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11. 发明申请

WO2010012587A1 ETHYLENE POLYMERS 审中-公开
标题翻译：乙烯聚合物
公开(公告)号：WO2010012587A1
公开(公告)日：2010-02-04
申请号：PCT/EP2009/058993
申请日：2009-07-14
申请人： BASELL POLYOLEFINE ITALIA S.R.L. , BALBONI, Davide , ESPOSITO, Simona , MORINI, Giampiero , PIEMONTESI, Fabrizio
发明人： BALBONI, Davide , ESPOSITO, Simona , MORINI, Giampiero , PIEMONTESI, Fabrizio
IPC分类号： C08F210/18 , C08F4/6592
CPC分类号： C08F210/02 , C08F4/65912 , C08F210/18 , C08F4/65927 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/17
摘要： A process for copolymerizing ethylene, one or more non-conjugated cyclic diene and optionally one or more alpha olefins of formula CH 2 =CHT wherein T is a C 1 -C 20 alkyl radical comprising the step of contacting the monomers under polymerization conditions in the presence of a catalyst system comprising a metallocene compound of formula (I) wherein: M is titanium zirconium or hafnium; X, is a hydrogen atom, a halogen atom, a R, OR, OR'O, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 group wherein R is an hydrocarbon radical and R' is a C 1 -C 20 -alkylidene, C 6 -C 20 -arylidene, C 7 -C 20 -alkylarylidene, or C 7 -C 20 -arylalkylidene radical; R 1 , is a C 1 -C 20 -alkyl radical; R 2 , R 3 , R 4 , R 5 , R 6 and R 7 are hydrogen atoms, or C 1 -C 20 hydrocarbon radicals or two or more R 2 , R 3 , R 4 , and R 5 can also be joined to form a C 3 -C 10 ring; L is a divalent C 1 -C 40 hydrocarbon radical.
摘要翻译：共聚乙烯，一种或多种非共轭环状二烯和任选一种或多种式CH 2 = CHT的α-烯烃的方法，其中T是C 1 -C 20烷基，其包括在聚合条件下，在催化剂体系包含式（I）的茂金属化合物，其中：M是钛锆或铪; X，是氢原子，卤素原子，R，OR，OR'O，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团，其中R是烃基，R'是C 1 -C 20亚烷基，C 6 -C 20 亚芳基，C 7 -C 20 - 亚烷基亚芳基或C 7 -C 20 - 芳基亚烷基; R1是C1-C20烷基; R2，R3，R4，R5，R6和R7是氢原子，或C1-C20烃基或两个或更多个R2，R3，R4和R5也可以连接形成C 3 -C 10环; L是二价C1-C40烃基。

12. 发明申请

WO2011006776A1 PROCESS FOR THE PREPARATION OF POLYMER OF 1-BUTENE 审中-公开
标题翻译：制备1-BOTENE聚合物的方法
公开(公告)号：WO2011006776A1
公开(公告)日：2011-01-20
申请号：PCT/EP2010/059440
申请日：2010-07-02
申请人： Basell Poliolefine Italia s.r.l. , VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella Maria Vittoria
发明人： VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella Maria Vittoria
IPC分类号： C08F210/08 , C08F4/649 , C08F4/651
CPC分类号： C08F210/08 , C08F10/08 , C08F110/08 , C08F4/651 , C08F4/6494 , C08F2500/15 , C08F2500/17 , C08F210/06
摘要： A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH 2 =CHZ wherein Z is a C 3 -C 20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl 2 (b) an alkylaluminum cocatalyst; and (c) a compound of formula (I) as external donor wherein R 1 , R 2 , R 3 , R 4 and R 5 hydrogen atoms or C 1 -C 20 hydrocarbon radicals, or two R 1 , R 2 , R 3 and R 4 can be joined to form a C 5 -C 20 , saturated or unsaturated, ring.
摘要翻译：一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法，其中α-烯烃选自式CH 2 = CHZ的乙烯，丙烯或α-烯烃，其中Z为C 3 -C 20烷基，其包括使1- 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下，包括：（a）固体组分，其包含Ti化合物和负载在MgCl 2（b）烷基铝助催化剂上的内电子给体化合物; 和（c）作为外给体的式（I）化合物，其中R1，R2，R3，R4和R5的氢原子或C1-C20烃基，或者两个R1，R2，R3和R4可以连接形成C5- C20，饱和或不饱和的环。

13. 发明申请

WO2007057361A1 PROPYLENE-ETHYLENE COPOLYMERS AND PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译：丙烯 - 乙烯共聚物及其制备方法
公开(公告)号：WO2007057361A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068354
申请日：2006-11-10
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , BACCI, Dino , FAIT, Anna , MORINI, Giampiero , PELLEGATTI, Giampaolo , PIEMONTESI, Fabrizio
发明人： BACCI, Dino , FAIT, Anna , MORINI, Giampiero , PELLEGATTI, Giampaolo , PIEMONTESI, Fabrizio
IPC分类号： C08F210/02
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F2500/20
摘要： Propylene-ethylene copolymers are flexible and show a very good balance between softness and mechanical properties in their crude state are obtained by solution polymerization in the presence of Ziegler-Natta catalysts. The said copolymers comprise from 10 to 50%wt of ethylene and are characterized by: product of the comonomer reactivity ratio r1•r2 ≤1.5; absence of 2,1 propylene insertions and tensile strength at break higher than 4 Mpa.
摘要翻译：丙烯 - 乙烯共聚物是柔性的，并且在齐格勒 - 纳塔催化剂存在下通过溶液聚合获得在其粗态下的柔软性和机械性能之间的非常好的平衡。所述共聚物包含10至50重量％的乙烯，其特征在于：共聚单体反应性比r1 r2 = 1.5的产物; 没有2,1丙烯插入和断裂拉伸强度高于4 Mpa。

14. 发明申请

WO2008017525A1 BUTENE-1 COPOLYMERS 审中-公开
标题翻译： BUTENE-1共聚物
公开(公告)号：WO2008017525A1
公开(公告)日：2008-02-14
申请号：PCT/EP2007/054798
申请日：2007-05-17
申请人： Basell Poliolefine Italia s.r.l. , PELLEGATTI, Giampaolo , SPATARO, Stefano , PIEMONTESI, Fabrizio , VITALE, Gianni
发明人： PELLEGATTI, Giampaolo , SPATARO, Stefano , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC分类号： C08F210/08 , C08F210/12
CPC分类号： C08F210/08 , C08F210/16 , C08F210/06 , C08F2500/03 , C08F2500/21 , C08F2500/12 , C08F210/14
摘要： Butene-1 copolymers containing: a) from 1 to 7 % by mole of ethylene derived units, and b) from 3 to 20 % by mole of units derived from one or more alpha-olefin(s) having general formula H 2 C=CHR, wherein R is methyl or a linear or branched alkyl radical C3-C8; said copolymers having a molecular weight distribution with a ratio (I) of less than or equal to 4 and a (b)/(a) molar ratio of more than or equal to 2.3.
摘要翻译：丁烯-1共聚物，其含有：a）1至7摩尔％的乙烯衍生单元，和b）3至20摩尔％的衍生自一种或多种具有通式H的α-烯烃的单元， 2 C = CHR，其中R是甲基或直链或支链烷基C3-C8; 所述共聚物具有小于或等于4的比率（I）和（b）/（a）摩尔比大于或等于2.3的分子量分布。

15. 发明申请

WO2010118962A1 PROCESS FOR THE PREPARATION OF POLYMER OF 1-BUTENE 审中-公开
标题翻译：制备1-BOTENE聚合物的方法
公开(公告)号：WO2010118962A1
公开(公告)日：2010-10-21
申请号：PCT/EP2010/054356
申请日：2010-03-31
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella, Maria, Vittoria , PELLEGATTI, Giampaolo
发明人： VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella, Maria, Vittoria , PELLEGATTI, Giampaolo
IPC分类号： C08F10/08 , C08F4/649 , C08F4/654
CPC分类号： C08F10/08 , C08F110/08 , C08F210/08 , C08F4/6494 , C08F2500/03 , C08F2500/15 , C08F2500/17 , C08F210/06 , C08F210/16
摘要： A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH 2 =CHZ wherein Z is a C 3 -C 20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl 2 (b) an alkylaluminum co catalyst; and (c) a compound of formula (I) as external donor Wherein: R 1 , R 2 , R 3 and R 4 , equal to or different from each other, are hydrogen atoms or C 1 -C 20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two R 1 , R 2 , R 3 and R 4 can be joined to form a C 5 -C 20 , saturated or unsaturated ring.
摘要翻译：一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法，其中α-烯烃选自式CH 2 = CHZ的乙烯，丙烯或α-烯烃，其中Z为C 3 -C 20烷基，其包括使1- 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下，包括：（a）固体组分，其包含Ti化合物和负载在MgCl 2上的内部电子给体化合物（b）烷基铝助催化剂 ; 和（c）作为外部给体的式（I）化合物，其中R1，R2，R3和R4彼此相同或不同，是氢原子或任选含有属于第13-17族的杂原子的C 1 -C 20烃基的元素周期表; 或两个R 1，R 2，R 3和R 4可以连接形成C 5 -C 20饱和或不饱和环。

16. 发明申请

WO2011061151A1 ETHYLENE COPOLYMERS 审中-公开
标题翻译：乙烯共聚物
公开(公告)号：WO2011061151A1
公开(公告)日：2011-05-26
申请号：PCT/EP2010/067490
申请日：2010-11-15
申请人： BASELL POLYOLEFINE GMBH , PIEMONTESI, Fabrizio , ESPOSITO, Simona
发明人： PIEMONTESI, Fabrizio , ESPOSITO, Simona
IPC分类号： C08F210/02
CPC分类号： C08F210/02 , C08F4/65912 , C08F10/00 , C08F210/18 , C08F210/06 , C08F236/20 , C08F2500/17 , C08F2500/25 , C08F4/65927
摘要： A process for copolymerizing ethylene, comprising the step of contacting ethylene, one or more non-conjugated cyclic diene and optionally one or more alpha olefins of formula CH 2 =CHT wherein T is a C 1 -C 20 alkyl radical under polymerization conditions in the presence of a catalyst system obtainable by contacting: A) a metallocene compound of formula (I) wherein: M is titanium zirconium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a hidrocabon group optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R 1 are C 1 -C 40 hydrocarbon radical; R 2 , and R 5 are hydrogen atoms, or C 1 -C 20 hydrocarbon radicals; R6, equal to or different from each other, are C1-C20 hydrocarbon radicals; R 3 and R 4 , form together a condensed saturated or unsaturaded C 3 -C 7 -membered ring; B) an alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally (C) an organo aluminum compound.
摘要翻译：一种使乙烯共聚的方法，其包括使乙烯，一种或多种非共轭环状二烯和任选的一种或多种式CH 2 = CHT的α-烯烃接触的步骤，其中T是C1-C20烷基，在聚合条件下，在催化剂体系可通过以下方式获得：A）式（I）的茂金属化合物，其中：M是钛锆或铪; X为相同或不同的氢原子，卤素原子，任选含有元素周期表第13-17族杂原子的吡啶酮基; R1是C1-C40烃基; R2和R5是氢原子或C1-C20烃基; R6相同或不同，为C1-C20烃基; R3和R4一起形成饱和或不饱和的C3-C7-元环; B）铝氧烷或能够形成烷基茂金属阳离子的化合物; 和（C）有机铝化合物。

17. 发明申请

WO2010026184A1 CATALYSTS FOR POLYMERIZING OLEFINS AND METHOD THEREOF 审中-公开
标题翻译：用于聚合烯烃的催化剂及其方法
公开(公告)号：WO2010026184A1
公开(公告)日：2010-03-11
申请号：PCT/EP2009/061394
申请日：2009-09-03
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , GULEVICH, Yuri , PIEMONTESI, Fabrizio , GADDI, Benedetta , GUIDOTTI, Simona , NIFANT'EV, Ilya E. , LYUBIMTSEV, Andrey
发明人： GULEVICH, Yuri , PIEMONTESI, Fabrizio , GADDI, Benedetta , GUIDOTTI, Simona , NIFANT'EV, Ilya E. , LYUBIMTSEV, Andrey
IPC分类号： C08F10/00 , C08F4/651 , C08F4/649
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6496 , C08F2500/12 , C08F2500/18
摘要： A solid catalyst component for polymerizing at least one olefin comprising Mg, Ti, at least one halogen, and at least one electron donor selected from arylsulfonates and arylsulfonyl derivatives of a specified formula. The solid catalyst component is able to give in high yields polyolefins with high stereoregularity.
摘要翻译：用于聚合包含Mg，Ti，至少一种卤素和至少一种选自具有规定式的芳基磺酸盐和芳基磺酰基衍生物的至少一种电子给体的至少一种烯烃的固体催化剂组分。固体催化剂组分能够以高收率产生具有高立构规整性的聚烯烃。

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