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    • 12. 发明申请
    • ELECTRICALLY CONDUCTING POLYMERS AND THEIR MANUFACTURE
    • 电导体聚合物及其制造
    • WO1997021228A1
    • 1997-06-12
    • PCT/GB1996002954
    • 1996-11-29
    • BICC PUBLIC LIMITED COMPANYTHORPE, Joan, Ann +lfDAVIDSON, KeithPONSONBY, Anna, Marguerite
    • BICC PUBLIC LIMITED COMPANYTHORPE, Joan, Ann +lfTHORPE, Frederick, Gordon +di
    • H01B01/12
    • H01B1/127C08G61/00C08G61/122C08G61/124C08G61/126H01B1/128
    • A conductive polymer comprises chains composed of resonant (aromatic and/or heterocyclic) rings in which conjugation extends from end to end of the molecule and cross-links between these chains which consist of aromatic groups conjugated to the chains that they link. In this way the polymer conducts from molecule to molecule and in principle may be isotropically conductive. Preferably, the polymer chains are selected from polyaniline, polypyrrole, polythiophene, poly-p-phenylene, poly-(p-phenylene sulfide) and poly-N-vinylcarbazole. The resonant groups may comprise carbocyclic or heterocyclic aromatic groups or pi -bonded aliphatic groups; p-phenylene groups and p-phenylene-vinylene groups are preferred. Such polymers can be made by a conjugative condensation reaction catalysed by a palladium compound. Three such condensation reactions are established and are named according to their respective authors as the Suzuki, Stille, and Heck reactions; the Suzuki reaction is preferred.
    • 导电聚合物包含由共振(芳族和/或杂环)环组成的链,其中缀合从分子的端部延伸到末端,并且这些链之间的交联连接在由它们连接的链上缀合的芳族基团组成。 以这种方式,聚合物从分子传导到分子,并且原则上可以是各向同性导电的。 优选地,聚合物链选自聚苯胺,聚吡咯,聚噻吩,聚对亚苯基,聚(对亚苯基硫醚)和聚-N-乙烯基咔唑。 共振基团可以包括碳环或杂环芳族基团或π-键合的脂族基团; 对亚苯基和对亚苯基 - 亚乙烯基是优选的。 这样的聚合物可以通过钯化合物催化的共轭缩合反应来制备。 建立了三个这样的缩合反应,根据各自的作者命名为铃木,Stille和Heck反应; 优选Suzuki反应。
    • 13. 发明申请
    • STRUCTURAL JOINTS
    • 结构接头
    • WO1996027050A1
    • 1996-09-06
    • PCT/GB1996000407
    • 1996-02-22
    • BICC PUBLIC LIMITED COMPANYSYNERGY COMPONENTS LIMITEDPARKIN, David, Charles
    • BICC PUBLIC LIMITED COMPANYSYNERGY COMPONENTS LIMITED
    • E02D05/52
    • E02D5/523
    • A structural joint for piles, columns and like structural members comprises first and second end-fittings for the respective structural members to be joined. The first end-fitting has a central socket (10) and a second end-fitting a central spigot (5) for entry into the said socket (10), and the socket (10) and the spigot (5) have mutually engaging cantilevered lugs (7), those on the spigot (5) projecting radially outwards and those on the socket (10) radially inwards. The lugs (7) are so spaced around the periphery of the joint that in one relative rotational position of the end-fittings the lugs (7) are disengaged and the end-fittings are freely separable in an axial direction and in another relative radial position of the end-fittings the lugs (7) are engaged in pairs to prevent any substantial relative axial movement. At least some pairs (preferably all) consist of lugs (7) each of which is tapered towards its unsupported end to form mutually engaging surfaces (16, 17, 18, 19, 20) having a dimension in the direction of the axis of the joint that is at least a major part of the dimension of the lug (7) in that direction and preferably practically all of it. The mutually engaging surfaces (16, 17, 18, 19, 20) are preferably parts of a cone.
    • 用于桩,柱和类似结构构件的结构接头包括用于要结合的相应结构构件的第一和第二端部配件。 第一端部配件具有中心插座(10)和第二端部配件,用于进入所述插座(10)的中心插口(5),并且插座(10)和插口(5)具有相互接合的悬臂 凸耳(7),位于插口(5)上的那些在径向向内突出并且在插座(10)上径向向内突出。 凸耳(7)围绕接头的周边间隔开,在端部接头的一个相对旋转位置,凸耳(7)脱开,并且端部接头在轴向方向和另一个相对径向位置可自由分离 的端部配件,凸耳(7)成对接合以防止任何显着的相对轴向运动。 至少一些对(优选全部)由凸耳(7)组成,每个凸耳朝向其未支撑的端部逐渐变细,以形成相互接合的表面(16,17,18,19,20),该表面具有沿着 该接头至少是凸耳(7)在该方向上的尺寸的主要部分,并且优选地实际上全部为该接头。 相互接合的表面(16,17,18,19,20)优选为锥体的一部分。
    • 14. 发明申请
    • OPTICAL NETWORK WITH WAVELENGTH-DEPENDENT ROUTING
    • 具有波长依赖路由的光网络
    • WO1996009736A1
    • 1996-03-28
    • PCT/GB1995002214
    • 1995-09-19
    • BICC PUBLIC LIMITED COMPANYMURPHY, Michael, MatthewHAIGH, Neil, Richard
    • BICC PUBLIC LIMITED COMPANY
    • H04Q11/00
    • H04Q11/0001H04Q11/0066
    • An optical network in which data signals are encoded with a wavelength corresponding to the address of the signals includes, at at least one point therein, a data routing switch (1) which comprises: (i) a wavelength comparator (3) for example a Bragg grating or a notch filter that will receive data signals and has associated therewith a characteristic wavelength so that it will send the data signal along a gate enabling line (5) or not in accordance with the relationship between the data signal encoding wavelength and the characteristic wavelength of the comparator; and (ii) a gate (7) which transmits or blocks the data signal in response to the presence or absence of the data signal in the gate enabling line. Normally the network will include a number of data routing switches having different characteristic wavelengths so that routing of the data is determined by which switch characteristic wavelength matches the data encoding wavelength. Since the wavelength comparison is a passive process, comparison and switching can be performed more rapidly than with conventional systems.
    • 数据信号以对应于信号地址的波长进行编码的光网络在其至少一个点处包括数据路由选择开关(1),其包括:(i)波长比较器(3),例如 布拉格光栅或陷波滤波器,其将接收数据信号并且与其相关联的特征波长,使得其将沿着栅极使能线(5)发送数据信号,或者根据数据信号编码波长和特性之间的关系发送数据信号 比较器的波长; 以及(ii)门(7),其响应于栅极使能线中的数据信号的存在或不存在而发送或阻止数据信号。 通常,网络将包括具有不同特征波长的多个数据路由交换机,使得数据的路由由哪个开关特征波长与数据编码波长匹配来确定。 由于波长比较是无源过程,因此可以比传统系统更快地执行比较和切换。
    • 15. 发明申请
    • SEMICONDUCTIVE LINEAR ELEMENT
    • 半导体线性元素
    • WO1995016933A1
    • 1995-06-22
    • PCT/GB1994002743
    • 1994-12-15
    • BICC PUBLIC LIMITED COMPANYROWLAND, Simon, Mark
    • BICC PUBLIC LIMITED COMPANY
    • G02B06/44
    • G02B6/4416G02B6/4417G02B6/4419G02B6/4422
    • A linear element (1, 61) suitable for extending between, and being supported by, towers of an overhead electrical power transmission system, includes one or more electrically semiconductive components (54, 62) that cause the element to have a linear resistance of 0.05 to 100 Mohms m , and which exhibit a negative temperature coefficient of resistance. The element may be a rope used for stringing up conductors of the system or it may be an optical cable. Preferred materials for forming the semiconductive components include carbonaceous fibre tows formed from pyrolised acrylonitrile fibres. The element has a controllable and reproducible resistance for reducing or eliminating dry-band arcing.
    • 适于在架空电力传输系统的塔架之间延伸并由其支撑的线性元件(1,61)包括一个或多个导电元件(54,62),其导致元件的线性电阻为0.05 至100Mohms m -1,并且具有负的耐温度系数。 该元件可以是用于将系统的导体串起来的绳索,或者它可以是光缆。 用于形成半导体组分的优选材料包括由热解的丙烯腈纤维形成的碳纤维丝束。 该元件具有可控和可重复的电阻,用于减少或消除干带电弧。
    • 16. 发明申请
    • MANUFACTURE OF A REVERSED LAY STRANDED ASSEMBLY
    • 反向布置组装的制造
    • WO1994028232A1
    • 1994-12-08
    • PCT/GB1994001124
    • 1994-05-23
    • BICC PUBLIC LIMITED COMPANYGOSLING, Cyril, Henry
    • BICC PUBLIC LIMITED COMPANY
    • D07B03/00
    • H01B13/0235D07B3/005
    • A method of manufacturing a stranded assembly of flexible elements for example an electrical or optical cable in which the lay of the elements is repeatedly reversed along the length of the assembly, comprises: (i) feeding the elements (X) into one end of a guide, the guide having an upstream region in which one internal lateral dimension thereof constrains the strands to lie in side-by-side relationship and in which an orthogonal internal lateral dimension is greater than the total width of the elements, and a downstream region in which the elements are forced into a generally cylindrical geometry; and (ii) removing the elements from the other end of the guide in the form of a stranded assembly (Y). The elements are fed into the guide at a higher speed than they are removed from the guide so that they are forced into a serpentine configuration in the guide, and in the downstream region the serpentine configuration is converted into a generally helical one in which the lay of the elements is repeatedly reversed.
    • 制造柔性元件的绞合组件的方法,例如电缆或光缆,其中元件的布置沿着组件的长度重复地反转,包括:(i)将元件(X)馈送到 引导件具有上游区域,其中一个内部横向尺寸限制线束并排关系,并且其中正交内侧横向尺寸大于元件的总宽度,并且其中下游区域 这些元件被迫进入大致圆柱形的几何形状; 和(ii)以引导组件(Y)的形式从引导件的另一端移除元件。 元件以比它们从引导件移除的速度更高的速度被馈送到引导件中,使得它们被迫在引导件中成蛇形结构,并且在下游区域中,蛇形结构被转换成大致螺旋形的构造,其中, 的元素反复颠倒。
    • 20. 发明申请
    • COMPOSITIONS AND ELECTRIC CABLES
    • 组合物和电线
    • WO1998021278A1
    • 1998-05-22
    • PCT/GB1997003098
    • 1997-11-12
    • BICC PUBLIC LIMITED COMPANYEASTER, Mark, Richard
    • BICC PUBLIC LIMITED COMPANY
    • C08L31/04
    • H01B3/44C08K3/04H01B1/24C08L31/04
    • A composition of matter for use as dielectric shield in an electric power cable having insulation of XLPE, EPR or EPDM comprises: a base polymer which is a copolymer of ethylene with a mono-unsaturated ester; conductive carbon black in an amount to give the composition an electrical resistivity below 500 Am; and as an adhesion-adjusting additive, 1-20 % by weight of the base polymer of a copolymer which consists essentially of ethylene and a comonomer having in its molecule at least one carbon-oxygen dipole, said copolymer having a molecular weight less than 20,000 Daltons but a melting point higher than 30 DEG C. This new class of additive permits use of EVA's with lower vinyl acetate content than prior art additives and so enables the composition to have less rubbery physical properties.
    • 在具有XLPE,EPR或EPDM绝缘的电力电缆中用作介电屏蔽的物质组合物包括:基础聚合物,其是乙烯与单不饱和酯的共聚物; 导电炭黑的量使得组合物的电阻率低于500Am; 并且作为粘合调节添加剂,1-20重量%的共聚物的基础聚合物,其基本上由乙烯和在其分子中具有至少一个碳 - 氧偶极子的共聚单体组成,所述共聚物的分子量小于20,000 道尔顿,但熔点高于30℃。这种新类添加剂允许使用具有比现有技术添加剂低的乙酸乙烯酯含量的EVA,因此使组合物具有较少的橡胶状物理性能。