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41. 发明申请

WO2007053268A1 LOW TEMPERATURE INITIATORS FOR IMPROVING THE RUBBER PHASE VOLUME OF HIPS FORMULATIONS 审中-公开
标题翻译：用于改善HIPS配方的橡胶相体积的低温起动器
公开(公告)号：WO2007053268A1
公开(公告)日：2007-05-10
申请号：PCT/US2006/039450
申请日：2006-10-10
申请人： FINA TECHNOLOGY, INC. , SOSA, Jose, M. , ULLAH, Shazia
发明人： SOSA, Jose, M. , ULLAH, Shazia
IPC分类号： C08L23/00 , C08F4/06
CPC分类号： C08F279/02 , C08L51/04 , C08L2666/02
摘要： Various embodiments of an electrical cooking apparatus are disclosed. In one embodiment, an electrical cooking apparatus includes a substantially continuous cooking surface, a plurality of electrical heating elements disposed under the substantially continuous cooking surface, and at least two temperature controllers configured to allow independent control of temperatures of at least two of the plurality of heating elements.
摘要翻译：公开了电烹饪设备的各种实施例。在一个实施例中，电烹饪设备包括基本上连续的烹饪表面，设置在基本上连续的烹饪表面下方的多个电加热元件，以及至少两个温度控制器，其被配置为允许独立地控制多个加热元件。

42. 发明申请

WO2007024637A2 MEASUREMENT AND PREPARATION OF BRANCHED VINYL POLYMERS 审中-公开
标题翻译：分散的乙烯基聚合物的测定和制备
公开(公告)号：WO2007024637A2
公开(公告)日：2007-03-01
申请号：PCT/US2006/032220
申请日：2006-08-17
申请人： FINA TECHNOLOGY, INC. , STILES, Brad , SOSA, Jose, M. , CHEVILLARD, Cyril , GRIFFITH, Aron , REMIERS, Jay
发明人： STILES, Brad , SOSA, Jose, M. , CHEVILLARD, Cyril , GRIFFITH, Aron , REMIERS, Jay
IPC分类号： C08L51/00
CPC分类号： C08F2/00 , C08F112/08 , C08F279/02 , C08F2400/02 , C08L25/06 , C08L2205/02 , C08L2666/04 , C08F212/08
摘要： Disclosed are novel non-linear vinyl polymers comprised of a multifunctional peroxide, and a cross-linking agent and/or a chain transfer agent, and methods of making such polymers having: at least 0.03 branches/1000 backbone carbons; linear portions with a molecular weight (Mw) of 350,000 or less; 0.2 to 3.0 branches/molecule; or, a Mz/Mw of from 1.7 to 5.7. Methods of quantifying branching are disclosed using a linear reference having 0.0 to 0.06 branches/1000 backbone carbons along with SEC techniques and measurements of molecular weight, molecular size, and concentration. Also discovered is a vinyl polymer resin comprised of from 0.1 to 50 weight percent of non-linear polymers having at least 0.06 branches/1000 backbone carbons, where branching is measured using a heat polymerized polystyrene having from 0.0 to 0.06 branches/1000 backbone carbons as a linear reference.
摘要翻译：公开了由多官能过氧化物，交联剂和/或链转移剂组成的新型非线性乙烯基聚合物，以及制备这种聚合物的方法，其具有：至少0.03个支链/ 1000个骨架碳; 分子量（Mw）为350,000以下的线性部分; 0.2〜3.0支/分子; 或者为1.7至5.7的Mz / Mw。使用具有0.0至0.06个支链/ 1000个骨架碳的线性参考文献以及SEC技术和分子量，分子大小和浓度的测量来公开定量分支的方法。还发现了一种乙烯基聚合物树脂，其由0.1至50重量％的具有至少0.06个支链/ 1000个骨架碳的非线性聚合物组成，其中使用具有0.0至0.06个支链/ 1000骨架碳的热聚合聚苯乙烯测量分支，线性参考。

43. 发明申请

WO2007018995A2 REDOX POLYMERIZATION OF VINYL AROMATIC MONOMERS BY PHOTOSYNTHESIS 审中-公开
标题翻译：光致合成乙烯基芳香族单体的氧化还原聚合
公开(公告)号：WO2007018995A2
公开(公告)日：2007-02-15
申请号：PCT/US2006/028127
申请日：2006-07-19
申请人： FINA TECHNOLOGY, INC. , SOSA, Jose , REIMERS, Jay
发明人： SOSA, Jose , REIMERS, Jay
IPC分类号： C08F2/50
CPC分类号： C08F2/48 , C08F112/08 , C08F279/02 , C08F212/08
摘要： A method for the production of a vinyl aromatic polymer through the use of a supported light-induced photoreductant. A reactor is provided which contains a catalyst bed comprising a light-induced photoreductant component supported on a particulate substrate forming a permeable catalyst bed. A reaction stream comprising a vinyl aromatic monomer, a soluble reductant, and a transition metal salt is introduced into the reactor and passed through the catalyst bed. In addition, a gaseous oxidizing agent is introduced into the reactor and flowed through the catalyst bed and into contact with the reaction stream. The catalyst bed is irradiated with electromagnetic radiation in the ultraviolet or visible light range at an intensity sufficient to activate the photoreductant component and produce a free radical to initiate polymerization of the vinyl aromatic monomer to form a corresponding vinyl aromatic polymer. The vinyl aromatic polymer is then recovered from the reactor. The photoreductant component is a photoreductant dye, such as a group consisting of acridine, methylene blue, rose bengal, tetraphenylporphine, A protoporphyrin, A phthalocyanine and eosin-y and erythrosin-b. The transition metal salt may be an iron, cobalt or manganese salt and the soluble reductant is selected from the group consisting of diethanolamine, thiodiethanol, triethanolamine, benzoin, ascorbic acid, ester, glyoxal trimer and toluene sulfinic acid.
摘要翻译：通过使用负载型光诱导光还原剂生产乙烯基芳族聚合物的方法。提供一种反应器，其含有催化剂床，所述催化剂床包含承载在颗粒基材上的光诱导的光致还原剂组分，形成可渗透催化剂床。将包含乙烯基芳族单体，可溶性还原剂和过渡金属盐的反应物流引入反应器并通过催化剂床。另外，将气态氧化剂引入反应器并流过催化剂床并与反应物流接触。用足以激活光还原剂组分的强度的紫外或可见光范围的电磁辐射照射催化剂床，并产生自由基引发乙烯基芳族单体聚合形成相应的乙烯基芳族聚合物。然后从反应器中回收乙烯基芳族聚合物。光还原剂组分是光致还原剂染料，例如由吖啶，亚甲蓝，玫瑰红，四苯基卟吩，A原卟啉，酞菁和伊红-y以及赤藓红-b组成的组。过渡金属盐可以是铁盐，钴盐或锰盐，可溶性还原剂选自二乙醇胺，硫代二乙醇，三乙醇胺，安息香，抗坏血酸，酯，乙二醛三聚体和甲苯亚磺酸。

44. 发明申请

WO2006054995A8 USE OF TETRAFUNCTIONAL INITIATORS TO IMPROVE THE RUBBER PHASE VOLUME OF HIPS 审中-公开
标题翻译：四通道引发剂用于改善HIPS橡胶相体积的用途
公开(公告)号：WO2006054995A8
公开(公告)日：2006-08-31
申请号：PCT/US2004038701
申请日：2004-11-18
申请人： FINA TECHNOLOGY , SOSA JOSE M , KENNETH PAUL BLACKMON
发明人： SOSA JOSE M , KENNETH PAUL BLACKMON
IPC分类号： C08F279/00 , C08F279/02
CPC分类号： C08F279/00 , C08F279/02 , C08F212/08
摘要： It has been discovered that improved polystyrene products, such as high impact polystyrene (HIPS), may be obtained by polymerizing styrene with a diene polymer in the presence of at least one multifunctional initiator. The presence of the multifunctional initiator tends to cause more branched structures in the polystyrene. Unexpectedly, the ratio of % gel to % rubber (G/R or rubber phase volume) increases as the swell index increases which is the opposite of the conventional trend. Additionally, acceptable G/R values can be achieved at increased polymerization rates with these initiators.
摘要翻译：已经发现，通过在至少一种多官能引发剂的存在下使苯乙烯与二烯聚合物聚合可以获得改进的聚苯乙烯产品，例如高抗冲聚苯乙烯（HIPS）。多官能引发剂的存在趋于在聚苯乙烯中引起更多的支化结构。出乎意料的是，随着溶胀指数增加，凝胶％与橡胶％（G / R或橡胶相体积）的比率增加，这与传统趋势相反。此外，使用这些引发剂可以在增加的聚合速率下实现可接受的G / R值。

45. 发明申请

WO2005063877A1 IMPACT MODIFIED POLYSTYRENE AND PROCESS FOR PREPARING SAME 审中-公开
标题翻译：冲击改性聚苯乙烯及其制备方法
公开(公告)号：WO2005063877A1
公开(公告)日：2005-07-14
申请号：PCT/US2004/040406
申请日：2004-12-02
申请人： FINA TECHNOLOGY, INC. , SOSA, Jose, M. , BLACKMON, Kenneth, Paul , BERTI, Doug
发明人： SOSA, Jose, M. , BLACKMON, Kenneth, Paul , BERTI, Doug
IPC分类号： C08L51/00
CPC分类号： C08F287/00 , C08F279/02 , C08L9/00 , C08L25/06 , C08L51/006 , C08L51/04 , C08L2666/02 , C08F212/08
摘要： Disclosed is a composition comprising an impact modified polystyrene prepared using a process comprising dissolving a styrene-butadiene-styrene block copolymer in styrene monomer and polymerizing the styrene monomer wherein the impact modified polystyrene has a haze value of less than or equal to 12 percent. Also disclosed is an impact modified polystyrene prepared using the same process and having a ratio of Mz/Mn of at least 4.1.
摘要翻译：公开了包含使用包括将苯乙烯 - 丁二烯 - 苯乙烯嵌段共聚物溶解在苯乙烯单体中并使苯乙烯单体聚合的方法制备的抗冲改性聚苯乙烯的组合物，其中抗冲改性聚苯乙烯的雾度值小于或等于12％。还公开了使用相同方法制备的具有至少4.1的Mz / Mn比的冲击改性聚苯乙烯。

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