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11. 发明申请

WO2022150414A1 FLUORINE SUBSTITUTED UNSYMMETRICAL ETHERS, AND COMPOSITIONS, METHODS AND USES INCLUDING SAME 审中-公开
公开(公告)号：WO2022150414A1
公开(公告)日：2022-07-14
申请号：PCT/US2022/011350
申请日：2022-01-05
申请人： HONEYWELL INTERNATIONAL INC.
发明人： RAMANATHAN, Sudharshanam , PAPANASTASIOU, Dimitrios , NAIR, Haridasan, K.
IPC分类号： C09K5/10 , H05K7/20 , H01M10/613
摘要： Compositions and methods comprising one or more compounds according to Formula I: where R1, R2 and R3 are each independently CxR'(2x+1)-yHy; each R' is independently selected from F or Cl and wherein the value of (2x+1)-y is the total number of R' substituents on the indicated carbon atom(s); each x is independently equal to or greater than 1 and equal to or less than 6; and y is equal to or greater than 0 and less than or equal to 2x+1, provided that the total number of R' present in the compound is 6 or greater, and that the compound has from zero up to two (2) Cl substituents.

12. 发明申请

WO2010105120A2 METHODS AND REACTOR DESIGNS FOR PRODUCING PHOSPHORUS PENTAFLUORIDE 审中-公开
标题翻译：生产磷酸二氢钠的方法和反应器设计
公开(公告)号：WO2010105120A2
公开(公告)日：2010-09-16
申请号：PCT/US2010/027073
申请日：2010-03-12
申请人： HONEYWELL INTERNATIONAL INC. , LULY, Matthew, H. , SMITH, Robert, A. , NAIR, Haridasan, K. , DEPRATO, Philip , POKROVSKI, Konstantin, A. , MERKEL, Daniel, C. , UHRICH, Kevin , COTTRELL, Stephen, A. , BRENNER, Daniel, J.
发明人： LULY, Matthew, H. , SMITH, Robert, A. , NAIR, Haridasan, K. , DEPRATO, Philip , POKROVSKI, Konstantin, A. , MERKEL, Daniel, C. , UHRICH, Kevin , COTTRELL, Stephen, A. , BRENNER, Daniel, J.
IPC分类号： C01B25/10 , C01B25/455 , C01B9/08 , B01J12/00 , B01J19/26
CPC分类号： C01B25/10 , B01J4/002 , B01J12/00 , B01J19/24 , C01B25/455
摘要： Processes and systems for the production of phosphorus pentafluoride (PF5) through continuous fluorination of phosphorus are provided herein. A phosphorus feed stream and a fluorine feed stream are provided to a reactor, wherein they are reacted in a gas-gas or liquid-gas reaction to produce phosphorus pentafluoride (PF5). The phosphorus feed can be derived from white phosphorus or yellow phosphorus, and can be provided to the reactor as a liquid or a vapor. The fluorine can be provided to the reactor as a vapor, and preferably comprises elemental fluorine gas.
摘要翻译：本文提供了通过连续氟化磷生产五氟化磷（PF5）的方法和系统。将磷进料流和氟进料流提供给反应器，其中它们在气 - 气或液 - 气反应中反应以产生五氟化磷（PF 5）。磷进料可以来自白磷或黄磷，并且可以作为液体或蒸气提供给反应器。可以将氟作为蒸气提供给反应器，并且优选地包含元素氟气。

13. 发明申请

WO2007005088A2 VAPORIZABLE METALORGANIC COMPOUNDS FOR DEPOSITION OF METALS AND METAL-CONTAINING THIN FILMS 审中-公开
标题翻译：用于沉积金属和含金属薄膜的可汽化金属有机化合物
公开(公告)号：WO2007005088A2
公开(公告)日：2007-01-11
申请号：PCT/US2006/014752
申请日：2006-04-17
申请人： HONEYWELL INTERNATIONAL INC. , THENAPPAN, Alagappan , LAO, Jingyu , NAIR, Haridasan, K. , DEVI, Anjana , BHAKTA, Raghunandan , MILANOV, Andrian
发明人： THENAPPAN, Alagappan , LAO, Jingyu , NAIR, Haridasan, K. , DEVI, Anjana , BHAKTA, Raghunandan , MILANOV, Andrian
IPC分类号： C07F7/00 , C07F9/00 , C23C16/00 , H01L21/00
CPC分类号： C23C16/45553 , C07F7/006 , C07F9/005 , C23C16/405
摘要： A new class of metalorganic vaporizable compounds with mixed ligands is described herein, along with their use for the deposition of thin films of metals and metal- containing oxides, nitrides, oxynitrides, silicates, suicides, metal containing materials, and combinations thereof. . The metalorganic vaporizable compounds comprise amides in combination with malonates and guanidinates as donor-functionalized bidentate chelating ligands. The use of a metalorganic vaporizable compounds with mixed ligands to deposit and modify thin films of Hf, Zr, Ti, Ta, Al, Sn, Zn, Ca, Mg, Ga, In, Tl, Sc, Bi, Rh, Ir, La, Pr, Eu, Gd, Ba, Sr, and other lanthanide metal oxides, nitrides, oxynitrides, silicates, suicides, and composites, and further use of metalorganic vaporizable compounds with mixed ligands to deposit thin films of Ru, Cu, Co, Ag, Au, Pd, Pt, Ni, Fe, Mn, Cr, V, Nb, Pb, W, Si, Ge and Mo metals, metal oxides, nitrides, oxynitrides, silicates, suicides and combinations thereof are also described herein. A process for the preparation of metalorganic vaporizable compounds comprising amides in combination with donor-functionalized bidentate chelating ligands as a mixed ligand system is described herein. In addition, the use of metalorganic vaporizable compounds in various vapor phase deposition processes such as metal organic chemical vapor deposition (MOCVD) and atomic layer deposition (ALD) of metals and metal-containing oxide thin films is described herein.
摘要翻译：本文描述了一类具有混合配体的新型有机金属可汽化化合物，以及它们用于沉积金属和含金属氧化物，氮化物，氮氧化物，硅酸盐，硅化物，含金属材料及其组合。。有机金属可汽化化合物包含酰胺与丙二酸盐和胍盐作为供体官能化二齿螯合配体。使用具有混合配体的金属有机气化性化合物来沉积和改性Hf，Zr，Ti，Ta，Al，Sn，Zn，Ca，Mg，Ga，In，Tl，Sc，Bi，Rh，Ir，La ，Pr，Eu，Gd，Ba，Sr和其它镧系金属氧化物，氮化物，氮氧化物，氮氧化物，硅酸盐，硅化物和复合物，以及进一步使用具有混合配体的金属有机气化化合物来沉积Ru，Cu，Co，，Au，Pd，Pt，Ni，Fe，Mn，Cr，V，Nb，Pb，W，Si，Ge和Mo金属，金属氧化物，氮化物，氮氧化物，硅酸盐，硅化物及其组合。本文描述了制备包含酰胺和供体官能化二齿螯合配体作为混合配体体系的金属有机可汽化化合物的方法。此外，本文描述了在各种气相沉积工艺如金属有机化学气相沉积（MOCVD）和原子层沉积（ALD）中金属和含金属氧化物薄膜的各种气相沉积工艺中使用金属有机可气化化合物。

14. 发明申请

WO2006063069A2 CATALYTIC CONVERSION OF HYDROFLUOROALKANOL TO HYDROFLUOROALKENE 审中-公开
标题翻译：氢氟烯烃催化转化为氢氟烯烃
公开(公告)号：WO2006063069A2
公开(公告)日：2006-06-15
申请号：PCT/US2005/044298
申请日：2005-12-09
申请人： HONEYWELL INTERNATIONAL INC. , MUKHOPADHYAY, Sudip , NAIR, Haridasan, K. , TUNG, HsuehSung
发明人： MUKHOPADHYAY, Sudip , NAIR, Haridasan, K. , TUNG, HsuehSung
IPC分类号： C07C17/00 , C07C21/18
CPC分类号： C07C17/00 , C07C17/25 , C07C21/18
摘要： Methane is used as the selective dehydrating agent for the production of 2,3,3,3-tetrafluoro-l-propene (R1234yf) from 2,2,3,3,3-pentafluoro-l-propanol. Supported transition metal catalysts are prepared and used for this reaction with high activity. Almost 58% selectivity to R1234yf is obtained at an alcohol conversion level of 60% using unsupported Ni-mesh as the catalyst. Pd and Pt show almost similar level of conversion; however, the selectivity to the desired product is low. The activity of the metal catalyst was found to be a function of the type of support material, activated carbon showing better activity than alumina. Different important process parameters such as temperature, pressure, and contact time are studied to optimize the process. High pressure and temperature are deleterious to the rate of 1234yf formation; yet, the highest yield to 1234yf is obtained while performing a reaction at 494°C with a contact time of 23 sec.
摘要翻译：使用甲烷作为选择性脱水剂，用于从2,2,3,3,3-五氟-1生产2,3,3,3-四氟-1-丙烯（R1234yf）丙醇。制备负载型过渡金属催化剂并用于具有高活性的该反应。使用无载体镍网作为催化剂，在醇转化率为60％时，对R1234yf的选择性几乎达到58％。 Pd和Pt显示几乎相似的转化水平; 然而，对所需产品的选择性很低。发现金属催化剂的活性是载体材料类型的函数，活性炭表现出比氧化铝更好的活性。研究了不同的重要工艺参数，如温度，压力和接触时间，以优化工艺。高压和高温对1234yf形成的速率是有害的; 然而，当在494℃和23秒的接触时间下进行反应时获得1234yf的最高产率。

15. 发明申请

WO2005108333A1 PROCESSES FOR SYNTHESIS OF 1,3,3,3-TETRAFLUOROPROPENE 审中-公开
标题翻译：合成1,3,3,3-四氯丙烯的方法
公开(公告)号：WO2005108333A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/014950
申请日：2005-04-29
申请人： HONEYWELL INTERNATIONAL, INC. , TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip , VAN DER PUY, Michael , MA, Jing Ji
发明人： TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip , VAN DER PUY, Michael , MA, Jing Ji
IPC分类号： C07C21/18
CPC分类号： C07C17/206 , C07C17/00 , C07C17/26 , C07C17/269 , C07C17/272 , C07C17/278 , C07C21/18
摘要： Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene which comprises, in one embodiment, reacting a compound of CF3X1 with a compound of CX2H=CHX3, wherein X1, X2, and X3 are each independently selected from the group consisting of fluorine, chlorine, bromine and iodine, to produce a reaction product comprising a compound of CF3CH=CHX3, wherein X3 is as described above; and when X3 is not fluorine, fluorinating the compound to produce 1,3,3,3-tetrafluoropropene. The process in another embodiment comprises preparing tetrafluoropropene comprising thermally cracking one or more compounds capable of producing a reaction mixture which preferably comprises diflurocarbene radicals and vinylidene fluoride, and converting said reaction mixture into -tetrafluoropropene (1,3,3,3-tetrafluoropropene).
摘要翻译：公开了合成1,3,3,3-四氟丙烯的方法，其在一个实施方案中包括CF 3 X 1的化合物与CX 2 H = CHX 3的化合物反应，其中X 1，X 2和X 3各自独立地选自由氟，氯，溴和碘组成的组，以产生包含CF 3 CH = CHX 3的化合物的反应产物，其中X 3如上所述; 当X3不是氟时，氟化该化合物以产生1,3,3,3-四氟丙烯。在另一个实施方案中的方法包括制备四氟丙烯，其包括热裂化一种或多种能够产生反应混合物的化合物，所述化合物优选包含二氟丙烯基和偏二氟乙烯，并将所述反应混合物转化为四氟丙烯（1,3,3,3-四氟丙烯）。

16. 发明申请

WO2005108332A1 PROCESSES FOR SYNTHESIS OF 1,3,3,3-TETRAFLUOROPROPENE 审中-公开
标题翻译：合成1,3,3,3-四氯丙烯的方法
公开(公告)号：WO2005108332A1
公开(公告)日：2005-11-17
申请号：PCT/US2005/015124
申请日：2005-04-29
申请人： HONEYWELL INTERNATIONAL, INC. , TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip, S.M. , VAN DER PUY, Michael
发明人： TUNG, Hsueh, S. , NAIR, Haridasan, K. , MUKHOPADHYAY, Sundip, S.M. , VAN DER PUY, Michael
IPC分类号： C07C17/25
CPC分类号： C07C17/206 , C07C17/00 , C07C17/25 , C07C17/275 , C07C17/278 , C07C21/18 , C07C19/10 , C07C19/16 , C07C19/14 , C07C19/01
摘要： Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene that comprises reacting a compound of the formula (I) CHFX 2 with a compound of formula (II) CH 2 =CF 2 to produce a reaction product comprising a compound of formula (III) CHXFCH 2 CXF 2 , wherein each X is independently selected from the group consisting of chlorine, bromine and iodine, and exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.
摘要翻译：公开了合成1,3,3,3-四氟丙烯的方法，其包括使式（I）CHFX 2的化合物与式（II）的化合物CH 2 = CF 2反应，以产生包含式（III）CHXFCH2CXF2，其中每个X独立地选自氯，溴和碘，并将所述式（III）化合物暴露于有效将所述化合物转化为1,3,3,3-四氟丙烯的反应条件。

17. 发明申请

WO2004041760A3 FLUORINATED POLYMERS 审中-公开
公开(公告)号：WO2004041760A3
公开(公告)日：2004-05-21
申请号：PCT/US2003/035223
申请日：2003-11-03
申请人： HONEYWELL INTERNATIONAL INC.
发明人： POSS, Andrew, J. , MA, Jing, Ji , VAN DER PUY, Michael , NALEWAJEK, David , NAIR, Haridasan, K.
IPC分类号： C07C33/44
摘要： Provided are compounds described by the formula (I), wherein W, X, Y and Z are independently selected from the group consisting of hydrogen, fluorine, hydroxyl, substituted alkyl and unsubstituted alkyl. Also provided are methods of making compounds of the present invention, and polymers derived from one or more compounds of the present invention.

18. 发明申请

WO2002102758A1 FLUORINE-CONTAINING COMPOUNDS AND POLYMERS DERIVED THEREFROM 审中-公开
标题翻译：含氟化合物和衍生自其的聚合物
公开(公告)号：WO2002102758A1
公开(公告)日：2002-12-27
申请号：PCT/US2002/019375
申请日：2002-06-18
申请人： HONEYWELL INTERNATIONAL, INC. , BRADLEY, David , MA, Jing-Ji , NALEWAJEK, David , SAMUELS, George, J. , STACHURA, Leonard, M. , VAN DER PUY, Michael , NAIR, Haridasan, K.
发明人： BRADLEY, David , MA, Jing-Ji , NALEWAJEK, David , SAMUELS, George, J. , STACHURA, Leonard, M. , VAN DER PUY, Michael , NAIR, Haridasan, K.
IPC分类号： C07C69/52
CPC分类号： D06M15/21 , C07C69/653 , C07C233/20 , C08F20/22 , C08F20/28 , D06M15/277 , D06M2200/12
摘要： Provided are fluorine-containing compounds, and polymers derived therefrom, for use in compositions used for treating textile substrates. Also provided are methods of making fluorine-containing compounds and polymers derived therefrom, compositions comprising the compounds and/or polymers of the present invention, methods of treating substrates, and the treated products derived therefrom.
摘要翻译：提供含氟化合物及其衍生的聚合物，用于处理织物基材的组合物中。还提供了制备含氟化合物和由其衍生的聚合物的方法，包含本发明的化合物和/或聚合物的组合物，处理底物的方法和由其衍生的处理产物。

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