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101. 发明申请

WO02028848A1 METHOD FOR THE CATALYTIC DIRECT OXIDATION OF UNSATURATED HYDROCARBONS IN THE GAS PHASE, USING GOLD 审中-公开
标题翻译：用于气相中不饱和烃催化直接氧化黄金
公开(公告)号：WO02028848A1
公开(公告)日：2002-04-11
申请号：PCT/EP2001/011007
申请日：2001-09-24
IPC分类号： C07D301/10
CPC分类号： C07D301/10
摘要： The invention relates to a catalytic gas phase method for producing epoxides from unsaturated hydrocarbons by oxidation of the latter with molecular oxygen in the presence of carbon monoxide and nanoscalar gold particles.
摘要翻译：本发明涉及一种用于在一氧化碳和纳米级金颗粒的存在下制备自不饱和烃的环氧化物的通过氧化用分子氧的催化气相方法。

102. 发明申请

WO02004116A1 METHOD FOR PRODUCING AN EPOXIDATION CATALYST 审中-公开
标题翻译：用于生产环氧化
公开(公告)号：WO02004116A1
公开(公告)日：2002-01-17
申请号：PCT/EP2001/008008
申请日：2001-07-11
IPC分类号： B01J23/50 , B01J35/00 , C07D301/10 , B01J23/40 , B01J23/46 , B01J23/48 , B01J23/74 , B01J23/72 , B01J23/06 , C07D301/06 , C07C51/235
CPC分类号： C07D301/10 , B01J23/50 , B01J35/0013
摘要： The invention relates to a method for producing a stabilised catalyst system. According to said method, a salt of a metal from the first, second or eighth subgroup is reduced to colloidal metal in an essentially water-free, oxidation resistant, organic solvent; with a reduction agent and in the presence of a stabiliser, said salt being soluble in said solvent. Alternatively, the metal salt can be hydrolysed to colloidal metal oxide with water, in the presence of a stabiliser. The solvent is selected from aliphatic, aromatic, nitrated aliphatic and nitrated aromatic, halogenated aliphatic and halogenated aromatic hydrocarbons and a hydrophobic stabiliser that is soluble therein is used as the stabiliser. By selecting the solvent in this way, it is possible to avoid unwanted secondary reactions such as the formation of secondary products such as glycols and glycol monoalkylethers to a large extent. The inventive catalyst system or the catalyst that can be isolated from the same can be used for the epoxidation of alkenes in solution. In a particularly preferred embodiment of the invention, a catalyst system containing colloidal silver is used for the epoxidation of ethylene.
摘要翻译：本发明描述了一种制备稳定的催化剂系统的方法，其中所述实质上水不免费的，对氧化稳定的有机溶剂中，在稳定剂的存在下，第一，第二或第八子组的金属的可溶性在其中盐与胶态金属还原剂还原。或者，金属的盐可以与水的稳定剂的存在下水解，以形成胶态金属氧化物。选自脂族，芳族，脂族硝化和硝化的芳族，卤代脂肪和卤代芳族烃中选择的溶剂，并且如在可溶性疏水稳定剂的稳定剂使用。通过溶剂不需要的副反应，如副产物例如二醇类和乙二醇单烷基在很大程度上排除地层的选择。或如图所示的可分离的催化剂体系从其催化剂可用于在溶液中的烯烃的环氧化。在本发明的一个特别优选的实施方案是含有胶态银的催化剂系统中，用于乙烯环氧化使用。

103. 发明申请

WO01058585A1 PROCESS FOR THE EPOXIDATION OF OLEFINS USING GOLD-CONTAINING CATALYSTS 审中-公开
标题翻译：使用含金属催化剂环氧化烯烃的方法
公开(公告)号：WO01058585A1
公开(公告)日：2001-08-16
申请号：PCT/EP2001/000809
申请日：2001-01-25
IPC分类号： C07D301/08 , B01J23/66 , B01J23/68 , B01J31/26 , B01J31/34 , B01J31/36 , B01J31/38 , C07B61/00 , C07D301/10 , C07D303/04
CPC分类号： B01J23/68 , B01J23/66 , C07D301/10
摘要： The invention is directed towards a process for the epoxidation of olefins, using molecular oxygen and hydrogen, characterized in that, as catalyst, a compound comprising gold, preferably in nanometer size, on a support material, in which the support material contain one or more element(s) selected from the group consisting of Scandium, Yttrium, Lanthanide, Zirconium, Hafnium, Vanadium, Niobium, Tantalum, Chromium, Molybdenum and/or Tungsten and is essentially free of titanium is applied, and a compound comprising gold, preferably in nanometer size, on a support material, in which the support material contain one or more element(s) selected from the group consisting of Scandium, Yttrium, Lanthanide, Zirconium, Hafnium, Vanadium, Niobium, Tantalum, Chromium, Molybdenum and/or Tungsten and is essentially free of titanium, a process for the preparation of said compounds and a method of catalyzing a chemical reaction through conducting said chemical reaction in the presence of said compound.
摘要翻译：本发明涉及一种使用分子氧和氢气进行烯烃环氧化的方法，其特征在于，作为催化剂，包含金，优选纳米尺寸的化合物在载体材料上，其中载体材料含有一种或多种选自钪，钇，镧系元素，锆，铪，钒，铌，钽，铬，钼和/或钨的元素，并且基本上不含钛，以及包含金的化合物，优选在纳米尺寸，在载体材料上，其中载体材料含有选自钪，钇，镧系元素，锆，铪，钒，铌，钽，铬，钼和/或钨的一种或多种元素并且基本上不含钛，制备所述化合物的方法和通过在所述化合物存在下进行所述化学反应来催化化学反应的方法天。

104. 发明申请

WO00021944A2 SELECTIVE OXIDATION PROCESS AND CATALYST THEREFOR 审中-公开
标题翻译：选择性氧化法和催化剂
公开(公告)号：WO00021944A2
公开(公告)日：2000-04-20
申请号：PCT/US1999/023347
申请日：1999-10-07
IPC分类号： C07D307/89 , B01J23/22 , B01J23/66 , B01J27/198 , B01J35/02 , B01J35/06 , B01J37/02 , C07B41/10 , C07B61/00 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/38 , C07C51/265 , C07D301/04 , C07D301/10 , C07D301/00
CPC分类号： C07D301/10 , B01J35/06 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/38 , C07C51/265 , C07C47/22 , C07C47/04 , C07C63/16
摘要： A process for selectively oxidizing an organic molecule by reacting said organic molecule and oxygen in the presence of a selective oxidation catalyst supported on a mesh-like structure.
摘要翻译：一种通过在负载在筛状结构上的选择性氧化催化剂存在下使所述有机分子和氧反应来选择性氧化有机分子的方法。

105. 发明申请

WO99040077A3 METHOD FOR THE DIRECT CATALYTIC OXIDATION OF UNSATURATED HYDROCARBONS IN GASEOUS PHASE 审中-公开
标题翻译：在气相中催化直接氧化不饱和烃的方法
公开(公告)号：WO99040077A3
公开(公告)日：1999-10-28
申请号：PCT/EP1999/000530
申请日：1999-01-27
IPC分类号： B01J23/52 , B01J35/00 , C07D301/03 , C07D301/10 , C07D303/04 , C07D301/08 , B01J23/66
CPC分类号： B01J23/52 , B01J35/0013 , C07D301/10 , Y10S977/775 , Y10S977/89 , Y10S977/896 , Y10S977/931
摘要： The present invention relates to a method for the oxidation of unsaturated hydrocarbons in gaseous phase, wherein said oxidation is carried out in the presence of a hydrogen-oxygen mixture on a catalyst coated with gold particles. This method comprises using a calcined catalyst which is produced from a titanium oxide hydrate optionally containing sulphate, said catalyst being coated with nanometrical gold particles. This method is preferably used for epoxidising ethene, propene or butene. This invention further relates to a catalyst for oxidising the above-mentioned unsaturated hydrocarbons.
摘要翻译：公开了一种用于在氢 - 氧混合物的存在下在气相不饱和烃中的占用的与金的氧化的方法颗粒催化剂，其特征在于，使用含有具有纳米级金颗粒从制备任选硫酸氧化钛水合物和煅烧所占据的催化剂。该方法优选适用于乙烯，丙烯或丁烯的环氧化。此外，描述了用于氧化所述不饱和烃的催化剂。

106. 发明申请

WO99016760A1 RECOVERY OF 3,4-EPOXY-1-BUTENE FROM 1,3-BUTADIENE OXIDATION EFFLUENTS 审中-公开
标题翻译：从1,3-丁二烯氧化液中回收3,4-环氧-1-丁烯
公开(公告)号：WO99016760A1
公开(公告)日：1999-04-08
申请号：PCT/US1998/018871
申请日：1998-09-09
IPC分类号： C07D301/08 , C07D301/10 , C07D301/32
CPC分类号： C07D301/32 , C07D301/10
摘要： Disclosed are improved processes for the recovery of 3,4-epoxy-1-butene (epoxybutene) from an epoxidation effluent comprising epoxybutane, butadiene, oxygen and an inert diluent obtained by the selective epoxidation of butadiene with an oxygen-containing gas in the presence of a catalyst and an inert gas. Epoxybutene is separated from the effluent by means of an absorption process using an extractant comprising liquid butadiene and, optionally, a hydrocarbon diluent. The formation of butenediols, by the reaction of epoxybutene and water, in the recovery process is inhibited by the addition of a base, preferably an alkali metal base, to the recovery system.
摘要翻译：公开了从包含环氧丁烷，丁二烯，氧和惰性稀释剂的环氧化流出物中回收3,4-环氧-1-丁烯（环氧丁烯）的改进方法，其通过在存在下用含氧气体选择性环氧化丁二烯的催化剂和惰性气体。通过使用包含液体丁二烯和任选的烃稀释剂的萃取剂的吸收方法将环氧丁烯与流出物分离。在回收过程中，通过环氧丁烯和水的反应形成丁二醇通过在回收系统中加入碱，优选碱金属碱来抑制。

107. 发明申请

WO99011370A1 ETHYLENE OXIDE CATALYST 审中-公开
标题翻译：乙烯氧化物催化剂
公开(公告)号：WO99011370A1
公开(公告)日：1999-03-11
申请号：PCT/US1998/017934
申请日：1998-08-28
IPC分类号： B01J23/66 , C07D301/10 , B01J27/02 , B01J27/055
CPC分类号： C07D301/10 , B01J23/66
摘要： A silver catalyst for ethylene oxidation to ethylene oxide is provided containing a promoter combination consisting of an alkali metal component, a sulfur component, a germanium or tin component, and a fluorine component, the catalyst being essentially free of rhenium and transition metal compounds.
摘要翻译：提供了用于乙烯氧化成环氧乙烷的银催化剂，其含有由碱金属组分，硫组分，锗或锡组分和氟组分组成的助催化剂组合，所述催化剂基本上不含铼和过渡金属化合物。

108. 发明申请

WO98052931A1 PROPYLENE OXIDE PROCESS USING ALKALINE EARTH METAL COMPOUND-SUPPORTED SILVER CATALYSTS CONTAINING TUNGSTEN AND POTASSIUM PROMOTERS 审中-公开
标题翻译：丙烯氧化工艺使用含碱土金属化合物的负载型银催化剂，含有金属和钾的促进剂
公开(公告)号：WO98052931A1
公开(公告)日：1998-11-26
申请号：PCT/EP1998/002422
申请日：1998-04-23
IPC分类号： B01J23/68 , C07B61/00 , C07D301/10 , C07D303/04
CPC分类号： B01J23/687 , C07D301/10 , Y02P20/142 , Y02P20/52
摘要： Direct oxidation of propylene to propylene oxide is accomplished using alkaline earth metal compound-supported silver catalysts containing tungsten and potassium promoters. In one embodiment of the invention, the tungsten promoter and the potassium promoter are simultaneously introduced through the use of potassium tungstate. Catalysts of this type exhibit unusually high propylene oxide productivity when carbon dioxide is present in the feedstream.
摘要翻译：使用含有钨和钾促进剂的碱土金属化合物负载的银催化剂实现丙烯直接氧化成环氧丙烷。在本发明的一个实施方案中，通过使用钨酸钾同时引入钨促进剂和钾促进剂。当在进料流中存在二氧化碳时，这种类型的催化剂表现出非常高的环氧丙烷生产率。

109. 发明申请

WO1998000415A1 PROCESS FOR THE DIRECT OXIDATION OF OLEFINS TO OLEFIN OXIDES 审中-公开
标题翻译：烯烃直接氧化成烯烃氧化物的方法
公开(公告)号：WO1998000415A1
公开(公告)日：1998-01-08
申请号：PCT/US1997011417
申请日：1997-06-30
申请人： THE DOW CHEMICAL COMPANY , CLARK, Howard, J. , MAJ, Joseph, J. , BOWMAN, Robert, G. , BARE, Simon, R. , HARTWELL, George, E.
发明人： THE DOW CHEMICAL COMPANY
IPC分类号： C07D301/10
CPC分类号： B01J23/50 , B01J23/52 , B01J23/66 , B01J29/89 , C07D301/04 , C07D301/10 , Y02P20/52 , Y02P20/584 , Y02P20/588
摘要： A process and catalyst for the direct oxidation of an olefin having three or more carbon atoms, such as propylene, by oxygen to an olefin oxide, such as propylene oxide. The process involves contacting the olefin with oxygen under reaction conditions in the presence of hydrogen and a catalyst. The catalyst comprises gold on a support of titanium dispersed on silica. The titanium phase is disorganized and substantially free of crystalline titanium dioxide, as determined by analytical methods, such as high resolution transmission electron microscopy and Raman spectroscopy. Selectivity to olefin oxide is high at good conversions of the olefin. The time between catalyst regenerations is long, and the catalyst is readily regenerated.
摘要翻译：用于将具有三个或更多个碳原子的烯烃（例如丙烯）通过氧气直接氧化成烯烃氧化物如环氧丙烷的方法和催化剂。该方法包括在氢气和催化剂存在下，在反应条件下使烯烃与氧接触。该催化剂包含分散在二氧化硅上的钛载体上的金。通过分析方法如高分辨率透射电子显微镜和拉曼光谱法测定，钛相是无组织的并且基本上不含结晶二氧化钛。烯烃氧化物的选择性高，烯烃转化率高。催化剂再生之间的时间长，催化剂容易再生。

110. 发明申请

WO1989007101A1 SELECTIVE EPOXIDATION OF OLEFINS 审中-公开
标题翻译：烯烃的选择性环氧化
公开(公告)号：WO1989007101A1
公开(公告)日：1989-08-10
申请号：PCT/US1989000341
申请日：1989-01-27
申请人： EASTMAN KODAK COMPANY
发明人： EASTMAN KODAK COMPANY , MONNIER, John, Robert , MUEHLBAUER, Peter, James
IPC分类号： C07D301/10
CPC分类号： C07D303/04 , B01J23/56 , C07D301/10
摘要： Process is disclosed for the selective epoxidation of olefins having no allylic hydrogens. Such olefins are contacted with an oxygen-containing gas in the presence of a silver catalyst and an organic halide under defined reaction conditions, thereby selectively producing expoxides in good yield.

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