPORATION , LAYMAN, William, J. , KOLICH, Charles, H. , MACK, Arthur, G. , MCCARNEY, Jonathan, P. , KUMAR, Govindarajulu , WANG, Junzuo , MORICE, Jorge , GE, Zhongxin , LIU, Bo , LUTHER, Douglas, W. , WHITE, Kimberly, M. , BERRIS, Bruce, C.
发明人： LAYMAN, William, J. , KOLICH, Charles, H. , MACK, Arthur, G. , MCCARNEY, Jonathan, P. , KUMAR, Govindarajulu , WANG, Junzuo , MORICE, Jorge , GE, Zhongxin , LIU, Bo , LUTHER, Douglas, W. , WHITE, Kimberly, M. , BERRIS, Bruce, C.
IPC分类号： C08F12/08 , C08F112/08 , C08K5/00 , C08F8/20
CPC分类号： C08K5/0066 , C08F8/22 , C08F12/08 , C08F112/08 , Y02P20/582 , C08F4/56 , C08F4/48 , C08L51/00 , C08L25/06
摘要： Described are a particular group of novel aromatic hydrocarbon telomers that, on bromination, result in the formation of novel flame retardants having a uniquely beneficial combination of properties. The resultant flame retardants and uses thereof are also described. The disclosure includes descriptions of methods for preparing both the aromatic hydrocarbon telomers and the brominated flame retardant polymers.
摘要翻译：描述了一组特殊的新型芳族烃调聚物，其在溴化时导致形成具有唯一有利的性质组合的新型阻燃剂。还描述了所得的阻燃剂及其用途。本公开内容包括用于制备芳族烃调聚物和溴化阻燃聚合物的方法的描述。

48. 发明申请

WO2007127691A3 LOW TRIPHENYLPHOSPHATE, HIGH PHOSPHOROUS CONTENT ISOPROPYL PHENYL PHOSPHATES WITH HIGH ORTHO ALKYLATION 审中-公开
公开(公告)号：WO2007127691A3
公开(公告)日：2007-11-08
申请号：PCT/US2007/067188
申请日：2007-04-23
申请人： ALBERMARLE CORPORATION , LAYMAN, William, Joseph Jr. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, Todd , CHEW, Hoover , LUTHER, Douglas, W.
发明人： LAYMAN, William, Joseph Jr. , MACK, Arthur, G. , TSAO, Techen , APLIN, Jeffrey, Todd , CHEW, Hoover , LUTHER, Douglas, W.
IPC分类号： C07F9/12 , C08K5/523 , C09K21/12 , C08L27/00 , C08L75/04
摘要： The present invention relates to low triphenyl phosphate, high phosphorous content aryl phosphates with high ortho alkylation that are suitable for use as flame retardant compositions, processes for their preparation, and their use as flame retardants.

49. 发明申请

WO2004104098A2 STABILIZED FLAME RETARDANT ADDITIVES AND THEIR USE 审中-公开
标题翻译：稳定的阻燃添加剂及其使用
公开(公告)号：WO2004104098A2
公开(公告)日：2004-12-02
申请号：PCT/US2004/014234
申请日：2004-05-05
申请人： ALBEMARLE CORPORATION
发明人： GOOSSENS, Danielle, F. , MACK, Arthur, G.
IPC分类号： C08L63/00
CPC分类号： C08K5/02 , C08K5/1515 , C08L25/02
摘要： A flame retardant additive composition having enhanced thermal stability which comprises a blend formed from (A) tetrabromocyclooctane or dibromoethyldibromocyclohexane, or both and (B) halogenated aromatic epoxide and/or halogenated aromatic oligomer in which the halogen atoms are chlorine or bromine, or both, in an (A)/(B) weight ratio in the range of about 95/5 to about 60/40. Components (A) and (B) can be included to provide flame retardancy to various polymers especially styrenic polymers including foamed or foamable styrenic polymers, crystal styrenic polymers, impact-modified styrenic polymers, and blends of crystal styrenic polymers, impact-modified styrenic polymers. In all cases the thermal stability of component (A) is significantly increased by the copresence of component (B).
摘要翻译：一种具有增强的热稳定性的阻燃添加剂组合物，其包含由（A）四溴环辛烷或二溴乙基二溴环己烷或两者形成的共混物，和（B）卤素芳族环氧化物和/或卤素芳族低聚物，其中卤素原子是氯或溴，（A）/（B）重量比在约95/5至约60/40的范围内。可以包括组分（A）和（B）以向各种聚合物提供阻燃性，特别是苯乙烯聚合物，包括发泡或可发泡苯乙烯聚合物，结晶苯乙烯聚合物，冲击改性苯乙烯聚合物，以及结晶苯乙烯聚合物，冲击改性苯乙烯聚合物。在所有情况下，组分（A）的热稳定性通过组分（B）的共存显着增加。

50. 发明申请

WO2004078818A1 PREPARATION OF FLAME RETARDED POLYISOCYANURATE FOAMS 审中-公开
标题翻译：阻燃聚氨酯类挥发物的制备
公开(公告)号：WO2004078818A1
公开(公告)日：2004-09-16
申请号：PCT/US2004/005130
申请日：2004-02-20
申请人： ALBEMARLE CORPORATION
发明人： FESKE, Elbert, F. , BROWN, William, R. , LANDRY, Susan, D. , MACK, Arthur, G.
IPC分类号： C08G18/42
CPC分类号： C08G18/092 , C08G18/4213
摘要： Polyisocyanurate foams are produced by mixing at least one organic isocyanate and at least one polyol in the presence of at least one aliphatic or cycloaliphatic C 4 - C 7 hydrocarbon having a boiling point of 70°C or less at 760 millimeters pressure, at least one trimerization catalyst, at least one alkylene glycol ester of tetrabromophthalic anhydride, and at least one phosphorus ester selected from (i) tri(chloroalkyl)phosphate in which each alkyl group has 2 or 3 carbon atoms, (ii) dialkyl alkanephosphonates in which each alkyl group has 1 or 2 carbon atoms and in which the alkane group has 1 or 2 carbon atoms, and (iii) triethylphosphate, and wherein the organic isocyanate and polyol components are proportioned to form a polyisocyanurate having an isocyanate index in the range of 240 to 280.
摘要翻译：多异氰脲酸酯泡沫是通过在760毫摩尔压力下在至少一种沸点为70℃或更低的脂肪族或脂环族C 4 -C 7烃的存在下混合至少一种有机异氰酸酯和至少一种多元醇来制备的，至少一种三聚催化剂，至少一种四溴邻苯二甲酸酐的亚烷基二醇酯和至少一种磷酸酯，其选自（i）其中每个烷基具有2或3个碳原子的三（氯烷基）磷酸酯，（ii）每个烷基具有的烷基烷基膦酸二烷基酯 1或2个碳原子，其中烷烃基具有1或2个碳原子，和（iii）磷酸三乙酯，并且其中有机异氰酸酯和多元醇组分成比例，形成异氰酸酯指数在240至280范围内的聚异氰脲酸酯。

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