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31. 发明申请

WO2003070672A1 PRODUCTION OF OLEFINS 审中-公开
标题翻译：生产油脂
公开(公告)号：WO2003070672A1
公开(公告)日：2003-08-28
申请号：PCT/GB2003/000637
申请日：2003-02-13
申请人： BP CHEMICALS LIMITED , WOODFIN, William, Terence
发明人： WOODFIN, William, Terence
IPC分类号： C07C5/333
CPC分类号： C07C5/333 , C10G2400/20 , C07C11/04
摘要： The present invention provides a process for the production of mono-olefins from a paraffin-containing hydrocarbon feed, comprising partially combusting a mixture of the hydrocarbon feed and a molecular oxygen-containing gas in contact with a catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability and subsequently separating the products of said combustion wherein energy for the separation is provided by a cogeneration process which simultaneously produces thermal energy and mechanical energy by combustion of fuel, the mechanical energy being converted to electricity, and the thermal energy being used to create steam for use in a steam turbine.
摘要翻译：本发明提供了一种从含链烷烃的烃进料中生产单烯烃的方法，包括部分燃烧烃进料和含能气体的分子氧气体的混合物，该催化剂能够支持超出正常燃料的燃料丰富的可燃性极限，随后分离所述燃烧的产物，其中用于分离的能量由热电联产过程提供，其通过燃料燃烧同时产生热能和机械能，将机械能转换为电，并且使用的热能以产生用于蒸汽轮机的蒸汽。

32. 发明申请

WO2003066551A1 PRODUCTION OF OLEFINS 审中-公开
标题翻译：生产油脂
公开(公告)号：WO2003066551A1
公开(公告)日：2003-08-14
申请号：PCT/GB2003/000498
申请日：2003-02-06
申请人： BP CHEMICALS LIMITED , BURNS, Andrew, Lindsay , GRIFFITHS, David, Charles , WOODFIN, William, Terence
发明人： BURNS, Andrew, Lindsay , GRIFFITHS, David, Charles , WOODFIN, William, Terence
IPC分类号： C07C5/48
CPC分类号： C10G2/32 , C07C5/48 , C07C2521/04 , C07C2523/42 , C10G2300/1081 , C10G2400/20 , Y02P30/40 , Y02P30/446 , C07C11/04
摘要： A process for the production of a mono-olefin from a feedstock comprising a paraffinic hydrocabon which process comprises a) partially combusting at a pressure of at least (15) barg a mixture of the hydrocarbon feed and a molecular oxygen-containing gas in contact with a catalyst capable of supporting combustion beyond the normal fuel rich limit of flammability where they are reacted to form a product comprising one or more mono-olefin(s), carbon monoxide and hydrogen and b) recovering the one or more olefin(s).
摘要翻译：一种从原料生产单烯烃的方法，包括链烷烃氢化氢，该方法包括：a）在至少（15）barg的烃进料和含有分子氧的气体的混合物的压力下部分燃烧，一种催化剂，其能够支持燃烧超过正常燃料富含的可燃性极限，其中它们反应以形成包含一种或多种单烯烃，一氧化碳和氢气的产物，以及b）回收一种或多种烯烃。

33. 发明申请

WO2003055838A1 INTEGRATED PROCESS FOR THE MANUFACTURE OF ALKENYL CARBOXYLATES 审中-公开
标题翻译：生产烯基羧酸盐的综合方法
公开(公告)号：WO2003055838A1
公开(公告)日：2003-07-10
申请号：PCT/GB2002/005455
申请日：2002-12-04
申请人： BP CHEMICALS LIMITED , CLARKE, Robert, William , ROBERTS, Mark, Stephen
发明人： CLARKE, Robert, William , ROBERTS, Mark, Stephen
IPC分类号： C07C67/05
CPC分类号： C07C67/54 , C07C5/48 , C07C51/215 , C07C51/46 , C07C67/055 , Y02P20/125 , Y02P20/582 , C07C69/15 , C07C53/08 , C07C11/04
摘要： An integrated process for the production of an alkenyl carboxylate, such as vinyl acetate which process comprises the steps of (a) contacting in an oxidation reaction zone a C 2 to C 4 alkane, such as ethane, a molecular oxygen-containing gas, optionally the corresponding alkene and optionally water, in the presence of a catalyst to produce a stream comprising alkene, carboxylic acid and water; (b) separating at least a portion of the stream from step (a) into a fraction comprising the alkene and a fraction comprising the carboxylic acid and water; (c) contacting in a second reaction zone at least a portion of said alkene fraction produced in step (b), a carboxylic acid and a molecular oxygen-containing gas, in the presence of a catalyst to produce a product stream comprising an alkenyl carboxylate, water and carboxylic acid; (d) separating at least a portion of the product stream from step (c) and at least a portion of the carboxylic acid and water fraction produced in step (b) by azeotropic distillation into an overhead fraction comprising the alkenyl carboxylate and a base fraction comprising the carboxylic acid; (e) recovering the alkenyl carboxylate from the overhead fraction separated in step (d).
摘要翻译：一种用于生产链烯基羧酸盐如乙酸乙烯酯的整合方法，该方法包括以下步骤：（a）在氧化反应区中使C 2 C与C 例如乙烷，含分子氧的气体，任选相应的烯烃和任选的水，在催化剂存在下反应以产生包含烯烃，羧酸和水的物流; （b）将来自步骤（a）的至少一部分物流分离成包含烯烃和包含羧酸和水的馏分的馏分; （c）在第二反应区中，在催化剂存在下，将步骤（b）中产生的所述烯烃馏分的至少一部分，羧酸和含分子氧的气体在催化剂存在下接触以产生包含羧酸烯基酯，水和羧酸; （d）通过共沸蒸馏将至少一部分来自步骤（c）的产物流和至少一部分步骤（b）中产生的羧酸和水馏分分离成包含烯基羧酸盐和碱馏分的塔顶馏分包含羧酸; （e）从步骤（d）中分离的塔顶馏分中回收链烯基羧酸酯。

34. 发明申请

WO2003014046A1 CHAIN GROWTH REACTION PROCESS 审中-公开
标题翻译：链生长反应过程
公开(公告)号：WO2003014046A1
公开(公告)日：2003-02-20
申请号：PCT/GB2002/003096
申请日：2002-07-05
申请人： BP CHEMICALS LIMITED , BRITOVSEK, George, Johan, Peter , COHEN, Steven, Alan , GIBSON, Vernon, Charles
发明人： BRITOVSEK, George, Johan, Peter , COHEN, Steven, Alan , GIBSON, Vernon, Charles
IPC分类号： C07C2/30
CPC分类号： C07C1/325 , C07C29/54 , C07F3/06 , C08F4/65922 , C08F10/00 , C08F10/02 , C08F210/16 , C08F2410/01 , Y10S526/941 , Y10S526/943 , C07C11/02 , C08F4/65912 , C08F210/14 , C08F2500/03 , C08F4/7042 , C07C31/02 , C08F2/38
摘要： A process is disclosed for the preparation of zinc alkyl chain growth products via a catalysed chain growth reaction of an alpha-olefin on a zinc alkyl, wherein the chain growth catalyst system employs a group 3-10 transition metal, or a group 3 main group metal, or a lanthanide or actinide complex, and optionally a suitable activator. The products can be further converted into alpha-olefins by olefin displacement of the grown alkyls as alpha-olefins from the zinc alkyl chain growth product, or into primary alcohols, by oxidation of the resulting zinc alkyl chain growth product to form alkoxide compounds, followed by hydrolysis of the alkoxides.
摘要翻译：公开了通过烷基锌上的α-烯烃的催化链生长反应制备烷基链烷基锌生长产物的方法，其中链增长催化剂体系采用3-10族过渡金属或第3族主要基团金属或镧系元素或锕系元素络合物，以及任选的合适的活化剂。通过将生成的烷基作为α-烯烃从烷基链生长产物或烷基链烯烃取代，可将产物进一步转化为α-烯烃，通过氧化得到的烷基链烷基锌生长产物形成醇盐化合物，随后通过醇盐的水解。

35. 发明申请

WO2002062858A1 HIGH ACTIVITY POLYETHYLENE CATALYSTS PREPARED WITH BORATES REAGENTS 审中-公开
标题翻译：高活性聚乙烯催化剂用硼酸盐试剂制备
公开(公告)号：WO2002062858A1
公开(公告)日：2002-08-15
申请号：PCT/GB2002/000407
申请日：2002-01-30
申请人： BP CHEMICALS LIMITED , BP CHEMICALS SNC , DOSSETT, Stephen, John
发明人： DOSSETT, Stephen, John
IPC分类号： C08F10/02
CPC分类号： C08F10/00 , C08F210/16 , Y02P20/52 , C08F4/658 , C08F210/14 , C08F2500/12
摘要： The present invention relates to an improved supported Ziegler-Natta catalyst especially useful for the olefin polymerisation, said catalyst comprising a carrier, an organomagnesium compound, a borate compound, and one transition metal compound.
摘要翻译：本发明涉及一种特别用于烯烃聚合的改进的支持齐格勒 - 纳塔催化剂，所述催化剂包含载体，有机镁化合物，硼酸盐化合物和一种过渡金属化合物。

36. 发明申请

WO1999000431A1 PROCESS FOR THE POLYMERISATION OF OLEFINS IN THE GAS PHASE 审中-公开
标题翻译：在气相中烯烃聚合的方法
公开(公告)号：WO1999000431A1
公开(公告)日：1999-01-07
申请号：PCT/GB1997001730
申请日：1997-06-27
申请人： BP CHEMICALS LIMITED , MADDOX, Peter, James , WILLIAMS, Peter, Sefton
发明人： BP CHEMICALS LIMITED
IPC分类号： C08F10/02
CPC分类号： C08F10/02 , C08F4/61908 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F110/06 , C08F210/16 , C08F2/34 , C08F2500/12 , C08F210/14
摘要： A process for the polymerisation of olefins in the gas phase is carried out in the presence of a supported transition metal catalyst. The process involves a prepolymerisation step which may be performed in-situ and in particular the prepolymer may be prepared in the dry phase. The catalyst may for example comprise a constrained geometry transition metal complex supported on silica and used in the presence of an activator. The prepolymerisation step unables the activity of the catalyst to be improved.
摘要翻译：在气相中烯烃聚合的方法是在负载的过渡金属催化剂的存在下进行的。该方法涉及可以原位进行的预聚合步骤，特别地，预聚物可以在干相中制备。催化剂可以例如包括负载在二氧化硅上并在活化剂存在下使用的约束几何形状的过渡金属络合物。预聚合步骤不能改善催化剂的活性。

37. 发明申请

WO1998030783A1 A PROCESS AND A FORMULATION TO INHIBIT SCALE IN OIL FIELD PRODUCTION 审中-公开
标题翻译：一种在油田生产中抑制规模的过程和配方
公开(公告)号：WO1998030783A1
公开(公告)日：1998-07-16
申请号：PCT/GB1997003553
申请日：1997-12-24
申请人： BP CHEMICALS LIMITED , COLLINS, Ian, Ralph
发明人： BP CHEMICALS LIMITED
IPC分类号： E21B37/06
CPC分类号： E21B37/06 , C09K8/524 , C09K8/528
摘要： This invention is a process and a formulation for minimising the squeezing and shut-in operations needed to inhibit scale in a production well using the precipitation squeeze method by injecting into an oil-bearing rock formation a water-miscible formulation comprising: (a) a water-miscible surfactant which is in liquid form, (b) a solution of water-soluble metal salt comprising a multivalent cation and (c) a solution of a water-miscible scale-inhibiting compound comprising an anionic component capable of forming a scale-inhibiting precipitate in situ in the presence of the cations in (b) upon injection into the rock formation, wherein the surfactant is a glycol ether and the minimum ion concentration of the scale-inhibiting compound (c) is 5000 ppm based on the total weight of the formulation.
摘要翻译：本发明是一种方法和配方，其用于使用沉淀挤压方法将抑制生产井中的水垢所需的挤压和关闭操作最小化，通过将含水岩石注入到含水岩层中，该水混溶性制剂包含：（a）水溶性表面活性剂，其为液体形式，（b）包含多价阳离子的水溶性金属盐溶液和（c）含水混溶性垢抑制化合物的溶液，该化合物包含能形成刻度尺的阴离子组分，在（b）中注入岩石中的阳离子存在时，原位抑制沉淀，其中表面活性剂是二醇醚，并且防垢化合物（c）的最小离子浓度基于总重量为5000ppm 的配方。

38. 发明申请

WO1998011144A1 POLYMERISATION CATALYST 审中-公开
标题翻译：聚合催化剂
公开(公告)号：WO1998011144A1
公开(公告)日：1998-03-19
申请号：PCT/GB1997002419
申请日：1997-09-05
申请人： BP CHEMICALS LIMITED , DORER, Birgit, Angelika , LITTLE, Ian, Raymond , SHARP, Christopher , STICHBURY, Joanne, Clare
发明人： BP CHEMICALS LIMITED
IPC分类号： C08F04/60
CPC分类号： C08F10/00 , C07F17/00 , C08F4/61908 , C08F4/61912 , C08F110/02 , C08F4/61925 , C08F4/6192
摘要： A catalyst composition suitable for use in the polymerisation of olefins comprises a discrete metal complex having chelating ligands comprising at least one atom from O, S, N and P bound directly to the metal. The complexes are used in the presence of Lewis acids and may be exemplified by bis(cyclopentadienyl) zirconium complexes. Typical chelating ligands include acetylacetonate and the complexes have the particular advantages of not requiring traditional activators such as MAO.
摘要翻译：适用于烯烃聚合的催化剂组合物包括具有螯合配体的离散金属络合物，其包含至少一个直接与金属结合的O，S，N和P的原子。络合物在路易斯酸存在下使用，可以列举双（环戊二烯基）锆络合物。典型的螯合配体包括乙酰丙酮化物，并且络合物具有不需要传统活化剂如MAO的特殊优点。

39. 发明申请

WO1998005620A1 INTEGRATED PROCESS FOR THE PRODUCTION OF VINYL ACETATE AND/OR ACETIC ACID 审中-公开
标题翻译：用于生产乙酸乙烯酯和/或乙酸的一体化方法
公开(公告)号：WO1998005620A1
公开(公告)日：1998-02-12
申请号：PCT/GB1997002101
申请日：1997-08-05
申请人： BP CHEMICALS LIMITED , JOBSON, Simon , WATSON, Derrick, John
发明人： BP CHEMICALS LIMITED
IPC分类号： C07C53/08
CPC分类号： C07C51/25 , C07C67/055 , Y02P20/125 , C07C53/08 , C07C69/01 , C07C69/15
摘要： Acetic acid and/or vinyl acetate are produced by an integrated process which comprises the steps: (a) contacting in a first reaction zone a gaseous feedstock comprising ethylene and/or ethane and optionally steam with a molecular oxygen-containing gas in the presence of a catalyst active for the oxidation of ethylene to acetic acid and/or ethane to acetic acid and ethylene to produce a first product stream comprising acetic acid, water and ethylene (either as unreacted ethylene and/or as co-produced ethylene) and optionally also ethane, carbon monoxide, carbon dioxide and/or nitrogen; (b) contacting in a second reaction zone in the presence or absence of additional ethylene and/or acetic acid at least a portion of the first gaseous product stream comprising at least acetic acid and ethylene and optionally also one or more of water, ethane, carbon monoxide, carbon dioxide and/or nitrogen with a molecular oxygen-containing gas in the presence of a catalyst active for the production of vinyl acetate to produce a second product stream comprising vinyl acetate, water, acetic acid and optionally ethylene; (c) separating the product stream from step (b) by distillation into an overhead azeotrope fraction comprising vinyl acetate and water and a base fraction comprising acetic acid; (d) either (i) recovering acetic acid from the base fraction separated in step (c) and optionally recycling the azeotrope fraction separated in step (c) after partial or complete separation of the water therefrom to step (c), or (ii) recovering vinyl acetate from the azeotrope fraction separated in step (c) and optionally recycling the base fraction separated in step (c) to step (b), or (iii) recovering acetic acid from the base fraction separated in step (c) and recovering vinyl acetate from the overhead azeotrope fraction recovered in step (c).
摘要翻译：乙酸和/或乙酸乙烯酯通过一体化方法生产，其包括以下步骤：（a）在第一反应区中使含有乙烯和/或乙烷的气态原料和任选的蒸汽与含分子氧的气体在用于将乙烯氧化成乙酸和/或乙烷至乙酸和乙烯的催化剂，以产生包含乙酸，水和乙烯（作为未反应的乙烯和/或作为共同生产的乙烯）的第一产物流，乙烷，一氧化碳，二氧化碳和/或氮气; （b）在存在或不存在另外的乙烯和/或乙酸的情况下，在第二反应区中接触至少一部分包含至少乙酸和乙烯的第一气态产物流，以及任选地还包含一种或多种水，乙烷，一氧化碳，二氧化碳和/或氮与含分子氧的气体在活性物质的存在下生产乙酸乙烯酯以产生包含乙酸乙烯酯，水，乙酸和任选的乙烯的第二产物流; （c）通过蒸馏将来自步骤（b）的产物流分离成包含乙酸乙烯酯和水的塔顶共沸组分和包含乙酸的碱部分; （d）（i）从步骤（c）中分离的碱馏分中回收乙酸，并任选地将步骤（c）中分离的共沸馏分循环到其中部分或完全分离到步骤（c）之后，或（ii）从步骤（c）中分离的共沸物馏分中回收乙酸乙烯酯，并任选地将步骤（c）中分离的碱部分再循环到步骤（b），或（iii）从步骤（c）中分离的碱馏分中回收乙酸和从步骤（c）中回收的塔顶共沸物馏分中回收乙酸乙烯酯。

40. 发明申请

WO1998000387A1 MIXTURE OF ESTERS AND USE THEREOF 审中-公开
标题翻译：奶油混合物及其用途
公开(公告)号：WO1998000387A1
公开(公告)日：1998-01-08
申请号：PCT/GB1997001741
申请日：1997-06-27
申请人： BP CHEMICALS LIMITED , GRACEY, Benjamin, Patrick , HALLETT, Christopher
发明人： BP CHEMICALS LIMITED
IPC分类号： C07C69/708
CPC分类号： C07C69/708 , C09D7/20
摘要： This invention relates to a composition comprising a mixture of a fumarate, maleate and 2-allyloxy-succinate esters falling within the area defined by points A, B, C and D of a triangular chemical composition diagram (hereafter "TCCD") said points representing respectively the ranges of concentration of said maleate, fumarate and succinate in said composition, a process for preparing the same and the use thereof as a reactive diluent in a paint or coating formulation.
摘要翻译：本发明涉及一种组合物，其包含落在由三角化学组成图（以下称“TCCD”）的点A，B，C和D所定义的区域内的富马酸盐，马来酸盐和2-烯丙氧基 - 琥珀酸酯的混合物，所述点代表分别在所述组合物中所述马来酸盐，富马酸盐和琥珀酸盐的浓度范围，其制备方法及其作为涂料或涂料制剂中反应性稀释剂的用途。

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