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    • 32. 发明申请
    • POLYARYLENE ETHER SULFONE (PAES) POLYMERS AND METHODS FOR MAKING THE SAME
    • 聚亚烷基醚(PAES)聚合物及其制备方法
    • WO2016071088A1
    • 2016-05-12
    • PCT/EP2015/073835
    • 2015-10-15
    • SOLVAY SPECIALTY POLYMERS USA, LLC
    • LOUIS, ChantalCHAPON, David
    • C07C317/14C08G61/00C08G65/40
    • C08G75/20
    • A poly(arylether sulfone)polymer[(t-PAES)polymer], wherein more than 70% moles of the recurring units are recurring units (R t ) of formula (St): -E-Ar 1 -SO 2 -[Ar 2 -(T-Ar 3 ) n -SO 2 ]m-Ar 4 - (formula S t ) wherein: n and m, equal to or different from each other, are independently zero or an integer ranging from1 to 5, each of Ar1, Ar2, Ar3 and Ar4 equal to or different from each other, is an aromatic moiety,T is a bond or a divalent group optionally comprising one or more than one heteroatom; - E is of formula (E t ): wherein each of R', equal to or different from each other, is selected from a halogen, an alkyl, an alkenyl, an alkynyl, an aryl,an ether, a thioether, a carboxylic an acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine,and a quaternary ammonium;j' is zero or an integer ranging from 1 to 4,and further wherein the (t-PAES) polymer exhibits a 1 H NMR signal at from about 8.1 to about 8.3 ppm of ≤ 1.
    • 聚(芳基醚砜)聚合物[(t-PAES)聚合物],其中多于70%摩尔的重复单元是式(St)的重复单元(Rt):-E-Ar1-SO2- [Ar2-(T -Ar3)n-SO2] m-Ar4-(式St)其中:n和m彼此相同或不同,分别为0或1〜5的整数,Ar1,Ar2,Ar3和Ar4各自相等 是芳族部分,T是任选包含一个或多于一个杂原子的键或二价基团; -E为式(Et):其中R'彼此相同或不同的每一个选自卤素,烷基,烯基,炔基,芳基,醚,硫醚,羧酸 酸,酯,酰胺,酰亚胺,碱金属或碱土金属磺酸盐,烷基磺酸盐,碱土金属膦酸盐,烷基膦酸盐,胺和季铵盐; j'为零或整数 (t-PAES)聚合物表现出约8.1-约8.3ppm≤1的1H NMR信号。
    • 34. 发明申请
    • CHEMICAL PROCESSING ARTICLES
    • 化学加工品
    • WO2015011004A2
    • 2015-01-29
    • PCT/EP2014/065307
    • 2014-07-16
    • SOLVAY SPECIALTY POLYMERS USA, LLC
    • THOMAS, David B.LOUIS, ChantalEL-HIBRI, Mohammad Jamal
    • C08G75/23
    • C08G75/23B05D1/265B29C45/0001B29C47/0016B29K2081/06C08L81/06F04C27/004
    • A chemical processing article comprising at least one part made of a poly(arylether sulfone) polymeric material comprising at least one poly(arylether sulfone) polymer, wherein said (t-PAES) polymer comprising more than 50% moles of recurring units (R t ) of formula (S t ):-E-Ar 1 -SO 2 -[Ar 2 -(T-Ar 3 )n-SO 2 ] m -Ar 4 wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group and E is of formula (E t ) wherein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4.
    • 一种化学处理制品,其包含由包含至少一种聚(芳基醚砜)聚合物的聚(芳基醚砜)聚合物材料制成的至少一部分,其中所述(t-PAES)聚合物包含超过50%摩尔的重复单元(Rt) 的式(St):-E-Ar 1 -SO 2 - [Ar 2 - (T-Ar 3)n -SO 2] m -Ar 4,​​其中n和m彼此相同或不同,独立地为0或1〜 如图5所示,Ar 1,Ar 2,Ar 3和Ar 4中的每一个彼此相同或不同,为芳香部分,T为键或二价基团,E为式(Et),其中R', 卤素,烷基,烯基,炔基,芳基,醚,硫醚,羧酸,酯,酰胺,酰亚胺,碱金属或碱土金属磺酸盐,烷基磺酸盐,碱或碱金属盐 碱土金属膦酸盐,烷基膦酸盐,胺和季铵; j'为零或为1〜4的整数。
    • 35. 发明申请
    • POLYARYLENE ETHER SULFONE (PAES) COMPOSITIONS
    • 聚亚甲基醚(PAES)组合物
    • WO2014180725A1
    • 2014-11-13
    • PCT/EP2014/058803
    • 2014-04-30
    • SOLVAY SPECIALTY POLYMERS USA, LLC
    • EL-HIBRI, Mohammad JamalLOUIS, ChantalTHOMAS, David B.PATEL, Hemantkumar
    • C08G75/23C08L81/06C08K3/40C08K7/14
    • C08L81/06C08K7/14
    • A composition [composition (C), herein after] comprising from 30 to 95% by weight of at least one poly(arylether sulfone) polymer, wherein said polymer comprising more than 50% moles of recurring units (R t ) of formula (S t ): -E-Ar 1 -SO 2 -[Ar 2 -(T-Ar 3 ) n -SO 2 ] m -Ar 4 -(formula S t ) wherein n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom;and E is of formula (E t ): herein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4, from to 50%wt. of at least one reinforcing filler, and wherein all% wt. are based on the total weight of the composition(C).
    • 包含30至95重量%的至少一种聚(芳基醚砜)聚合物的组合物[组合物(C)),其中所述聚合物包含大于50%摩尔的式(St)的重复单元(R t) :-E-Ar1-SO2- [Ar2-(T-Ar3)n-SO2] m-Ar4-(式St)其中n和m彼此相同或不同,分别为0或1〜 如图5所示,Ar1,Ar2,Ar3和Ar4中的每一个彼此等于或不同,并且在每次出现时均为芳族部分,T为任选包含一个或多于一个杂原子的键或二价基团; E为式 (Et):本文中R'彼此相同或不同的每一个选自卤素,烷基,烯基,炔基,芳基,醚,硫醚,羧酸,酯,酰胺,酰亚胺,碱或 碱土金属磺酸盐,烷基磺酸盐,碱金属或碱土金属膦酸盐,烷基膦酸盐,胺和季铵; j'为零或为1至4的整数,至50重量%。 的至少一种增强填料,并且其中所有的%wt。 基于组合物(C)的总重量。