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    • 2. 发明申请
    • PAPER MAKING PROCESS UTILIZING AN AMPHOTERIC MUCOUS STRUCTURE AS BINDER
    • 使用AMPHTERIC MUCOUS结构作为粘合剂的造纸工艺
    • WO1982001020A1
    • 1982-04-01
    • PCT/EP1981000147
    • 1981-09-16
    • SUNDEN OSUNDEN A
    • D21H03/02
    • D21H17/27D21H17/29D21H17/30D21H17/43D21H17/65D21H17/66D21H17/69
    • Paper making process with improved retention and binding of fillers and second grade fibers. It is characterized by the use of an amphoteric mucous like compound as binder. This compound is the reaction product between cationic starch of low charge density and an anionic polymer of high charge density as carboxymethyl cellulose. The compound has amphoteric and mucous characters and should be used for paper making, while in a unique transient structure. This structure is characterized by filler particles being enclosed and finely distributed in droplets of the highly hydrated but substantially water-insoluble mucous compound. According to the invention this transient structure may further be reorganized to a less hydrated and more resistant gel structure, still enclosing the filler. This gel structure can stand the draining forces on a paper machine wire. This structural reorganization is achieved by reaction with colloidal inorganic polymers of very high surface charge as polysilicic acid and polyaluminium compounds. The process yields papers of high strengths and filler retentions of more than 90% at a single fire passage even at extreme filler contents of 30-60% of the paper weight.
    • 造纸工艺具有改进的填料和二级纤维的保留和结合。 其特征在于使用两性粘液样化合物作为粘合剂。 该化合物是低电荷密度的阳离子淀粉与作为羧甲基纤维素的高电荷密度的阴离子聚合物之间的反应产物。 该化合物具有两性和粘性特征,应用于造纸,而在独特的瞬态结构中。 该结构的特征在于填充剂颗粒被包封并精细分布在高度水合但基本上不溶于水的粘液化合物的液滴中。 根据本发明,这种瞬态结构可以进一步重新组织成仍然封闭填料的较少水合和更耐性的凝胶结构。 这种凝胶结构可以承受造纸机线上的排水力。 通过与作为聚硅酸和聚铝化合物的表面电荷非常高的胶态无机聚合物反应,可以实现这种结构重组。 该方法即使在纸张重量的30-60%的极端填料含量下,在单个火焰通道上产生高达90%以上的高强度和填料保留性的纸张。
    • 4. 发明申请
    • METHOD AND PRODUCTS FOR SIZING PAPER AND SIMILAR MATERIALS
    • 尺寸纸和类似材料的方法和产品
    • WO1988002047A1
    • 1988-03-24
    • PCT/US1987002200
    • 1987-09-04
    • WEYERHAEUSER COMPANY
    • WEYERHAEUSER COMPANYTIEDEMAN, George, TrentGESS, Jerome, Murray
    • D21H03/02
    • D21H23/765D21H17/03D21H17/55
    • Method of sizing paper and, in particular, paper made under neutral to alkaline conditions at least as high as 10.5. The papermaking stock is first treated with a polycationic material to provide sizing receptive sites uniformly distributed over the fiber surface. The presence of the anchoring points is critical to the later redistribution of the sizing material in the dryer section of the paper machine. The sizing material is then added to the slurry. This is then brought down onto the fibers by addition of a small amount of a size precipitant such as alum. The sizing molecule should have a hydrophilic portion with two hetero atoms forming a bidentate analog structure. This must have a pK in water of 6.0 or higher and a vapor pressure preferably at least 0.0006 mm Hg at 60 DEG C. The polycationic material provides anchoring/orienting sites on the fiber to which the small globules of sizing attach when the emulsion is broken by the precipitant. Sizing will develop in the dryer section of the paper machine, presumably by vapor phase redistribution of sizing from the attached globules to unfilled sites where an anchoring point is present. Alkyl and alkenyl substituted catechols, beta-diones, hydrozamic acids and imides are among the new classes of sizing materials disclosed.
    • 纸张尺寸的方法,特别是在中性至碱性条件下至少高达10.5的纸张。 首先用聚阳离子材料处理造纸原料,以提供均匀分布在纤维表面上的施胶接收位点。 锚定点的存在对于造纸机的干燥器部分中的上浆材料的后续再分配至关重要。 然后将上浆材料加入浆料中。 然后通过加入少量的大小沉淀剂(例如明矾)将其还原到纤维上。 上浆分子应具有亲水部分,其中两个杂原子形成双齿模拟结构。 在60℃或以上的水中必须具有pK,在60℃下蒸气压优选至少为0.0006mmHg。聚阳离子材料在乳液破碎时附着的小尺寸颗粒附着的纤维上提供锚定/取向位点 由沉淀物。 造纸机的烘干部分会发生尺寸变化,可能是通过气相重新分配尺寸从连接的小球到存在锚定点的未填充部位。 烷基和链烯基取代的邻苯二酚,β-二酮,氢化唑和酰亚胺是公开的新型施胶材料之一。
    • 6. 发明申请
    • LOW-DENSITY MATERIAL CONTAINING A VEGETABLE FILLER
    • 低密度材料含有蔬菜灌装机
    • WO1989005884A1
    • 1989-06-29
    • PCT/FR1988000610
    • 1988-12-14
    • GOMEZ, Daniel
    • D21H03/02
    • D21H21/52C08L97/02C09D7/40C09D7/65C09D7/69D21H17/02D21H19/38
    • In a new process for reducing the density, increasing the bulk, the hand and the porosity of a sheet material containing fibres by means of a vegetable filler, a vegetable filler of density less than 500 kg/m is introduced into the fibrous mass during the manufacture of the material. At least 95 % of the particles of the vegetable filler are less than 150 micrometres in size and at least 80 % of said particles are greater than 10 micrometres in size. The process is particularly useful for obtaining paper and cardboard of low density with improved hand and porosity. It is also attractive since it reduces the cost prices and enhances the thermal and acoustic insulation properties.
    • 在减少密度的新方法中,通过植物填料增加包含纤维的片材的体积,手和孔隙率,将密度小于500kg / m 3的植物填料引入纤维 在材料制造过程中的质量。 至少95%的植物填料颗粒的尺寸小于150微米,并且至少80%的所述颗粒的尺寸大于10微米。 该方法对于获得具有改善的手和孔隙率的低密度纸和纸板特别有用。 它也是有吸引力的,因为它降低了成本价格并且增强了热和隔音性能。