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    • 12. 发明申请
    • (METH)ACRYLOXY GROUPS-CONTAINING ORGANOSILICIC COMPOUNDS, THEIR PREPARATION AND USE
    • (甲基)丙烯酰氧基有机硅化合物,其生产和使用
    • WO1997003110A1
    • 1997-01-30
    • PCT/EP1996003036
    • 1996-07-11
    • WACKER-CHEMIE GMBHDAUTH, JochenDEUBZER, BernwardMAHR, GünterGRATZL, PetraOTT, Monika
    • WACKER-CHEMIE GMBH
    • C08G77/38
    • C09D183/06C08G77/20C08G77/38
    • New (meth)acryloxy groups-containing organosilicic compounds are disclosed with units having the formula (I), in which R are the same or different and stand for a monovalent, optionally halogenated hydrocarbon rest with 1 to 18 carbon atoms per rest or a rest having the formula -R'-[OCH2CH2]o-[OCH(CH3)CH2]p-[O(CH2)4]q-OR'', in which X are the same or different and stand for a chlorine atom or a rest having the formula -OR , in which R', R'', R , o, p and q have the meaning given in the first claim, a equals 0 or 1, b equals 0, 1, 2 or 3, c equals 0, 1, 2 or 3 and the sum a+b+c stands for a linear or branched alkylene rest with 1 to 8 carbon atoms per rest, that may optionally contain ether, amine, sulphide, ester, amide, urea and urethane groups, R stands for a hydrogen atom or a methyl rest, and Y are the same or different and stand for a hydrogen atom or a linear or branched alkyl rest with 1 to 6 carbon atoms per rest or have the meaning given in the first claim, provided that at least one rest A be contained in each molecule.
    • 新的(甲基)(I)式的单元:其中R是相同的或不同的,一价,任选卤代的烃基,其具有每个基1至18个碳原子(一个或多个)或下式基团-R的“有机硅化合物的含丙烯酰氧基 - [OCH 2 CH 2] 邻 - [OCH(CH 3)CH 2] p - [O(CH 2)4] q-OR 'X相同或不同,代表氯原子或一个式的基团-OR <1>,其中R',R“ ,R <1>,O,p和q具有权利要求1中所示的含义,a是0或1,b为0,1,2或3,c为0,1,2或3,并且a + b之+ C < / = 4,A为基团的式(a)中,其中z为1,2,3,4或5,R <2>是直链或支链亚每个基团,具有1至8个碳原子(一个或多个),其任选醚 可以含有,胺,硫醚,酯,酰胺,脲和氨基甲酸酯基团,R <3>是一个氢原子或一个甲基基团和Y相同或不同,表示碳原子数为1〜6的氢原子或直链或支链烷基, - (一个或多个).J ë基团或如在权利要求1具有中所定义,条件是至少一个基团A是每个分子中存在的条件,进行说明。
    • 15. 发明申请
    • SOLVENT-RESISTANT TEXTILE BINDER
    • 耐溶剂性粘结剂纺织品
    • WO1996008597A1
    • 1996-03-21
    • PCT/EP1995003623
    • 1995-09-14
    • WACKER-CHEMIE GMBHLUMPP, AndreasKÖGLER, Gerhard
    • WACKER-CHEMIE GMBH
    • D06M15/29
    • D04H1/587D04H1/4258D04H1/64D06M15/227D06M15/244D06M15/263D06M15/285D06M15/29D06M15/333Y10T428/2933Y10T428/3188Y10T428/31935
    • The invention pertains to the use of N-(alkoxymethyl)-meth(acrylamide-functional textile binders to improve resistance to solvents in finishing and stabilizing fiber materials with textile binders, characterized in that the textile binder used is an aqueous copolymer dispersion or a redispersible copolymer powder of copolymers with a Tg of -60 DEG C to +60 DEG C, containing (a) one or more monomer units from the group consisting of vinyl esters of unbranched or branched carboxylic acids with 1 to 12 carbon atoms, esters of acrylic acid and methacrylic acid with unbranched or branched alcohols with 1 to 12 carbon atoms, vinyl aromatics, vinyl halides and alpha -olefins, and (b) 0.3 to 10 wt %, relative to the total weight of the copolymer, of one or more N-(alkoxymethyl)-acrylamides or N-(alkoxymethyl)methacrylamides with a C1-C6 alkyl residue, or mixtures of these N-(alkoxymethyl)-meth(acrylamides with N-methylolacrylamide and/or N-methylolmethacrylamide in a weight ratio of N-methylol compound to N-(alkoxymethyl) compound of at most 5:1.
    • 本发明提供了N-(烷氧基甲基)的 - (甲基)丙烯酰胺官能化纺织品粘合剂用于改善在整理并用纺织品的粘合剂的纤维材料的接合,其特征在于,作为织物粘合剂,含水共聚物分散体或具有共聚物的可再分散的共聚物粉末的溶剂的电阻 的-60℃下的Tg到60℃下,包含(a)选自下组的一种或多种单体单元选自由具有1至12个碳原子,丙烯酸和甲基丙烯酸与非支化或支化的醇的酯的直链或支化的羧酸的乙烯基酯的 具有1至12个C原子的,乙烯基芳族化合物,乙烯基卤化物和α-烯烃和(b)0.3〜10重量%,基于该共聚物,一种或多种N-(烷氧基甲基)或N-(烷氧基甲基)甲基丙烯酰胺的总重量计的丙烯酰胺 用C1至C6烷基,或这些N-(烷氧基甲基)的混合物 - (甲基)与N-丙烯酰胺Methylolacry lamid和/或N-羟甲基甲基中N-羟甲基化合物与N-(烷氧基甲基)的不超过5化合物的重量比。使用1