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11. 发明申请

WO01070649A1 METHOD FOR REDUCING ORGANIC COMPOUNDS IN A MICROREACTOR BY MEANS OF HYDRIDES AND/OR THE DERIVATIVES THEREOF 审中-公开
标题翻译：程序由氢化物和/或其衍生物在微反应器有机化合物还原
公开(公告)号：WO01070649A1
公开(公告)日：2001-09-27
申请号：PCT/EP2001/002302
申请日：2001-03-01
IPC分类号： C07D233/22 , B01J19/00 , C07B31/00 , C07B41/02 , C07B61/00 , C07C29/147 , C07D233/54 , C07D233/58 , C07B45/06
CPC分类号： C07D233/64 , B01J19/0093 , B01J2219/00873 , B01J2219/00984 , C07B31/00 , C07B41/02 , C07C29/147
摘要： The present invention relates to a method for reducing aliphatic, aromatic or heterocyclic organic compounds by means of hydrides and/or the derivatives thereof. The inventive method is characterised in that the reaction is carried out in a microreactor.
摘要翻译：本发明涉及一种使用氢化物和/或它们的衍生物的脂肪族，芳香族或杂环的有机化合物的还原过程，其特征在于反应发生在微反应器。

12. 发明申请

WO99054332A1 PREPARATION OF ALKYLTHIO- AND/OR ARYLTHIO-SUBSTITUTED DIKETO-DIARYL-PYRROLOPYRROLES 审中-公开
标题翻译：烷基 - 和/或芳基取代的二酮 - 二异丙基吡咯烷的制备
公开(公告)号：WO99054332A1
公开(公告)日：1999-10-28
申请号：PCT/EP1999/002513
申请日：1999-04-14
IPC分类号： C07D487/04 , C07D519/00 , C08K5/3415 , C08K5/3417 , C08L101/00 , C09B57/00 , C09B67/22 , A61K31/40 , C07B45/06
CPC分类号： C09B57/004 , C08K5/3415 , C09B67/0039
摘要： Preparation of alkylthio and/or arylthio-substituted diketo-diaryl-pyrrolopyrroles (DPPs) of formula (Ia) and dithio-bridged bis-diketo-diaryl-pyrrolopyrroles (bis-DPPs) of formula (Ib), in which in formula (Ia) G is phenyl substituted by at least one arylthio or alkylthio group, and G1 is G or a carbocyclic or heterocyclic radical, by reacting a haloaryl with a thiol or thiolate, and in formula (Ib) G5 is a phenylene, G6 is G1 but not G, and G7 is alkylene, cycloalkylene or phenylene, by reacting two haloaryls with a dithiol or dithiolate, which comprises reacting a thiol or thiolate with a halo-diketo-diaryl-pyrrolopyrrole ("halo-DPP") of formula (IIa) in which G2 is a halogenated phenyl group and G3 is G2 or G1, or reacting a dithiol or dithiolate with two halo-diketo-diaryl-pyrrolopyrroles ("halo-DPPs") of formula (IIb) in which Hal is halogen such as fluorine, chlorine, bromine or iodine, and G6 is G1, and also novel DPPs and also bis-DPPs, compositions comprising DPPs of formula (Ia) prepared in accordance with the invention, and their uses.
摘要翻译：式（Ia）的烷硫基和/或芳硫基取代的二酮 - 二芳基 - 吡咯并吡咯（DPP）和式（Ib）的二硫桥联的双 - 二 - 二芳基 - 吡咯并吡咯（bis-DPP），其中在式）G是被至少一个芳硫基或烷硫基取代的苯基，并且G 1是G或碳环或杂环基，通过卤代芳基与硫醇或硫醇盐反应，而在式（Ib）中，G 5是亚苯基，G 6是G 11，但是通过使两个卤代芳基与二硫醇或二硫醇盐反应，其中G 7是亚烷基，亚环烷基或亚苯基，其包括使硫醇或硫醇盐与式（IIa）的卤代二酮 - 二芳基 - 吡咯并吡咯（“卤代DPP”）反应，其中G2是卤代苯基，G3是G2或G1，或使二硫醇或二硫醇盐与Hal（其中Hal是卤素如氟）的二卤代二酮 - 二芳基 - 吡咯并吡咯（“卤代DPP”）反应，氯，溴或碘，G 6是G 1，以及新的DPP和双DPP，包含式（Ia）及其用途。

13. 发明申请

WO2018045090A1 BISPECIFIC ANTIBODIES 审中-公开
标题翻译：双特异性抗体
公开(公告)号：WO2018045090A1
公开(公告)日：2018-03-08
申请号：PCT/US2017/049472
申请日：2017-08-30
申请人： IMMUNOMAB, INC.
发明人： MIAO, Zhenwei , ZHANG, Fen , LU, Jennifer
IPC分类号： C07K16/46 , A61K39/395 , A61K47/54 , C07B45/06 , A61P35/00
摘要： In certain aspects, bispecific antibodies and uses thereof are provided.
摘要翻译：在某些方面，提供双特异性抗体及其用途。

14. 发明申请

WO2012041858A1 A PROCESS FOR THE SYNTHESIS OF THIO-TRIAZOLO-GROUP CONTAINING COMPOUNDS 审中-公开
标题翻译：用于合成含有三氮杂环基的化合物的方法
公开(公告)号：WO2012041858A1
公开(公告)日：2012-04-05
申请号：PCT/EP2011/066777
申请日：2011-09-27
申请人： BASF SE , DOCHNAHL, Maximilian , KEIL, Michael , GEBHARDT, Joachim , VOGELBACHER, Uwe Josef , RACK, Michael
发明人： DOCHNAHL, Maximilian , KEIL, Michael , GEBHARDT, Joachim , VOGELBACHER, Uwe Josef , RACK, Michael
IPC分类号： C07D405/06 , C07F3/02 , C07B45/06
CPC分类号： C07D405/02 , C07D249/10 , C07D405/06 , C07F3/02 , Y02P20/582
摘要： The present invention relates to a process using specific magnesium reagents for providing thio-triazolo group-containing compounds and for the synthesis of precursors therefor. The invention furthermore relates to intermediates and to their preparation.
摘要翻译：本发明涉及使用特定的镁试剂来提供含硫代三唑基的化合物和用于合成其前体的方法。本发明还涉及中间体及其制备方法。

15. 发明申请

WO2008136770A1 POLY-N-HETEROCYCLIC CARBENE TRANSITION METAL COMPLEXES AND N-HETEROCYCLIC CARBENE TRANSITION METAL COMPLEXES FOR CARBON-SULFUR AND CARBON-OXYGEN COUPLING REACTIONS 审中-公开
标题翻译：用于碳硫和碳氧联合反应的聚-N-杂环碳酸盐过渡金属络合物和N-杂环碳酸盐转移金属络合物
公开(公告)号：WO2008136770A1
公开(公告)日：2008-11-13
申请号：PCT/SG2008/000157
申请日：2008-05-02
申请人： AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH , ZHANG, Yugen , YING, Jackie Y. , ZHAO, Lan
发明人： ZHANG, Yugen , YING, Jackie Y. , ZHAO, Lan
IPC分类号： C07B41/04 , C07B45/06 , C07F15/04
CPC分类号： C07F15/04 , C07B41/04 , C07B45/06 , Y02P20/582
摘要： Methods for carbon-sulfur (C S) or carbon-oxygen (C-O) coupling reactions are provided. The methods involve the use of a transition metal complex comprising a heterocyclic carbene ligand complexed with a transition metal. Transition metal complexes comprising a heterocyclic carbene ligand complexed with nickel are also provided. The nickel heterocylic carbene complexes may be used for C-S or C-O coupling reactions.
摘要翻译：提供了碳 - 硫（C）或碳 - 氧（C-O）偶合反应的方法。所述方法包括使用包含与过渡金属络合的杂环卡宾配体的过渡金属络合物。还提供了包含与镍络合的杂环卡宾配体的过渡金属络合物。镍杂环卡宾络合物可用于C-S或C-O偶联反应。

16. 发明申请

WO2004029022A3 CATALYTIC METHOD OF PRODUCING MERCAPTANS FROM THIOETHERS 审中-公开
标题翻译：从硫醚生产MERCAPTANS的催化方法
公开(公告)号：WO2004029022A3
公开(公告)日：2004-05-06
申请号：PCT/FR0302790
申请日：2003-09-23
申请人： ATOFINA , FREMY GEORGES , ESSAYEM NADINE , LACROIX MICHEL , ZAUSA ELODIE
发明人： FREMY GEORGES , ESSAYEM NADINE , LACROIX MICHEL , ZAUSA ELODIE
IPC分类号： C07B45/06 , C07C319/06 , C07C321/04 , B01J27/182 , B01J21/18 , B01J23/30 , B01J27/186 , C07C319/04
CPC分类号： C07B45/06 , C07C319/06 , C07C321/04
摘要： The invention relates to a method of producing a mercaptan from a thioether and hydrogen sulphide. The inventive method is performed in the presence of hydrogen and a catalytic composition comprising a strong acid, such as a heteropolyacid, and at least one metal from group VIII of the periodical table.
摘要翻译：本发明涉及由硫醚和硫化氢生产硫醇的方法。本发明方法在氢和包含强酸如杂多酸和至少一种来自周期表第VIII族的金属的催化组合物存在下进行。

17. 发明申请

WO02036538A1 PROCESS FOR PRODUCING ESTERIFICATED CONDENSATE 审中-公开
标题翻译：生产精制冷凝液的方法
公开(公告)号：WO02036538A1
公开(公告)日：2002-05-10
申请号：PCT/JP2001/007195
申请日：2001-08-23
IPC分类号： B01J27/135 , B01J31/02 , B01J31/22 , B01J31/38 , C07B61/00 , C07C67/08 , C07C69/24 , C07C69/612 , C07C69/618 , C07C69/734 , C07C69/75 , C07C69/753 , C07C69/78 , C07C201/14 , C07C205/56 , C07C327/20 , C07C327/22 , C07D309/30 , C07D313/04 , C08G63/81 , C08G63/85 , C07B41/12 , C07B45/06
CPC分类号： B01J31/0212 , B01J27/135 , B01J31/2208 , B01J2231/40 , B01J2531/40 , C07C67/08 , C07C327/22 , C07D309/30 , C08G63/81 , C08G63/85 , C07C69/007 , C07C69/013 , C07C69/017 , C07C69/003 , C07C69/612 , C07C69/618 , C07C69/75 , C07C69/24 , C07C69/734 , C07C69/78
摘要： A process for producing an esterificated condensate, wherein a monomeric ester or thioester, or a polyester or polythioester is produced by carrying out a direct condensation reaction from a carboxylic acid and an equimolar amount of an alcohol or a little excess amount of a thiol in a non-polar solvent such as toluene using, as a (poly)condensation catalyst, a tetravalent hafnium compound, typically, hafnium(IV) chloride, in particular hafnium(IV) chloride . (THF)2 and hafnium(IV) butoxide in an oxygen-free atmosphere under reflux. During refluxing with heating, water being distilled as an azeotropic mixture is preferably removed from the reaction system. The process permits a catalytic esterification using equimolar amounts of a carboxylic acid and an alcohol and a catalytic thioesterification using a carboxylic acid and an equimolar or a little excess amount of a thiol, and accordingly is greatly promising as a commercial process for a large scale production from the view point of green chemistry.
摘要翻译：制备酯化缩合物的方法，其中通过在羧酸和等摩尔量的醇或少量过量的硫醇中进行直接缩合反应来制备单体酯或硫酯或聚酯或聚硫酯非极性溶剂如甲苯，使用（多）缩合催化剂，四价铪化合物，通常为氯化铪（IV），特别是氯化铪（IV）。（THF）2和铪（IV），在无氧气氛中回流。在加热回流期间，优选从反应体系中除去作为共沸混合物蒸馏的水。该方法允许使用等摩尔量的羧酸和醇进行催化酯化和使用羧酸和等摩尔或少量过量的硫醇进行催化硫酯化，因此作为大规模生产的商业方法是非常有希望的从绿色化学的角度。

18. 发明申请

WO1994012450A1 METHOD OF PREPARING SULFUR-CONTAINING COMPOUNDS 审中-公开
标题翻译：制备含硫化合物的方法
公开(公告)号：WO1994012450A1
公开(公告)日：1994-06-09
申请号：PCT/NL1993000254
申请日：1993-11-29
申请人： TECHNISCHE UNIVERSITEIT DELFT , DE GRAAF, Willem , DE LEEUW, Jan, Willem , SINNINGHE, Damsté, Jacobus, Smede
发明人： TECHNISCHE UNIVERSITEIT DELFT
IPC分类号： C07B45/06
CPC分类号： C08K5/37 , C07B45/06 , C07C319/24 , C07D331/04 , C07D335/02 , C07D339/00 , C07D339/04 , C08G75/14 , C08K5/45 , C08L21/00 , C07C321/14
摘要： The invention relates to a method of preparing sulfur-containing compounds, comprising reacting a sulfur compound with a compound containing unsaturated carbon-carbon bonds, wherein in a solvent one or more compounds containing non-activated unsaturated carbon-carbon bonds react with monohydrogen polysulfides. The invention further relates to methods of preparing polymeric polysulfides, heterocyclic sulfur compounds and of vulcanizing rubber.
摘要翻译：本发明涉及一种制备含硫化合物的方法，包括使硫化合物与含有不饱和碳 - 碳键的化合物反应，其中在一种或多种含非活化不饱和碳 - 碳的化合物的溶剂中，与单氢多硫化物反应。本发明还涉及制备聚合多硫化物，杂环硫化合物和硫化橡胶的方法。

19. 发明申请

WO2022008283A1 REAGENTS FOR THE POLYFLUOROALKYLTHIOLATION OF ORGANIC COMPOUNDS AND METHOD FOR PRODUCTION THEREOF 审中-公开
公开(公告)号：WO2022008283A1
公开(公告)日：2022-01-13
申请号：PCT/EP2021/067690
申请日：2021-06-28
申请人： UNIVERSITAT ROVIRA I VIRGILI , FUNDACIÓ EURECAT
发明人： MESTRE, Jordi , BOUTUREIRA, Omar , CASTILLON, Sergio , BERNUS, Miguel
IPC分类号： C07D275/06 , C07C311/03 , C07C311/17 , C07C311/52 , C07B45/06
摘要： The present invention to a group of compounds of formula (I) useful for the transfer of polyfluoroalkylthiol groups of at least two carbons atoms into a great variety of organic compounds as well as to the process for their preparation. The invention is also directed to the method for the polyfluoroalkylthiolation of an organic compound with the reagents of the invention.

20. 发明申请

WO2017024092A1 METAL-CATALYZED OXIDATIVE COUPLING OF THIOLS 审中-公开
标题翻译：金属催化氧化氧化偶联
公开(公告)号：WO2017024092A1
公开(公告)日：2017-02-09
申请号：PCT/US2016/045464
申请日：2016-08-04
申请人： ECOLAB USA INC.
发明人： ANANTANENI, Prakasa Rao , HARRINGTON, Ryan , LAURENT, Boyd
IPC分类号： C07C319/24 , C07B45/06 , C07B33/00 , C01G53/00 , C01G53/10 , B01J23/755
CPC分类号： C07C319/24 , C07C323/52 , C07C323/12 , C07C323/25 , C07C321/04 , C07C321/28 , C07C323/33 , C07C321/10
摘要： Disclosed are methods for preparing disulfide compounds through oxidative coupling of thiol compounds. Thiols are oxidized to the corresponding disulfide compound in high yield in presence of a base and a metal salt. The method uses low catalyst loadings and provides organic disulfide compounds with little to no byproducts.
摘要翻译：公开了通过硫醇化合物的氧化偶联制备二硫化物的方法。在碱和金属盐的存在下，硫醇以高产率氧化成相应的二硫化物。该方法使用低催化剂负载量，并提供几乎没有副产物的有机二硫化物。

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