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    • 23. 发明申请
    • CHROME TANNING PROCESS
    • 铬染色工艺
    • WO2015044766A8
    • 2016-04-07
    • PCT/IB2014001960
    • 2014-09-30
    • RHODIA POLIAMIDA E ESPECIALIDA
    • LOURENÇO WAGNER CÉLIO FERRAZ
    • C14C1/08C14C3/06
    • C14C3/06C14C1/08
    • The invention concerns a process for tanning hide to obtain leather. The general process for obtaining the intermediary wet blue stage comprises the following steps : a) a picking step with acid and salt, followed by b) a tanning step with chromium salt, followed by c) a basification step. The invention is characterized in that between step b) and c), a re-acidification step with organic acids is added. In particular the organic acids are selected from glutaric acid (GA), 2-methyl glutaric acid (MGA), succinic acid, ethyl succinic acid (ESA), adipic acid (AA), maleic anhydride, fumaric anhydride, tricarboxylic acids, hydroxycarboxylic acids, and mixture thereof. This invention enables an increase of the up-taking of the re-tanning products and provides leather with improved mechanical properties.
    • 本发明涉及一种鞣制皮革以获得皮革的方法。 获得中间湿蓝色阶段的一般方法包括以下步骤:a)用酸和盐进行采摘步骤,然后b)用铬盐进行鞣制步骤,然后c)碱化步骤。 本发明的特征在于在步骤b)和c)之间,加入有机酸的再酸化步骤。 特别地,有机酸选自戊二酸(GA),2-甲基戊二酸(MGA),琥珀酸,乙基琥珀酸(ESA),己二酸(AA),马来酸酐,富马酸酐,三羧酸,羟基羧酸 ,及其混合物。 本发明能够增加鞣制产品的上升,并为皮革提供改善的机械性能。
    • 25. 发明申请
    • TANNING PROCESS FOR OBTAINING LEATHER
    • 用于获取皮革的TANNING工艺
    • WO2015044765A1
    • 2015-04-02
    • PCT/IB2014001956
    • 2014-09-30
    • RHODIA POLIAMIDA E ESPECIALIDA
    • FERRAZ LOURENÇO WAGNER CÉLIO
    • C14C1/08C14C3/06
    • C14C3/06C14C1/08
    • The invention concerns a process for tanning hide to obtain leather. The general process for obtaining the intermediary wet blue stage comprises the following steps: a) a picking step with acid and salt, followed by b) a tanning step with chromium salt, followed by c) a basification step. The invention is characterized in that the bath of the pickling step comprises organic acids selected from 2-Methyl glutaric acid (MGA), ethyl succinic acid (ESA) and mixture thereof instead of the traditional strong acid, generally sulfuric acid This process requires less basification agent and enables an increase of the up-taking of the re- tanning products. This invention provides leather with improved mechanical properties.
    • 本发明涉及一种鞣制皮革以获得皮革的方法。 获得中间湿蓝色阶段的一般方法包括以下步骤:a)用酸和盐进行采摘步骤,然后b)用铬盐进行鞣制步骤,然后c)碱化步骤。 本发明的特征在于,酸洗步骤的浴包括选自2-甲基戊二酸(MGA),乙基琥珀酸(ESA)和其混合物的有机酸,而不是传统的强酸,通常是硫酸。该方法需要较少的碱化 代理商,并且能够增加禁用产品的上升。 本发明提供具有改进的机械性能的皮革。
    • 27. 发明申请
    • PROCEDURE FOR THE TANNING OF SKINS, MATERIAL OBTAINED DURING SAID PROCEDURE AND DEVICE
    • 皮肤鞣制程序,在程序和设备期间获得的材料
    • WO2010070571A3
    • 2010-08-19
    • PCT/IB2009055733
    • 2009-12-14
    • INVEST DE LAS IND DEL CURTIDOADZET ADZET JOSE MARIA
    • ADZET ADZET JOSE MARIA
    • C14C1/00C14C1/08C14C3/06C14C3/10C14C15/00
    • C14C15/00C14C1/00C14C1/08C14C3/06C14C3/10
    • The procedure comprises subjecting the skins to riverside works and, A) sammying the skins; dehydration and degreasing in a water miscible solvent; drying of said solvent; or B) sammying the skins; dehydration and degreasing in a water miscible solvent that comprises aliphatic hydrocarbons; drying of said solvent; or C) pickling; laying out; degreasing; acidification; sammying the skins; drying; or D) pickling; laying down; degreasing; acidification; pre-tanning with pre-tanning products; sammying of the skins; and drying; wherein said drying allows dry and frayed skins to be obtained and, next, a tanning stage by immersion in a solution of mineral salts, vegetable tannin extracts or mixtures thereof. This invention also provides a material obtained before the tanning, useful as a replacement for the skin tanned by conventional methods, as well as a device for dehydrating and degreasing the skins following option A) of the claimed procedure.
    • 该程序包括使皮肤进行河边作品,以及(A)使皮肤松弛; 在水混溶性溶剂中脱水脱脂; 干燥所述溶剂; 或B)sammying皮肤; 在包含脂肪烃的水混溶性溶剂中脱水和脱脂; 干燥所述溶剂; 或C)酸洗; 铺设; 除油; 酸化; samying皮肤; 烘干; 或D)酸洗; 放下 除油; 酸化; 预鞣制与预鞣制品; samying的皮肤; 并干燥; 其中所述干燥允许获得干燥和磨碎的表皮,接下来,通过浸入无机盐,植物单宁提取物或其混合物的溶液中进行鞣制阶段。 本发明还提供了在鞣制之前获得的材料,其可用作通过常规方法鞣制的皮肤的替代物,以及根据所要求保护的方法的选择A)的用于脱皮和脱脂皮肤的装置。
    • 29. 发明申请
    • PRODUCT FOR PELT CONDITIONING FOR TANNING: PROCESS FOR PELT CONDITIONING AND FOLLOWING TANNING
    • 用于鞣剂的皮带调理产品:用于皮肤调理和鞣制的方法
    • WO2006089384A3
    • 2006-11-09
    • PCT/BR2006000033
    • 2006-02-21
    • ACQUAQUIMICA LTDAKONRATH RENATO AUGUSTOFRANCISCO JOSE FAVAEVETON BRAUN JOSE
    • KONRATH RENATO AUGUSTOFRANCISCO JOSE FAVAEVETON BRAUN JOSE
    • C14C1/08C14C3/02C14C3/28
    • C14C1/00
    • The present invention is related to the use of a new conditioning agent for treating pelts for tanning. This conditioning agent consists in a composition of modified aldehydes, carboxylic acids or polycarboxylic acids and additives. The conditioning agent is used for replacing the steps of deliming and pickling in the pelts treatment. The action of the product can eliminate the step of basification when the tanning is made with chromium salts. The objective of the present invention is the use of a novel composition that can replace the steps of deliming, step 6, and pickling, step 8, described before for one just step called conditioning The proposed system, neutralizes the alkalinity and hence removes the solubility of Calcium from the liming operation attached in the pelt. The system described is obtained from functional aldehydes with the general formulation as following: The system comprises functional aldehydes to which are added a combination or just one of the following chemicals: mono, di, tri and polycarboxilic acids; anhydrides: fumaric, maleic and ftalic anhydrides of dicarboxilic acids that contains at least 2 to 8 carbon atoms; esters of mono, di, tri and polycarboxilic acids; EDTA; boric acid and sodium and calcium tripolyphosphates As solvents to stabilize the system it is used one or a mixture of the following compounds: water, branched or non-branched aliphatic alcohol, glycols and polyols.
    • 本发明涉及使用新的调理剂处理用于鞣革的毛皮。 该调理剂由改性醛,羧酸或多元羧酸和添加剂组成。 调理剂用于替代皮毛处理中的脱灰和酸洗步骤。 当鞣制铬盐时,产品的作用可以消除碱化的步骤。 本发明的目的是使用新颖的组合物,该组合物可以代替之前描述的仅用于一个称为调理的步骤的步骤6和酸洗步骤8,所述步骤8被称为调节。所提出的系统中和碱度并因此去除溶解度 来自附加在毛皮上的石灰操作中的钙。 所描述的体系由功能性醛得到,其通用配方如下:该体系包含功能性醛,其中加入了一种组合或仅仅是下列化学物质之一:单,二,三和多羧酸; 酸酐:含有至少2至8个碳原子的富马酸,马来酸和二羧酸的酸酐; 单,二,三和多羧酸的酯; EDTA; 硼酸和三聚磷酸钠和三聚磷酸钠作为稳定体系的溶剂,使用下列化合物之一或其混合物:水,支化或非支化脂肪醇,二醇和多元醇。