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11. 发明申请

WO2014201487A1 VERFAHREN UND VORRICHTUNG ZUR ENTSCHWEFELUNG VON GASGEMISCHEN 审中-公开
标题翻译：方法和装置脱硫气体混合
公开(公告)号：WO2014201487A1
公开(公告)日：2014-12-24
申请号：PCT/AT2014/050132
申请日：2014-06-13
申请人： TECHNISCHE UNIVERSITÄT WIEN
发明人： HARASEK, Michael , MAKARUK, Aleksander
IPC分类号： B01D53/52 , B01D53/73 , B01D53/78 , C01B17/05
CPC分类号： B01D53/1468 , B01D53/1418 , B01D53/526 , B01D53/73 , B01D53/78 , B01D2251/106 , B01D2251/30 , B01D2251/604 , B01D2252/102 , B01D2252/204 , B01D2256/245 , B01D2258/05 , C01B17/05 , C10L3/103 , C10L3/104
摘要： Die Erfindung betrifft ein Verfahren zur Entschwefelung eines H 2 S und CO 2 enthaltenden Gasgemischs mittels selektiver Absorption des H 2 S in ein basisches Absorptionsmittel und anschließender Oxidation des absorbierten H 2 S mit einem Oxidationsmittel das dadurch gekennzeichnet ist, dass i) als zu entschwefelndes Gasgemisch ein H 2 und/oder CH 4 enthaltendes, brennbares Biogas eingesetzt wird; ii) nach dem Absorptionsschritt ein Phasentrennschritt zur Abtrennung der flüssigen Phase in Form des mit Sulfid angereicherten Absorptionsmittels von der die brennbaren Gaskomponenten enthaltenden Gasphase durchgeführt wird; und iii) die so entgaste flüssige Phase mit einem Oxidationsmittel in Kontakt gebracht wird, um das Sulfid zu elementarem Schwefel und/oder höheren Oxidationsstufen des Schwefels zu oxidieren.
摘要翻译：本发明涉及一种用于脱硫通过在H 2 S的选择性吸收用氧化剂的装置含有所吸收的H 2 S的基本吸收性和随后氧化为H 2 S和CO 2气体混合物，其特征在于i）其中待脱硫含有H 2和/或CH 4的气体混合物可燃沼气被使用; ii）中进行，在形式的液相中分离的相分离步骤中的硫化物富集从含有气相至吸收步骤可燃性气体成分吸收剂; 和iii）在接触氧化剂如此脱气液体相接触以氧化硫化物为元素硫和/或硫的更高氧化态。

12. 发明申请

WO2012175630A1 Catalytic Oxidation of Sulphide Species 审中-公开
标题翻译：硫化物催化氧化
公开(公告)号：WO2012175630A1
公开(公告)日：2012-12-27
申请号：PCT/EP2012/062005
申请日：2012-06-21
申请人： FRIEDRICH-ALEXANDER-UNIVERSITÄT ERLANGEN-NÜRNBERG , IVANOVIC-BURMAZOVIC, Ivana , FILIPOVIC, Milos
发明人： IVANOVIC-BURMAZOVIC, Ivana , FILIPOVIC, Milos
IPC分类号： C10G27/10 , B01D53/86 , C01B17/05 , C02F1/72
CPC分类号： B01D53/52 , B01D53/8612 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/705 , B01D2256/24 , B01D2257/304 , B01D2258/025 , B01D2258/0283 , B01D2258/05 , B01J31/1616 , B01J31/165 , B01J31/1815 , B01J31/2243 , B01J2231/70 , B01J2531/025 , B01J2531/0252 , B01J2531/842 , B01J2531/845 , B01J2531/847 , B01J2540/42 , B01J2540/54 , B01J2540/64 , C01B17/05 , C02F1/725 , C02F2101/101 , C10G27/10 , C10G2300/207
摘要： The present invention relates to a process for the catalytic oxidation of sulphide, mono- and/or dihydrogen sulphide, comprising the step of contacting the sulphide, mono- and/or dihydrogen sulphide in the presence of oxygen with a chelate complex comprising (i) a metal cation selected from the group consisting of Fez+, Mn z+ , Ni z* and Co z+ , where z = 2 or 3, and (ii) a chelate ligand containing a porphyrin, a phtha!ocyanine or a porphyrazine ring coordinated to the metal cation, and at least one cationic substituent covalentiy attached to the ring in the chelate ligand.
摘要翻译：本发明涉及硫化物，硫化氢和/或二氢化硫的催化氧化方法，包括在氧气存在下使硫化物，硫化氢和/或二氢化氢与螯合络合物接触的步骤，所述螯合络合物包括（i）选自Fez +，Mnz +，Niz *和Coz +的金属阳离子，其中z = 2或3，和（ii）含有与金属阳离子配位的卟啉，酞菁或四氮杂卟啉环的螯合配体，和至少一个阳离子取代基共轭偶联在螯合配体中的环上。

13. 发明申请

WO2012164468A1 METHOD FOR SELECTIVELY REMOVING SULPHUR AND/OR SULPHUR CONTAINING CONTAMINANT COMPOUNDS FROM A GAS FLOW 审中-公开
标题翻译：从气体流中选择性地去除含有污染物质的硫和/或硫的方法
公开(公告)号：WO2012164468A1
公开(公告)日：2012-12-06
申请号：PCT/IB2012/052638
申请日：2012-05-25
申请人： FRAMES BIOGAS PROCESSING B.V. , VERSTEEG, Geert, Frederic , VAN LOO, Sjaak , GERNTHOLTZ, Otto, Carl , IJBEN, Piet , TER MAAT, Henk , WERMINK, Wouter
发明人： VERSTEEG, Geert, Frederic , VAN LOO, Sjaak , IJBEN, Piet , TER MAAT, Henk , WERMINK, Wouter
IPC分类号： B01D53/96 , B01D53/52 , C01B17/033 , C01B17/05
CPC分类号： B01D53/1418 , B01D53/1425 , B01D53/1468 , B01D2258/05 , C01B17/05 , C01B17/06
摘要： The present invention relates to a method for selectively removing sulphur and/or sulphur containing contaminant compounds from a gas flow which includes a method for regenerating spent aqueous absorption liquid. The spent aqueous absorption liquid is regenerated by converting the solid metal salt into solid sulphur and/or a solid sulphur containing compound and converting the corresponding metal salt into the metal ion in solution with aid of a polyvalent second metal (which is the strongest oxidiser). The regeneration process may consist of four process steps: regeneration, oxidation, extraction and crystallisation.
摘要翻译：本发明涉及一种从气流中选择性除去含硫和/或含硫污染化合物的方法，该方法包括再生废水吸收液体的方法。通过将固体金属盐转化成固体硫和/或固体含硫化合物并通过多价第二金属（其是最强氧化剂）将相应的金属盐转化成溶液中的金属离子来再生废水溶液吸收液体，。再生过程可以由四个工艺步骤组成：再生，氧化，萃取和结晶。

14. 发明申请

WO2010112501A1 PROCESS FOR PRODUCING PURIFIED SYNTHESIS GAS 审中-公开
标题翻译：生产纯化合成气的方法
公开(公告)号：WO2010112501A1
公开(公告)日：2010-10-07
申请号：PCT/EP2010/054186
申请日：2010-03-30
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DEN BORN, Isaac Cormelis , VAN HEERINGEN, Gijsbert Jan , SMIT, Cornelis Jacobus , WOLDHUIS, Alex Frederik
发明人： VAN DEN BORN, Isaac Cormelis , VAN HEERINGEN, Gijsbert Jan , SMIT, Cornelis Jacobus , WOLDHUIS, Alex Frederik
IPC分类号： B01D53/14 , C01B3/16 , C01B3/52 , C01B17/04 , C01B17/05
CPC分类号： C01B3/16 , B01D53/1425 , B01D53/1462 , B01D2251/206 , B01D2256/16 , B01D2256/20 , B01D2257/304 , B01D2257/308 , B01D2257/406 , B01D2257/408 , B01D2257/504 , C01B3/52 , C01B17/0408 , C01B17/05 , C01B2203/0415 , C01B2203/0475 , C01B2203/0485 , Y02C10/06 , Y02P20/152
摘要： The invention provides a process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising besides the main constituents carbon monoxide and hydrogen also hydrogen sulphide, carbonyl sulphide and/or hydrogen cyanide and optionally ammonia, the process comprising the steps of: (a) contacting the feed synthesis gas stream with a water gas shift catalyst in a shift reactor in the presence of water and/or steam to react at least part of the carbon monoxide to carbon dioxide and hydrogen and at least part of the hydrogen cyanide to ammonia and/or at least part of the carbonyl sulphide to hydrogen sulphide, to obtain a shifted synthesis gas stream enriched in H2S and in CO 2 and optionally comprising ammonia; (b) removing H 2 S and CO 2 from the shifted synthesis gas stream by contacting the shifted synthesis gas stream with an absorbing liquid to obtain semi-purified synthesis gas and an absorbing liquid rich in H 2 S and CO 2 ; (c) heating at least part of the absorbing liquid rich in H 2 S and CO 2 in a heater to obtain heated absorbing liquid rich in H2S and CO 2 ; (d) de-pressurising the heated absorbing liquid rich in H 2 S and CO 2 in a flash vessel, thereby obtaining flash gas rich in CO 2 and absorbing liquid rich in H 2 S; (e) contacting the absorbing liquid rich in H 2 S at elevated temperature with a stripping gas, thereby transferring H 2 S to the stripping gas to obtain regenerated absorbing liquid and stripping gas rich in H 2 S; (f) converting H 2 S in stripping gas rich in H 2 S to elemental sulphur; (g) removing H 2 S from the semi-purified synthesis gas by converting H 2 S in the semi-purified synthesis gas to elemental sulphur to obtain the purified synthesis gas.
摘要翻译：本发明提供了一种从原料合成气流生产纯化的合成气流的方法，除了主要成分一氧化碳和氢还包括硫化氢，硫化羰和/或氰化氢和任选的氨，该方法包括以下步骤：（ a）在水和/或蒸汽存在下，将转化反应器中的原料合成气流与水煤气变换催化剂接触，使至少一部分一氧化碳与二氧化碳和氢气以及至少部分氰化氢反应至氨和/或至少部分羰基硫化物转化成硫化氢，以获得富含H 2 S和CO 2并任选地包含氨的转移的合成气流; （b）通过使经移动的合成气流与吸收液体接触从移动的合成气流中除去H 2 S和CO 2，以获得富含H 2 S和CO 2的半纯化合成气和吸收液; （c）在加热器中加热至少部分富含H 2 S和CO 2的吸收液体，以获得富含H 2 S和CO 2的加热吸收液; （d）在闪蒸容器中对富含H 2 S和CO 2的加热吸收液进行减压，从而获得富含CO 2的闪蒸气体并吸收富含H 2 S的液体; （e）在升高的温度下将富含H 2 S的吸收液体与汽提气体接触，从而将H 2 S转移到汽提气体中以获得再生的吸收液体和汽提富含H 2 S的气体; （f）将富含H 2 S的汽提气体中的H 2 S转化为元素硫; （g）通过将半纯化合成气中的H 2 S转化为元素硫来从半纯化合成气中除去H 2 S，得到纯化的合成气。

15. 发明申请

WO01056683A1 TREATMENT OF GASEOUS FUELS, ACID GASES AND OFF GASES 审中-公开
标题翻译：气体燃料，酸性气体和关闭气体的处理
公开(公告)号：WO01056683A1
公开(公告)日：2001-08-09
申请号：PCT/PL2000/000009
申请日：2000-02-07
IPC分类号： B01D53/14 , B01D53/52 , B01D53/86 , C01B17/05
CPC分类号： B01D53/8615 , B01D53/1425 , B01D53/1468 , B01D53/52 , B01D2251/90 , C01B17/05
摘要： A process for removing hydrogen sulphide or hydrogen sulphide and organic sulphur compounds from a gas mixture, where the process comprises: contacting the gas mixture with a chelate solution in a vessel (11); regenerating the spent first chelate solution, thereby producing oxidised polyvalent metal chelate solution and a separate stream (22) containing elemental sulphur or elemental sulphur and organic disulphides; containing the said separate stream (22) in a vasel (23) with a solution of a chelating agent, thereby reducing the content of insoluble degradation products of the metal chelates in the system, and producing a spent chelating-agent solution; adding fresh chelate solution to a vessel (30); recirculating the chelate solution from vessel (30) to vessel (11).
摘要翻译：一种从气体混合物中除去硫化氢或硫化氢和有机硫化合物的方法，其中该方法包括：使气体混合物与容器（11）中的螯合溶液接触; 再生废弃的第一螯合溶液，从而产生氧化的多价金属螯合溶液和含有元素硫或元素硫和有机二硫化物的单独流（22）; 将螯合剂溶液中的所述分离物流（22）包含在血管（23）中，从而降低系统中金属螯合物的不溶性降解产物的含量，并制备废螯合剂溶液; 向容器（30）中加入新鲜的螯合溶液; 将螯合溶液从容器（30）再循环到容器（11）。

16. 发明申请

WO00053290A1 METHOD FOR DESULPHURIZATION OF GASES 审中-公开
标题翻译：气体脱硫方法
公开(公告)号：WO00053290A1
公开(公告)日：2000-09-14
申请号：PCT/NL2000/000155
申请日：2000-03-08
IPC分类号： B01D53/52 , B01D53/84 , C01B17/05 , C02F3/34
CPC分类号： B01D53/52 , B01D53/84 , C01B17/05 , Y02A50/2358
摘要： The present invention relates to a method of removing hydrogen sulphide from a gas stream wherein the hydrogen sulphide is scrubbed from the gas phase by means of an aqueous solution, the hydrogen sulphide in the aqueous solution is biologically oxidized in a bioreactor to produce elemental sulphur, and the elemental sulphur is separated from the aqueous solution, characterized in that the gas stream to be treated is cooled to such a degree that at least sufficient water vapour condenses from said gas stream to compensate for the discharge stream for the purpose of removing salts. This means that no water need be supplied to the bioreactor. This method is suitable, in particular, for gas streams which contain hydrogen sulphide, the hydrogen sulphide having been obtained by catalytic conversion of sulphur compounds.
摘要翻译：本发明涉及一种从气流中除去硫化氢的方法，其中硫化氢通过水溶液从气相中洗涤，水溶液中的硫化氢在生物反应器中被生物氧化以产生元素硫，并且元素硫与水溶液分离，其特征在于待处理的气流被冷却至至少足够的水蒸汽从所述气流中冷凝以补偿排出流以除去盐的程度。这意味着不需要向生物反应器供应水。该方法特别适用于含有硫化氢的气流，硫化氢是通过硫化合物的催化转化获得的。

17. 发明申请

WO98055209A1 METHOD AND SYSTEM FOR SELECTIVE REMOVAL OF CONTAMINATION FROM GAS FLOWS 审中-公开
标题翻译：从气体流中选择性去除污染的方法和系统
公开(公告)号：WO98055209A1
公开(公告)日：1998-12-10
申请号：PCT/NL1998/000312
申请日：1998-05-29
IPC分类号： B01D53/50 , B01D53/52 , C01B17/05 , C01B17/20 , C22B3/20 , C22B15/00
CPC分类号： C22B3/20 , B01D53/50 , B01D53/526 , C01B17/05 , C01B17/20 , C22B15/0089 , Y02P10/234 , Y02P10/236
摘要： The invention relates to a method for selectively removing sulphur and/or sulphur containing contaminant compounds from a gas flow, which also comprises CO2, said method comprising the steps of: placing the gas flow into contact with a preselected metal ion at a pH lying in the range of between about -0.05 and about 7.0, wherein the metal ion and the contaminants react together in order to form a solid metal salt of the contaminants which precipitates out of the gas flow, wherein the lower pH limit of about -0.05 substantially ensures that the metal salt formed between the metal ion and the contaminants substantially exclusively is precipitated out of the gas flow, and wherein the upper pH limit substantially ensures that CO2 is not precipitated out of the gas flow as a metal carbonate salt.
摘要翻译：本发明涉及一种从气流中选择性除去含硫和/或含硫污染物化合物的方法，该气流还包括二氧化碳，所述方法包括以下步骤：将气流置于与预选金属离子接触的pH值在约-0.05和约7.0之间的范围，其中金属离子和污染物一起反应以形成从气流中沉淀的污染物的固体金属盐，其中约-0.05的较低pH限度基本上确保在金属离子和污染物之间形成的金属盐基本上仅从气流中沉淀出来，其中上限pH值基本上确保了作为金属碳酸盐的CO 2不会从气流中析出。

18. 发明申请

WO1994012431A1 PROCESS FOR RECOVERING SULFUR AND HYDROGEN FROM HYDROGEN SULFIDE 审中-公开
标题翻译：从硫化氢中回收硫和氢的方法
公开(公告)号：WO1994012431A1
公开(公告)日：1994-06-09
申请号：PCT/US1993008916
申请日：1993-09-20
申请人： MARATHON OIL COMPANY
发明人： MARATHON OIL COMPANY , PLUMMER, Mark, A.
IPC分类号： C01B17/05
CPC分类号： C01B17/05 , B01D53/52 , C01B3/04 , C01B3/22 , C07C46/00 , Y02E60/364 , C07C50/16
摘要： A process for converting hydrogen sulfide which is contained in a gaseous feed stream to elemental sulfur and hydrogen. The process comprises contacting said gaseous feed stream with a polar organic solvent having an anthraquinone, and optionally a complexing agent, dissolved therein, reacting the hydrogen sulfide gas and anthraquinone to produce sulfur and an anthrahydroquinone in the solvent, and catalytically dehydrogenating the anthrahydroquinone to anthraquinone and hydrogen. In accordance with the present invention, a relatively small quantity of water is added to a polar organic solvent thereby increasing the elemental sulfur which is precipitated and thus recovered. The addition of water prior to or during sulfur production also increases hydrogen product selectivity in the subsequent dehydrogenation of anthrahydroquinone.
摘要翻译：将气态进料流中包含的硫化氢转化为元素硫和氢的方法。该方法包括使所述气态进料流与溶解有蒽醌和任选的络合剂的极性有机溶剂接触，使硫化氢气体和蒽醌反应，在溶剂中产生硫和蒽醌，并将蒽醌催化脱氢成蒽醌和氢气。根据本发明，将相对少量的水加入到极性有机溶剂中，从而增加沉淀并因此回收的元素硫。在硫生产之前或期间加入水还可以在随后的蒽氢醌脱氢中提高氢产物的选择性。

19. 发明申请

WO1993002961A1 REMOVAL OF HYDROGEN SULPHIDE 审中-公开
标题翻译：去除氢硫化物
公开(公告)号：WO1993002961A1
公开(公告)日：1993-02-18
申请号：PCT/GB1992001328
申请日：1992-07-20
申请人： McKENNA, Antonia, Francesca, Evelyna +ef , SOLVAY INTEROX LIMITED , CLAPP, Phillip, Anthony
发明人： McKENNA, Antonia, Francesca, Evelyna +ef , SOLVAY INTEROX LIMITED , EVANS, Dennis, Frederick +di
IPC分类号： C01B17/05
CPC分类号： B01D53/1493 , B01D53/1418 , B01D53/8612 , C01B15/022 , C01B17/05
摘要： Hydrogen sulphide can be removed from a gaseous stream by contact with a 2,3-dialkyl substituted naphthoquinone in the presence of a catalytic amount of an amine catalyst dissolved in a hydrophobic organic solvent system, with consequential formation of a corresponding quinhydrone and insoluble elemental sulphur. Preferably the total number of carbons in the alkyl substituents is from 2 to 6. Particularly suitable compounds comprise dimethyl and/or ethyl/methyl naphthoquinones. Preferably the amine catalyst has a pK in the range of about 9 to 11.5. Preferred solvent systems comprise mixtures of aromatic hydrocarbons with aliphatic esters such as methyl cyclohexanol acetate or dialkylketones such as diisobutylcarbinol. Advantageously, the naphthoquinones react with hydrogen sulphide significantly faster than do the anthraquinone or tetrahydroanthraquinone compounds hitherto proposed. The insoluble sulphur can be recovered as product and the resultant solution containing a reduced species, believed to be naphthoquinhydrone, can be contacted with an oxygen-containing gas for generation of hydrogen peroxide and reformation of the naphthoquinone. After extraction of the hydrogen peroxide with water, the organic solution is available for contact with further hydrogen sulphide.
摘要翻译：可以在催化量的溶解在疏水性有机溶剂体系中的胺催化剂存在下，与2,3-二烷基取代的萘醌接触，从气态物流中除去硫化氢，从而形成相应的醌氢醌和不溶性元素硫。优选地，烷基取代基中的碳原子数为2至6.特别合适的化合物包括二甲基和/或乙基/甲基萘醌。优选地，胺催化剂的pK在约9至11.5的范围内。优选的溶剂体系包括芳族烃与脂肪族酯的混合物，例如甲基环己醇乙酸酯或二烷基酮如二异丁基甲醇。有利地，萘醌与硫化氢反应显着地快于迄今提出的蒽醌或四氢蒽醌化合物。可以回收不溶性硫作为产物，并且将含有被认为是萘醌氢醌的还原物质的所得溶液与含氧气体接触以产生过氧化氢并重整萘醌。用水萃取过氧化氢后，有机溶液可与另外的硫化氢接触。

20. 发明申请

WO1991000243A1 REMOVAL OF HYDROGEN SULFIDE FROM PRODUCED FLUIDS 审中-公开
标题翻译：从生产的流体中除去氢硫化物
公开(公告)号：WO1991000243A1
公开(公告)日：1991-01-10
申请号：PCT/US1990003647
申请日：1990-06-26
申请人： UNION OIL COMPANY OF CALIFORNIA
发明人： UNION OIL COMPANY OF CALIFORNIA , STOUT, Charles, A.
IPC分类号： C01B17/05
CPC分类号： C09K8/54 , C01B17/05 , C10L1/328
摘要： Hydrogen sulfide is removed from a water-in-oil emulsion by treatment of the emulsion with sulfur dioxide to convert the hydrogen sulfide to elemental sulfur. The elemental sulfur formed is distributed between the oil phase and the aqueous phase of the emulsion.

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