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    • 36. 发明申请
    • PROCESS FOR MIXING OLEFIN POLYMER WITH REACTANTS
    • 混合烯烃聚合物与反应物的方法
    • WO2016162453A1
    • 2016-10-13
    • PCT/EP2016/057684
    • 2016-04-08
    • BOREALIS AG
    • BRAUN, HermannREGUILLO CARMONA, RebecaKALTENBACHER, SaschaKLIMKE, KatjaMUSTER, UdoPROKSCHI, Hermann
    • C08F255/02
    • C08J3/12C08F210/06C08F236/06C08F255/02C08L23/14
    • The present invention is directed to a process for producing a modified olefin polymer having increased melt strength in an extruder. The process comprising the steps of: (A) contacting a stream comprising particles of an olefin polymer with a vapour stream of a functionally unsaturated compound in vapour phase thereby producing a first mixed stream; (B) passing the first mixed stream to an extruder; (C) melting the polymer particles of the first mixed stream in the extruder; (D) introducing a stream of a free radical generator either into the first mixed stream or into the extruder; and (E) extruding the first mixed stream and the free radical generator at a temperature which is greater than the decomposition temperature of the free radical generator and the melting temperature of the olefin polymer but less than the decomposition temperature of the olefin polymer thereby producing the modified olefin polymer in the extruder.
    • 本发明涉及在挤出机中生产具有增加的熔体强度的改性烯烃聚合物的方法。 该方法包括以下步骤:(A)使包含烯烃聚合物颗粒的物流与功能不饱和化合物的蒸汽流气相接触,从而产生第一混合流; (B)将第一混合流送入挤出机; (C)在挤出机中熔化第一混合流的聚合物颗粒; (D)将自由基产生剂流引入第一混合物流或挤出机中; 和(E)在大于自由基发生剂的分解温度和烯烃聚合物的熔融温度但低于烯烃聚合物的分解温度的温度下挤出第一混合流和自由基发生剂,从而产生 改性烯烃聚合物。