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    • 21. 发明申请
    • POLYARYLENE ETHER SULFONE (PAES) POLYMERS
    • 聚亚烷基醚(PAES)聚合物
    • WO2014180724A2
    • 2014-11-13
    • PCT/EP2014/058799
    • 2014-04-30
    • SOLVAY SPECIALTY POLYMERS USA, LLC
    • LOUIS, ChantalEL-HIBRI, Mohammad JamalTHOMAS, David B.PATEL, Hemantkumar
    • C08G75/23B05D1/12B29C43/003B29C45/0001B29C47/0004B29C64/106B29K2081/06B33Y10/00B33Y70/00G01N30/02
    • A poly(arylether sulfone) polymer [(t-PAES) polymer, herein after], wherein more than 70 % moles of the recurring units are recurring units (R t ) of formula (St) : -E-Ar 1 -S0 2 -[Ar 2 -(T-Ar 3 ) n -SO 2 ]m-Ar 4 - (formula S t ) wherein : n and m, equal to or different from each other, are independently zero or an integer of 1 to 5, each of Ar 1 , Ar 2 , Ar 3 and Ar 4 equal to or different from each other and at each occurrence, is an aromatic moiety, T is a bond or a divalent group optionally comprising one or more than one heteroatom; - E is of formula (E t ), wherein each of R', equal to or different from each other, is selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; j' is zero or is an integer from 1 to 4, and said (t-PAES) polymer having a number average molecular weight (M n ) ranging from 41 000 to 90 000.
    • 聚(芳基醚砜)聚合物[(t-PAES)聚合物,此后]其中多于70%摩尔的重复单元是式(St)的重复单元(R t):-E-Ar 1 -SO 2 - [Ar 2 - (T-Ar 3)n-SO 2] m -Ar 4 - (式St)其中:n和m彼此相同或不同,分别为0或1〜5的整数,Ar 1,Ar 2,Ar 3 和Ar 4彼此相同或不同,并且在每次出现时均为芳族部分,T为任选包含一个或多于一个杂原子的键或二价基团; - E为式(Et),其中R'彼此相同或不同,各自选自卤素,烷基,烯基,炔基,芳基,醚,硫醚,羧酸,酯,酰胺 酰亚胺,碱金属或碱土金属磺酸盐,烷基磺酸盐,碱金属或碱土金属膦酸盐,烷基膦酸盐,胺和季铵盐; j'为0或1〜4的整数,所述(t-PAES)聚合物的数均分子量(Mn)为41000〜90000。
    • 25. 发明申请
    • Process for the manufacture of terphenyl compounds
    • 制造三联苯化合物的方法
    • WO2015158580A1
    • 2015-10-22
    • PCT/EP2015/057567
    • 2015-04-08
    • SOLVAY SPECIALTY POLYMERS USA, LLC
    • LOUIS, ChantalTHOMAS, David B.
    • C07C37/01C07C39/15C07C67/42C07C45/68
    • C07C37/0555C07C37/01C07C39/15C07C45/68C07C67/42C07C49/784C07C69/16C07C67/12
    • A process for the manufacture of a terphenyl compound [compound (T), herein after] of formula (T): wherein each of R and R', equal to or different from each other, are selected from the group consisting of halogen, alkyl, aryl, ether, thioether, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; - each of j' and k, equal to or different from each other, are zero or are an integer from 1 to 4, including the steps of (i) reacting at least one organozinc compound of formula (I) with at least one dihalocompound of formula (II) in the presence of a catalyst compound; wherein Y is selected from the group consisting of a chloride, a bromide, an iodide, an alkanesulfonate or a fluoroalkanesulfonate anion, R2 is selected from selected from the group consisting of C 1 -C 10 -alkyl, C 3 -C 10 -cycloalkyl, C 1 -C 10 -halooalkyl and C 3 -C 10 halocyclo alkyl, each of Z, equal to or different from each other, are selected from the group consisting of a chloride, a bromide, an iodide, an alkanesulfonate or a fluoroalkanesulfonate anion; (ii) a Bayer-Villiger oxidation and (iii) hydrolysis or alcoholysis.
    • 制备式(T)的本文后三联苯化合物[化合物(T))的方法:其中R和R'彼此相同或不同的各自选自卤素,烷基 芳基,醚,硫醚,酯,酰胺,酰亚胺,碱金属或碱土金属磺酸盐,烷基磺酸盐,碱金属或碱土金属膦酸盐,烷基膦酸盐,胺和季铵盐; - 彼此相同或不同的j'和k中的每一个为零或为1至4的整数,包括以下步骤:(i)使至少一种式(I)的有机锌化合物与至少一种二卤化合物 式(II)的化合物在催化剂化合物的存在下反应; 其中Y选自氯化物,溴化物,碘化物,链烷磺酸盐或氟烷基磺酸根阴离子,R2选自C1-C10-烷基,C3-C10-环烷基,C1-C10 卤代烷基和C 3 -C 10卤代环烷基,Z各自相同或不同,选自氯,溴,碘,烷烃磺酸盐或氟代烷基磺酸根阴离子; (ii)拜耳维利格(Bayer-Villiger)氧化和(iii)水解或醇解。
    • 26. 发明申请
    • PROCESS FOR THE MANUFACTURE OF TERPHENYL COMPOUNDS
    • 三苯甲基化合物的制备方法
    • WO2015136015A1
    • 2015-09-17
    • PCT/EP2015/055114
    • 2015-03-11
    • SOLVAY SPECIALTY POLYMERS USA, LLCSOLVAY SA
    • LOUIS, Chantal
    • C07C37/20
    • C07C37/20C07C39/15
    • A process for the manufacture of terphenyl compounds comprising reacting at least one compound of general formula (I) with at least one cyclic compound and wherein the process is carried out in the presence of a mixture which contains at least one Lewis acid, optionally, at least one thio compound of formula R-S-R' and at least one co-catalyst compound selected from the group consisting of C 1 -C 10 alkanols, C 1 -C 10 amides, C 1 -C 10 ethers and C 1 -C 10 amines; and wherein the ratio of the total molar amount of Lewis acid and co-catalyst compound to the molar amount of compound (C) is equal to or above 5:1 and equal to or below 20:1 and the molar ratio co-catalyst compound to Lewis acid is equal to or above 0.01:1.
    • 一种制备三联苯化合物的方法,包括使至少一种通式(I)的化合物与至少一种环状化合物反应,其中该方法在含有至少一种路易斯酸的混合物存在下进行,任选地, 至少一种式RSR'的硫代化合物和至少一种选自C 1 -C 10链烷醇,C 1 -C 10酰胺,C 1 -C 10醚和C 1 -C 10胺的助催化剂化合物; 并且其中路易斯酸和助催化剂化合物的总摩尔量与化合物(C)的摩尔量之比等于或大于5:1且等于或低于20:1,并且助催化剂化合物 对路易斯酸等于或高于0.01:1。