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    • 19. 发明申请
    • BIAXIALLY ORIENTED COPOLYESTER FILM FOR CAPACITOR DIELECTRIC USE OR THERMAL TRANSFER RIBBON USE
    • 用于电容器介质使用或热转印使用的双向定向共聚聚酯薄膜
    • WO1994013464A1
    • 1994-06-23
    • PCT/US1992010710
    • 1992-12-09
    • HOECHST AKTIENGESELLSCHAFTHOECHST CELANESE CORPORATIONBENNETT, CynthiaCHOE, E-WonFLINT, John, AnthonyKUHMANN, Bodo
    • HOECHST AKTIENGESELLSCHAFTHOECHST CELANESE CORPORATION
    • B32B03/10
    • C08J5/18B29C55/12B29D7/01B29K2067/00C08J2367/02C08K3/01C08K2201/016H01G4/18C08L67/02
    • The present invention comprises a biaxially oriented copolyester film useful for capacitor dielectrics or thermal transfer printing ribbons. Such films have good winding characteristics, slipperiness, good mechanical properties (stiffness and strength), and excellent thermal stability. The biaxially oriented copolyester film has at least 25 mole percent of the dicarboxylic acid or its ester equivalent content in the copolyester of 4,4'-bibenzoic acid. The remainder of the copolyester is such that the melting point is about 260 DEG C such that the copolyester is capable of withstanding a thermal treatment of 260 DEG C for about 10 seconds. The biaxially oriented copolyester film also includes an effective amount of fillers having a bimodal particle distribution sufficient to provide slip and good winding characteristics such as those that are known in the art. The bimodal particle distribution generally should comprise: (a) fine particles having an average particle diameter of 3 to 50 nm and employed in the range of from about 0.01 to about 3 percent by weight based on weight of the copolyester, and (b) a large particle distribution having an average particle diameter of 0.05 to 4 mu m and an aspect ratio of from 1.0 to 1.2 and being employed in the range of 0.005 to 1 percent by weight based on the weight of the copolyester.
    • 本发明包括可用于电容器电介质或热转移印刷带的双轴取向的共聚酯膜。 这种膜具有良好的缠绕特性,光滑性,良好的机械性能(刚度和强度)和优异的热稳定性。 双轴取向的共聚酯膜在4,4'-联苯甲酸的共聚酯中具有至少25摩尔%的二羧酸或其酯当量含量。 共聚酯的其余部分使得熔点为约260℃,使得共聚酯能够承受260℃的热处理约10秒。 双轴取向的共聚酯膜还包括有效量的填料,其具有足以提供滑动和良好卷绕特性的双峰颗粒分布,例如本领域已知的那些。 双峰颗粒分布通常应包括:(a)平均粒径为3至50nm并基于共聚酯重量计约0.01至约3重量%的细颗粒,和(b) 平均粒径为0.05〜4μm,长径比为1.0〜1.2,相对于共聚聚酯的重量,为0.005〜1重量%的粒子分布。