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31. 发明申请

WO2015181122A1 FISCHER-TROPSCH GASOIL FRACTION 审中-公开
公开(公告)号：WO2015181122A1
公开(公告)日：2015-12-03
申请号：PCT/EP2015/061514
申请日：2015-05-26
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： MORSINK, Johannes Bernardus Wilhelmus , TURFBOER, Johannes , WIERSMA, Rendert Jan , WINTER, Ferry
IPC分类号： C10L1/04 , C10M105/04
CPC分类号： C10G2/332 , C09D7/20 , C09D11/033 , C10G2300/1022 , C10G2300/1055 , C10G2300/301 , C10G2300/302 , C10G2400/06 , C10L1/04 , C10M107/02 , C10M2205/173 , C10N2240/401
摘要： The present invention provides a Fischer-Tropsch gasoil fraction having an initial boiling point of at least 200°C and a final boiling point of at most 300°C. In another aspect the present invention provides a composition and the use of a Fischer-Tropsch gasoil fraction according to the invention.
摘要翻译：本发明提供了具有至少200℃的初始沸点和至多300℃的最终沸点的费 - 托瓦斯油馏分。在另一方面，本发明提供了根据本发明的费 - 托汽油部分的组合物和用途。

32. 发明申请

WO2014105553A1 PREPARATION OF A HYDROCARBON CONVERSION CATALYST 审中-公开
标题翻译：氢转移催化剂的制备
公开(公告)号：WO2014105553A1
公开(公告)日：2014-07-03
申请号：PCT/US2013/076016
申请日：2013-12-18
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： KIJLSTRA, Wiebe Sjoerd , DOMOKOS, Laszlo , ALKEMA, Sjoerd , COOPER, David Allen , WINTER, Ferry , ONG, Lay Hwa
IPC分类号： B01J37/03 , B01J37/20 , B01J21/12 , B01J23/85 , B01J23/888 , B01J35/10 , B01J37/00 , B01J37/02 , C10G45/60
CPC分类号： B01J23/888 , B01J21/12 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J37/0009 , B01J37/0203 , B01J37/03 , B01J37/036 , B01J37/20 , C10G47/12 , C10G47/14
摘要： A process for preparing a hydrocarbon conversion catalyst that comprises a specially made silica-alumina composition and a metal or metal compound selected from Group VIB and Group VIII metals. The silica-alumina composition is made by preparing an aqueous mixture containing aluminum sulfate followed by adding alkali metal aluminate to the mixture to inhance the pH to within specified range and then adding aluminum sulfate to the mixture to lower the pH. Then alkali metal silicate is added followed by several other pH swings to provide a mixture containing silica-alumina. The resulting mixture is treated with an alkaline solution to provide a precipitate solid that is recovered to obtain a silica-alumina composition containing of from 30 to 70 %wt silica and of from 70 to 30 %wt of alumina.
摘要翻译：一种制备烃转化催化剂的方法，其包含特殊制备的二氧化硅 - 氧化铝组合物和选自VIB族和VIII族金属的金属或金属化合物。二氧化硅 - 氧化铝组合物通过制备含有硫酸铝的含水混合物，然后向混合物中加入碱金属铝酸盐以将pH提高到规定范围内，然后向混合物中加入硫酸铝以降低pH。然后加入碱金属硅酸盐，然后加入几种其它pH波动，以提供含有二氧化硅 - 氧化铝的混合物。所得混合物用碱性溶液处理以提供沉淀固体，回收得到二氧化硅 - 氧化铝组合物，其含有30至70重量％的二氧化硅和70至30重量％的氧化铝。

33. 发明申请

WO2014041152A1 PROCESS FOR THE PREPARATION OF A HYDROCRACKING CATALYST 审中-公开
标题翻译：制备水解催化剂的方法
公开(公告)号：WO2014041152A1
公开(公告)日：2014-03-20
申请号：PCT/EP2013/069113
申请日：2013-09-16
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： JONGKIND, Hermanus , KIJLSTRA, Wiebe Sjoerd , PELGRIM, Bart , RIGUTTO, Marcello Stefano , WINTER, Ferry
IPC分类号： B01J37/02 , B01J37/04 , B01J23/888 , C10G47/20 , B01J29/16 , B01J29/14 , B01J35/00 , B01J37/20
CPC分类号： B01J29/166 , B01J21/04 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J29/146 , B01J31/06 , B01J35/0006 , B01J37/0203 , B01J37/0205 , B01J37/0213 , B01J37/04 , B01J37/08 , B01J37/20 , B01J2229/16 , B01J2229/186 , B01J2229/42 , C10G47/20
摘要： The invention relates to a process for the preparation of a hydrocracking catalyst, which comprises the steps of: (a) mixing a zeolite Y having a unit cell size in the range of from 24.42 to 24.52 Å, a bulk silica to alumina molar ratio (SAR) in the range of from 10 to 15, and a surface area of from 910 to 1020 m 2 /g with an alumina binder component and two or more catalytically active metal components which metal components are contained in one or more solutions, wherein the zeolite Y is present in an amount of 40 wt.% or greater, based on the total weight of the zeolite Y and the alumina binder component; (b) extruding the mixture as obtained in step (a); (c) drying the extruded mixture as obtained in step (b); (d) calcining the dried and extruded mixture as obtained in step (c); and (e) mixing the calcined product as obtained in step (d) with two or more catalytically active metal components which metal components are contained in one or more solutions. The invention further provides a process for hydrocracking a hydrocarbonaceous feedstock, which process comprises contacting the feedstock at elevated temperature with a hydrocracking catalyst as prepared by the present process. A process for the preparation of a hydrocracking catalyst, which comprises the steps of: (a) mixing a zeolite Y having a unit cell size in the range of from 24.42 to 24.52 A, a bulk silica to alumina molar ratio (SAR) in the range of from 10 to 15, and a surface area of from 910 to 1020 m 2 /g with an alumina binder component and a first metals-containing solution), wherein the zeolite Y is present in an amount of 40 wt.% or greater, based on the total weight of the zeolite Y and the alumina binder component; (b) extruding the mixture as obtained in step (a); (c) drying the extruded mixture as obtained in step (b); (d) calcining the dried and extruded mixture as obtained in step (c); and (e) impregnating the calcined product as obtained in step (d) with a second metals-containing solution.
摘要翻译：本发明涉及一种制备加氢裂化催化剂的方法，其包括以下步骤：（a）将具有24.42至24.52埃的单位晶胞尺寸的沸石Y，本体二氧化硅与氧化铝的摩尔比（ SAR）为10〜15，表面积为910〜1020m2 / g，具有氧化铝粘合剂成分和2种以上催化活性金属成分，该金属成分含在一种或多种溶液中，其中沸石基于沸石Y和氧化铝粘结剂组分的总重量，Y以40重量％或更大的量存在; （b）挤出步骤（a）中获得的混合物; （c）干燥步骤（b）中获得的挤出混合物; （d）煅烧步骤（c）中获得的干燥和挤出的混合物; 和（e）将步骤（d）中获得的煅烧产物与两种或更多种催化活性金属组分混合，所述金属组分在一种或多种溶液中包含。本发明还提供了一种烃类原料的加氢裂化方法，该方法包括使原料在升高的温度下与本方法制备的加氢裂化催化剂接触。一种制备加氢裂化催化剂的方法，其包括以下步骤：（a）将具有24.42至24.52A范围内的晶胞尺寸的沸石Y与本体二氧化硅与氧化铝的摩尔比（SAR）混合在一起范围为10至15，表面积为910至1020m2 / g，氧化铝粘合剂组分和第一含金属溶液），其中沸石Y的存在量为40重量％以上，基于沸石Y和氧化铝粘结剂组分的总重量; （b）挤出步骤（a）中获得的混合物; （c）干燥步骤（b）中获得的挤出混合物; （d）煅烧步骤（c）中获得的干燥和挤出的混合物; 和（e）用第二含金属溶液浸渍在步骤（d）中获得的煅烧产物。

34. 发明申请

WO2013092808A1 PROCESS FOR PREPARING HYDROCRACKING CATALYST COMPOSITIONS 审中-公开
标题翻译：制备水解催化剂组合物的方法
公开(公告)号：WO2013092808A1
公开(公告)日：2013-06-27
申请号：PCT/EP2012/076294
申请日：2012-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , SHELL OIL COMPANY
发明人： KIJLSTRA, Wiebe Sjoerd , WINTER, Ferry
IPC分类号： B01J21/04 , B01J29/14 , B01J37/02 , C10G47/20 , C10G45/20
CPC分类号： B01J37/20 , B01J23/883 , B01J27/0515 , B01J29/084 , B01J29/146 , B01J29/166 , B01J37/0009 , B01J37/0036 , B01J37/0213 , B01J2229/186 , B01J2229/36 , B01J2229/37 , B01J2229/42 , C10G47/20
摘要： A process for the preparation of a naphtha-selective hydrocracking catalyst comprising of from 3 to 4.8 %wt of molybdenum, calculated as metal, and of from 1.5 to 3 %wt of nickel, calculated as metal, which comprises loading a refractory oxide support comprising an alumina binder component and a zeolite Y component in a content of from 65 to 75 wt% based on the total weight of the catalyst, with nickel and molybdenum in the presence of citric acid, wherein the zeolite Y component has a unit cell size in the range of from 24.42 to 24.52 Å, a SAR in the range of from 8 to 15, and a surface area of from 850 to 1020 m 2 /g.
摘要翻译：一种制备石脑油选择性加氢裂化催化剂的方法，其包含以金属计算的3至4.8重量％的钼，以金属计算为1.5至3重量％的镍，其包括加载难熔氧化物载体，其包括：氧化铝粘合剂组分和沸石Y组分，其含量为催化剂总重量的65至75重量％，在柠檬酸存在下为镍和钼，其中沸石Y组分具有单位晶胞尺寸范围为24.42至24.52埃，SAR范围为8至15，表面积为850至1020平方米/克。

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