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31. 发明申请

WO2003000755A2 OLEFIN POLYMERISATION CATALYST AND METHODS FOR PREPARING THE SAME 审中-公开
标题翻译：烯烃聚合催化剂及其制备方法
公开(公告)号：WO2003000755A2
公开(公告)日：2003-01-03
申请号：PCT/EP2002/006716
申请日：2002-06-18
申请人： BOREALIS POLYMERS OY , DENIFL, Peter , LEINONEN, Timo , VAN PRAET, Erik , GAROFF, Thomas , PESONEN, Kari
发明人： DENIFL, Peter , LEINONEN, Timo , VAN PRAET, Erik , GAROFF, Thomas , PESONEN, Kari
IPC分类号： C08F10/06
CPC分类号： C08F110/06 , C08F4/6546 , C08F4/651 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： The present invention relates to an olefin polymerisation catalyst comprising a catalyst component in the form of particles having a predetermined size range and a low surface area, but high activity, said catalyst being suitable for use in olefin polymerisation, to the process for preparing the catalysts as such and to their use in polymerisation olefins.
摘要翻译：烯烃聚合催化剂本发明涉及一种烯烃聚合催化剂，其包含具有预定尺寸范围和低表面积，但具有高活性的所述催化剂适合用于烯烃聚合的颗粒形式的催化剂组分，用于制备催化剂的方法因此它们在聚合烯烃中的用途。

32. 发明申请

WO2002060962A1 CATALYST COMPONENT COMPRISING MAGNESIUM, TITANIUM, A HALOGEN AND AN ELECTRON DONOR AND ITS PREPARATION 审中-公开
标题翻译：包含镁，钛，卤素和电子助催化剂的催化剂组分及其制备
公开(公告)号：WO2002060962A1
公开(公告)日：2002-08-08
申请号：PCT/EP2002/000593
申请日：2002-01-22
申请人： BOREALIS TECHNOLOGY OY , DENIFL, Peter , LEINONEN, Timo
发明人： DENIFL, Peter , LEINONEN, Timo
IPC分类号： C08F10/00
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6546 , C08F4/025 , C08F2500/12 , C08F2500/18
摘要： Process for preparing an olefin polymerisation catalyst component, in which a liquid phase IV-valent titanium compound is combined with a dissolved magnesium complex to form a solution of a catalyst precursor from which said component is eventually precipitated, the combining being effected in the presence of a silica or magnesium chloride seed. The component is employed, together with an organometallic co-catalyst and optionally an external electron donor, for polymerisation of C 2 -C 10 α-olefins.
摘要翻译：制备烯烃聚合催化剂组分的方法，其中将液相IV价钛化合物与溶解的镁络合物结合以形成最终沉淀所述组分的催化剂前体溶液，所述组合在存在下进行二氧化硅或氯化镁种子。该组分与有机金属助催化剂和任选的外部电子给体一起用于C2-C10α-烯烃的聚合。

33. 发明申请

WO2011138214A1 PREPARATION OF A SOLID CATALYST SYSTEM 审中-公开
标题翻译：固体催化剂体系的制备
公开(公告)号：WO2011138214A1
公开(公告)日：2011-11-10
申请号：PCT/EP2011/056705
申请日：2011-04-28
申请人： BOREALIS AG , KALLIO, Kalle , MUSTONEN, Marja , ELO, Pertti , DENIFL, Peter , SEVERN, John
发明人： KALLIO, Kalle , MUSTONEN, Marja , ELO, Pertti , DENIFL, Peter , SEVERN, John
IPC分类号： C08F10/00 , C08F4/659 , C08F4/6592 , B01J31/22 , B01J31/14 , C07F5/06
CPC分类号： C08F4/76 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/90 , B01J2531/94 , C07F5/068 , C08F4/52 , C08F4/6028 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912
摘要： Process for the preparation of a solid catalyst system (CS) comprising the steps of preparing a liquid clathrate (LC) comprising (a) a lattice (L) being the reaction product of (i) aluminoxane (A), (ii) an organometallic compound (O) of a transition metal (M) of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and (i) a compound (B) being effective to form with the aluminoxane (A) and the organometallic compound (O) the lattice (L), and (b) a guest (G) being an hydrocarbon compound (HC), and subsequently precipitating said liquid clathrate (LC) obtaining said solid catalyst system (SC).
摘要翻译：制备固体催化剂体系（CS）的方法，包括以下步骤：制备液体包合物（LC），其包含（a）格子（L），其为（i）铝氧烷（A），（ii）有机金属（IUPAC 2007）第3至10族的过渡金属（M）或锕系元素或镧系元素的化合物（O）和（i）与铝氧烷（A）形成有效的化合物（B）和有机金属化合物（O），晶格（L）和（b）作为烃化合物（HC）的客体（G），随后沉淀得到所述固体催化剂体系（SC）的所述液体包合物（LC）。

34. 发明申请

WO2011138212A1 PREPARATION OF A SOLID CATALYST SYSTEM 审中-公开
标题翻译：固体催化剂体系的制备
公开(公告)号：WO2011138212A1
公开(公告)日：2011-11-10
申请号：PCT/EP2011/056702
申请日：2011-04-28
申请人： BOREALIS AG , KALLIO, Kalle , MUSTONEN, Marja , ELO, Pertti , SEVERN, John , DENIFL, Peter
发明人： KALLIO, Kalle , MUSTONEN, Marja , ELO, Pertti , SEVERN, John , DENIFL, Peter
IPC分类号： C08F10/00 , C08F4/659 , C08F4/6592 , B01J31/22 , B01J31/14 , C07F5/06
CPC分类号： C08F4/76 , B01J31/0239 , B01J31/0268 , B01J31/124 , B01J31/128 , B01J31/143 , B01J31/2295 , B01J31/26 , B01J2531/90 , C08F4/52 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F2410/01 , C08F4/65912
摘要： Process for the preparation of a solid catalyst system comprising the steps of generating an emulsion by dispersing a liquid clathrate in a solution wherein (i) the solution constitutes the continuous phase of the emulsion and (ii) the liquid clathrate constitutes in form of droplets the dispersed phase of the emulsion, solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system, wherein the liquid clathrate comprises a lattice being the reaction product of aluminoxane, an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, and a further compound being effective to form with the aluminoxane and the organometallic compound the lattice, and a guest being an hydrocarbon compound, and the solution comprises a silicon fluid and a hydrocarbon solvent.
摘要翻译：制备固体催化剂体系的方法，包括以下步骤：通过将液体包合物分散在溶液中产生乳液，其中（i）溶液构成乳液的连续相，和（ii）液体包合物以液滴的形式构成分散相，固化所述分散相，将所述液滴转化为固体颗粒，任选地回收所述颗粒以获得所述催化剂体系，其中所述液体包合物包含格子，其为铝氧烷，过渡金属的有机金属化合物周期表第3至10组（IUPAC 2007）或锕系元素或镧系元素，以及有效与铝氧烷和有机金属化合物形成晶格的另外的化合物，以及作为烃化合物的客体，该溶液包含硅液和烃溶剂。

35. 发明申请

WO2011076617A1 PREPARATION OF SINGLE-SITE CATALYSTS 审中-公开
标题翻译：单壁催化剂的制备
公开(公告)号：WO2011076617A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/069633
申请日：2010-12-14
申请人： BOREALIS AG , DENIFL, Peter , CASTRO, Pascal , RAUTIO, Soile , HUHTANEN, Lauri , OKSMAN, Marita , MUSTONEN, Marja
发明人： DENIFL, Peter , CASTRO, Pascal , RAUTIO, Soile , HUHTANEN, Lauri , OKSMAN, Marita , MUSTONEN, Marja
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F2410/01 , C08F4/65912
摘要： The formula (II) is (formula (II)) wherein R 1 is a semi-, highly- or perfluorinated hydrocarbon residue, and R 2 is a residue selected from the group consisting of -C(R 3 )=C(R 3' )-R 4 , wherein R 3 , R 4 , R 3' , are independently from each other selected from the group consisting of H, C 1 to C 20 alkyl, C 2 to C 20 alkenyl, C 2 to C 20 alkinyl.
摘要翻译：式（II）是（式（II）），其中R 1是半，高度或全氟化的烃残基，R 2是选自-C（R 3）= C（R 3'）-R 4 其中R3，R4，R3'彼此独立地选自H，C1至C20烷基，C2至C20烯基，C2至C20炔基。

36. 发明申请

WO2011069888A1 PROCESS FOR THE PREPARATION OF AN UNSUPPORTED, SOLID METALLOCENE CATALYST SYSTEM AND ITS USE IN POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：制备不需要的固体金属催化剂体系的方法及其在烯烃聚合中的应用
公开(公告)号：WO2011069888A1
公开(公告)日：2011-06-16
申请号：PCT/EP2010/068783
申请日：2010-12-03
申请人： BOREALIS AG , RONAN, Nicolas , DENIFL, Peter
发明人： RONAN, Nicolas , DENIFL, Peter
IPC分类号： C08F10/00 , C08F4/659
CPC分类号： C08F10/00 , C08F4/65927 , C08F12/20 , C08F12/22 , C08F110/06 , C08F293/005 , C08F2410/01 , C08F2438/01 , C08F4/65912 , C08F2500/12
摘要： Process for the preparation of an unsupported, heterogeneous olefin polymerization catalyst system, comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) in the form of solid particles comprising the steps of a) preparing a solution (A) comprising ai) an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, a 2 ) a cocatalyst comprising an element of group 13 of the Periodic Table (IUPAC 2007) and a 3 ) a solvent (A-1 ), b) preparing a liquid/liquid emulsion system by dispersing the solution (A) in a solvent (B) essentially immiscible with said solution (A) in the presence of a polystyrene-b-fluoro polystyrene copolymer of the formula (I) in which n is a number from 10 to 100, m is a number from 1 to 40, x is a number from 5 to 16, y is a number from 11 to 33, provided that m, n, x and y are selected in a way that the block copolymer is soluble in the solvent B or the solution A in such an extent that a stable emulsion is formed by adding the block copolymer, b 1 ) the solvent (B) constitutes the continuous phase of the emulsion, b 2 ) the solution (A) constitutes in the form of droplets the dispersed phase and b 3 ) the organometallic compound and the cocatalyst are present in the droplets, c) solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system; an unsupported, heterogeneous olefin polymerization catalyst, obtainable by the process and the use of the catalyst in olefin polymerization.
摘要翻译：制备无支撑的非均相烯烃聚合催化剂体系的方法，其包含固体颗粒形式的元素周期表第3至10族的过渡金属的有机金属化合物（IUPAC 2007），包括以下步骤：a）制备溶液（A）包含ai）周期表第3至10族的过渡金属的有机金属化合物（IUPAC 2007）或锕系元素或镧系元素，a2）包含元素周期表第13族元素的助催化剂（IUPAC 2007 ）和a3）溶剂（A-1），b）通过将溶液（A）分散在基本上与所述溶液（A）不混溶的溶剂（B）中，在聚苯乙烯-b的存在下制备液体/液体乳液体系式（I）的氟代聚苯乙烯共聚物，其中n为10至100的数，m为1至40的数，x为5至16的数，y为11至33的数，条件是 m，n，x和y以嵌段共聚物可溶解的方式选择 nt B或溶液A，通过加入嵌段共聚物形成稳定的乳液，b1）溶剂（B）构成乳液的连续相，b2）溶液（A）以液滴的形式构成分散相和b3）有机金属化合物和助催化剂存在于液滴中，c）固化所述分散相以将所述液滴转化为固体颗粒，并任选地回收所述颗粒以获得所述催化剂体系; 一种无支撑的非均相烯烃聚合催化剂，可通过烯烃聚合中的方法和使用催化剂获得。

37. 发明申请

WO2010052263A1 SOLID CATALYST COMPOSITION 审中-公开
标题翻译：固体催化剂组合物
公开(公告)号：WO2010052263A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064669
申请日：2009-11-05
申请人： BOREALIS AG , HAKALA, Kimmo , MANSNER, Erik , DENIFL, Peter , LEHTINIEMI, Ismo , KAUHANEN, Jyrki , HUHTANEN, Lauri
发明人： HAKALA, Kimmo , MANSNER, Erik , DENIFL, Peter , LEHTINIEMI, Ismo , KAUHANEN, Jyrki , HUHTANEN, Lauri
IPC分类号： B01J31/12 , B01J31/16 , B01J31/22 , B01J31/14 , C08F4/00
CPC分类号： B01J31/128 , B01J31/143 , B01J31/165 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Solid catalyst composition comprising a polymer matrix (A) and distributed therein a solid catalyst system (B), wherein • the solid catalyst system (B) • has a porosity measured according to ASTM 4641 of less than 1.40 ml/g, • comprises a transition metal compound of formula (I) L m R n MX q , (I) wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent anionic σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), "R" is a bridging group linking two organic ligands (L), "m" is 2 or 3, "n" is 0, 1 or 2, "q" is 1, 2 or 3, m+q is equal to the valency of the transition metal (M), and a cocatalyst (Co) comprising a compound of A1, and • the weight ratio of the polymer matrix (A) and the catalyst system (B) [weight polymer matrix (A)/weight catalyst system (B)] in the solid catalyst composition is below 25.0.
摘要翻译：包含聚合物基体（A）并分布在其中的固体催化剂体系（B）的固体催化剂组合物，其中固体催化剂体系（B）°具有根据ASTM 4641测量的孔隙率小于1.40ml / g的固体催化剂组合物包含式（I）的过渡金属化合物LmRnMXq，（I）其中“M”是周期表（IUPAC）中3至10族中的任何一个的过渡金属，每个“X”独立地是一价阴离子S-配体，每个“L”独立地是与过渡金属（M）配位的有机配体，“R”是连接两个有机配体（L）的桥连基团，“m”是2或3，“n”是0,1或 2中，“q”为1,2或3，m + q等于过渡金属（M）的化合价，以及包含A1化合物的助催化剂（Co），以及聚合物基质的重量比 A）和固体催化剂组合物中的催化剂体系（B）[重量聚合物基质（A）/重量催化剂体系（B）]低于25.0。

38. 发明申请

WO2009068579A1 PROCESS FOR THE PREPARATION OF PROPYLENE RANDOM COPOLYMERS 审中-公开
标题翻译：制备丙烯随机共聚物的方法
公开(公告)号：WO2009068579A1
公开(公告)日：2009-06-04
申请号：PCT/EP2008/066267
申请日：2008-11-26
申请人： BOREALIS TECHNOLOGY OY , DENIFL, Peter , LEINONEN, Timo , HAIKARAINEN, Anssi , VESTBERG, Torvald
发明人： DENIFL, Peter , LEINONEN, Timo , HAIKARAINEN, Anssi , VESTBERG, Torvald
IPC分类号： B01J35/08 , C08F4/651 , C08F210/06
CPC分类号： B01J37/0209 , B01J21/08 , B01J37/0203 , C08F110/06 , C08F210/06 , C08F210/16 , C08F4/025 , C08F4/6546 , C08F2/001 , C08F2500/24 , C08F2500/12
摘要： A process for the preparation of a propylene random copolymer, wherein propylene is polymerised with ethylene and/or a C4-C20 alpha-olefin in the presence of a catalyst system comprising solid catalyst particles, wherein the solid catalyst particles (a) have a specific surface area of less than 20 m 2 /g, (b) comprise a transition metal compound which is selected from one of the groups 4 to 10 of the periodic table or a compound of actinide or lanthanide,10 (c) comprise a metal compound which is selected from one of the groups 1 to 3 of the periodic table, and (d) comprise inclusions not having catalytically active sites.
摘要翻译：一种制备丙烯无规共聚物的方法，其中在包含固体催化剂颗粒的催化剂体系的存在下，丙烯与乙烯和/或C 4 -C 20α-烯烃聚合，其中固体催化剂颗粒（a）具有特定的表面积小于20m2 / g，（b）包含选自元素周期表第4至10族之一的过渡金属化合物或锕系元素或镧系元素的化合物，10（c）包含金属化合物，选自周期表第1至3组之一，（d）包含不具有催化活性位点的夹杂物。

39. 发明申请

WO2007137853A1 CATALYST WITH AL-ALKOXY COMPONENT 审中-公开
标题翻译：催化剂与AL-ALKOXY组件
公开(公告)号：WO2007137853A1
公开(公告)日：2007-12-06
申请号：PCT/EP2007/004839
申请日：2007-05-31
申请人： BOREALIS TECHNOLOGY OY , DENIFL, Peter , LEINONEN, Timo
发明人： DENIFL, Peter , LEINONEN, Timo
IPC分类号： C08F10/00 , C08F4/651 , C08F4/655
CPC分类号： C08F4/6555 , C08F110/06 , C08F4/6557 , C08F4/651 , C08F2500/12 , C08F2500/04 , C08F2500/17 , C08F2500/19
摘要： The invention refers to a process for preparing a Group 2 metal/transition metal olefin polymerization catalyst component in particulate form having an improved high temperature activity and the use thereof in a process for polymerising olefins.
摘要翻译：本发明涉及一种制备具有改善的高温活性的颗粒形式的第2族金属/过渡金属烯烃聚合催化剂组分的方法及其在烯烃聚合方法中的用途。

40. 发明申请

WO2007077027A1 CATALYST PARTICLES 审中-公开
标题翻译：催化剂颗粒
公开(公告)号：WO2007077027A1
公开(公告)日：2007-07-12
申请号：PCT/EP2006/012631
申请日：2006-12-29
申请人： BOREALIS TECHNOLOGY OY , DENIFL, Peter , LEINONEN, Timo
发明人： DENIFL, Peter , LEINONEN, Timo
IPC分类号： C08F4/651 , C08F10/00 , B01J35/08
CPC分类号： C08F10/06 , C08F110/06 , C08F110/14 , C08F4/6548 , C08F4/651 , C08F2500/18 , C08F2500/12
摘要： The present invention relates to novel and unique catalyst particles, a method for preparing same, the use of the catalyst particles for polymerization reactions and methods of controlling the catalyst particle morphology.
摘要翻译：本发明涉及新型和独特的催化剂颗粒，其制备方法，催化剂颗粒用于聚合反应的用途和控制催化剂颗粒形态的方法。

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