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    • 24. 发明申请
    • 水処理装置
    • 水处理设备
    • WO2003066529A1
    • 2003-08-14
    • PCT/JP2003/001045
    • 2003-02-03
    • 三洋電機株式会社中西 稔吉田 茂樹広 直樹河内 基樹岸 稔河村 要藏稲本 吉宏廣田 達哉
    • 中西 稔吉田 茂樹広 直樹河内 基樹岸 稔河村 要藏稲本 吉宏廣田 達哉
    • C02F1/461
    • C02F1/4676C02F1/46104C02F2101/16C02F2101/163C02F2201/46125C02F2209/30
    • A structure of a device for automatically controlling a sequence of water treatment to reduce nitrate nitrite ions in water being treated by an electrochemical reaction, to substitute nitrogen gas for the produced ammonia, and thereby to remove the ammonia from the water and a sensing method using such a device for automatically detecting the progress of reduction or denitrification or degradation of the treating capability of the cathode or anode are disclosed. The water treating device comprises a cathode 15 for reducing nitrate nitrite ions by an electrochemical reaction, an anode 16, an electrolytic bath 10 containing the cathode and anode, and a hydrogen gas sensor 30 for measuring the concentration of the hydrogen gas in the electrolytic bath 10. Water to be treated is introduced into the electrolytic bath 10. Current is applied to the water. The end of the reduction of the nitrate nitrite ions or degradation of reduction capability of the cathode 15 can be sensed on the basis of the value measured by the hydrogen gas sensor 30 or the controlled current value of the electrolytic bath 10.
    • 用于自动控制水处理顺序的装置的结构,以减少通过电化学反应处理的水中的硝酸盐亚硝酸根离子,以替代氮气用于产生的氨,并由此从水中除去氨以及使用 公开了一种用于自动检测阴极或阳极的还原或脱氮或降解进程的装置。 水处理装置包括用于通过电化学反应还原硝酸盐亚硝酸根离子的阴极15,阳极16,含有阴极和阳极的电解槽10和用于测量电解槽中的氢气浓度的氢气传感器30 将待处理的水引入电解槽10中。将电流施加于水。 可以基于由氢气传感器30测量的值或电解浴10的受控电流值来检测硝酸亚硝酸根离子的还原结束或阴极15还原能力的降低。
    • 29. 发明申请
    • ELECTROCHEMICAL REDUCTION OF NITRATE IN THE PRESENCE OF AN AMIDE
    • 硝酸盐在电化学中的电化学还原
    • WO01092603A1
    • 2001-12-06
    • PCT/US2001/017681
    • 2001-05-31
    • C02F1/467C25B1/00C25C1/00
    • C02F1/4676C02F2101/16C02F2101/163
    • The electrochemical reduction of nitrates in aqueous solutions thereof in the presence of amides to gaseous nitrogen (N2) is described. Generally, electrochemical reduction of NO3 proceeds stepwise, from NO3 to NO2 , and subsequently in several consecutive steps to ammonia (NH3) as a final product. Addition of at least one amide to the solution being electrolyzed suppresses ammonia generation, since suitable amides react with NO2 to generate N2. This permits nitrate reduction to gaseous nitrogen to proceed by electrolysis. Suitable amides include urea, sulfamic acid, formamide, and acetamide.
    • 描述了在酰胺存在下,将其在含水溶液中的硝酸盐在气态氮(N 2)中的电化学还原。 通常,NO 3 - 的电化学还原逐步进行,从NO 3 - 到NO 2 - ,随后在几个连续步骤中以氨(NH 3)作为最终产物。 在正在电解的溶液中加入至少一种酰胺抑制氨的产生,因为合适的酰胺与NO 2 - 反应产生N 2。 这允许硝酸盐还原成气态氮以通过电解进行。 合适的酰胺包括尿素,氨基磺酸,甲酰胺和乙酰胺。