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    • 11. 发明申请
    • POLYCARBONATE POLYOLS
    • 聚碳酸酯多元醇
    • WO2013034539A1
    • 2013-03-14
    • PCT/EP2012/067192
    • 2012-09-04
    • BAYER INTELLECTUAL PROPERTY GMBHAVTOMONOV, EvgenyFLECK, Olaf
    • AVTOMONOV, EvgenyFLECK, Olaf
    • C08G18/44C08G64/02
    • C08G64/0208C08G18/44C08G64/305
    • A mixture comprises a polycarbonate polyol with a decomposition temperature of ≥ 180 °C at ≥ 0.1 mbar to ≤ 1 mbar which is based on at least two different diols selected from the group consisting of C 4 , C 5 and C 6 diols, the mixture having an altogether low amount of amines and/or ammonium ions, alkali metal atoms and/or ions, earth alkali metal atoms and/or ions, metals and/or ions of the 13th through 15 th Group of the Periodic Table of the Elements (i.e. metals from Boron, Carbon and Nitrogen Group), and transition metal atoms and/or ions of the 4 th through 12 th Group of the Periodic Table of the Elements in relation to the total weight of the polycarbonate polyol. Furthermore, the pH value of the 10 weight-% slurry of this mixture in water lies in the range from ≥ 5.0 to ≤ 8.0. The present invention also relates to the use of these polyols for the production of polyurethanes, in particular dispersions and thermoplastic polymers.
    • 混合物包含在> = 0.1毫巴至<= 1毫巴的分解温度> = 180℃的聚碳酸酯多元醇,其基于选自C4,C5和C6二醇的至少两种不同的二醇,该混合物 具有完全低量的胺和/或铵离子,碱金属原子和/或离子,碱金属原子和/或离子,元素周期表第13至第15组的金属和/或离子(即 来自硼,碳和氮组的金属)以及元素周期表第4至12族的过渡金属原子和/或离子相对于聚碳酸酯多元醇的总重量。 此外,该混合物在水中的10重量%浆料的pH值在> = 5.0至<= 8.0的范围内。 本发明还涉及这些多元醇用于生产聚氨酯,特别是分散体和热塑性聚合物的用途。