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    • 11. 发明申请
    • PROCESS FOR PRODUCING POLYMER TERMINATED WITH OPTIONALLY PROTECTED FUNCTIONAL GROUP
    • 用可选择保护的功能组终止聚合物的方法
    • WO1995025753A1
    • 1995-09-28
    • PCT/JP1995000499
    • 1995-03-20
    • KURARAY CO., LTD.MAEKAWA, KazuhikoSATO, Toshiaki
    • KURARAY CO., LTD.
    • C08F04/00
    • C08F2/38
    • A process for producing a polymer terminated with optionally protected functional group(s), which comprises conducting free-radical polymerization of a radical-polymerizable monomer by using a polymerization initiator comprising at least one member selected from the group (A) consisting of thiocarboxylic acids of general formula (1) and dithiocarboxylic acids of general formula (2) and at least one member selected from the group (B) consisting of polysulfides of general formula (3), polysulfides of the general formula (4): R -(S)m-R , and sulfoxides of general formula (5). In formula (1) R represents a hydrocarbon group which may have a substituent containing a functional group. In formula (2) R represents a hydrocarbon group which may have a substituent containing a functional group. In formula (3) R and R represent each a hydrocarbon group which may have a substituent containing a functional group; and n represents an integer of 2 or above. In formula (4) R and R represent each a hydrocarbon group having a functional group; and m represents an integer of 2 or above. In formula (5) R and R represent each a hydrocarbon group having a functional group. The process enables a polymer having a high content of functional groups introduced into one or both of its terminals to be produced independently of the rate of polymerization and the degree of polymerization of the product.
    • 一种制备用任选保护的官能团封端的聚合物的方法,其包括通过使用包含至少一种选自由以下组成的组的聚合引发剂进行自由基聚合单体的自由基聚合:(A) 通式(1)的二硫代羧酸和通式(2)的二硫代羧酸和选自由通式(3)的多硫化物组成的组(B)中的至少一种,通式(4)的多硫化物:R 5 - (S)mR 6,和通式(5)的亚砜。 式(1)中,R 1表示可具有含有官能团的取代基的烃基。 式(2)中,R 2表示可具有含有官能团的取代基的烃基。 在式(3)中,R 3和R 4各自表示可以具有含有官能团的取代基的烃基; n表示2以上的整数。 在式(4)中,R 5和R 6各自表示具有官能团的烃基; m表示2以上的整数。 在式(5)中,R 7和R 8各自表示具有官能团的烃基。 该方法使得能够独立于聚合速率和产物的聚合度而制备引入其一个或两个末端的高官能团含量的聚合物。