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    • 2. 发明申请
    • MULTI-METAL CYANIDE CATALYSTS
    • 多金属氰化物催化剂
    • WO0074844A8
    • 2001-03-29
    • PCT/EP0004572
    • 2000-05-19
    • BASF AGGROSCH GEORG HEINRICHHARRE KATHRINERBES JOERGLORENZ REINHARDBAUER STEPHANOSTROWSKI THOMASBAUM EVAJUNGE DIETER
    • GROSCH GEORG HEINRICHHARRE KATHRINERBES JOERGLORENZ REINHARDBAUER STEPHANOSTROWSKI THOMASBAUM EVAJUNGE DIETER
    • B01J27/26C08G65/26C08G65/10
    • C08G65/2663B01J27/26
    • The invention relates to multi-metal cyanide compounds of the general formula (I). In said formula: M represents at least one metal ion, selected from the group containing Zn , Fe , Co , Ni , Mn , Pb , Fe , Mo , Mo , Al , V , Sr , W , W , Cu , Cr , Cr , Cd , Hg , Pd , Pt , V , Mg , Ca , Ba ; M represents at least one metal ion, selected from the group containing Fe , Fe , Co , Cr , Mn , Mn , Rh , Ru , Ru , V , V , Co , Ir and Cr and M is different from M ; X represents at least one anion, selected from the group containing halide, hydroxide, sulphate, carbonate, cyanide, thiocyanate, isocyanate, carboxylate, in particular, formiate, acetate, propionate, oxalate, nitrate; A represents at least one anion, selected from the group containing halide, hydroxide, sulphate, carbonate, cyanate, thiocyanate, isocyanate, carboxylate or nitrate, in particular, cyanide; a, b, c and d are whole or fractional numbers which are selected in such a way, that the electroneutrality of the cyanide compound is guaranteed, whereby a, b and d are greater than zero and c is greater than or equal to zero; e is a whole or fractional number greater than zero and h is a whole or fractional number greater than or equal to zero; and f and g are whole or fractional numbers which are selected in such a way that the electroneutrality of M fXg is guaranteed.
    • 涉及多金属的式(I)的氰化:M <1> [M <2>(CN)BAC] D * E中号<1> FXG * H 2 O,其中M <1>,选自Zn <中选择的至少一种金属离子2+ >,铁<2+>,钴<3+>,镍<2+>,锰<2+>,钴<2+>,锡<2+>,铅<2+>,铁<3+> 沫<4+>,莫<6+>,铝<3+>,V <5+>,SR <2+>,W <4+>,W <6+>,铜<2+>,铬< 2+>,铬<3+>,镉<2+>,汞<2+>,钯<2+>,铂<2+>,V <2+>,镁<2+>,钙<2+ >,钡<2+>; 中号<2>的至少一种金属选自Fe <2+>,铁<3+>,钴<3+>,铬<3+>,锰<2+>,锰<3+>,铑<3+ >,茹<2+>,钌<3+>,V <4+>,V <5+>,钴<2+>,IR <3+>和Cr <2+>和M <2>不同 是M <1>的; X是至少一种阴离子选自卤化物,氢氧化物,硫酸盐,碳酸盐,氰化物,硫氰酸盐,异氰酸酯,羧酸盐中,特别是甲酸盐,乙酸盐,丙酸盐,草酸盐,硝酸盐; 甲至少一个阴离子选择卤化物,氢氧化物,硫酸盐,碳酸盐,氰酸盐,硫氰酸盐,异氰酸酯,羧酸盐,或硝酸盐,特别是氰化装置; 并且a,b,c和d是被选择的整数或分数,使得氰化物化合物的电中性保证,其中a,b和d是大于零,而c是大于或等于零,并且f和g是整数或分数 是被选择使得M <1> FXG的Elektoneutralität保证数字。
    • 3. 发明申请
    • COMPOSITE SUITABLE FOR USE IN ELECTROCHEMICAL CELLS
    • 复合材料适用于电化学电池
    • WO9919917A3
    • 1999-06-24
    • PCT/EP9806394
    • 1998-10-08
    • BASF AGGS JAPAN STORAGEBAUER STEPHANBRONSTERT BERNDMOEHWALD HELMUTSTEPHAN OSKARTUKAMOTO HISASHI
    • BAUER STEPHANBRONSTERT BERNDMOEHWALD HELMUTSTEPHAN OSKARTUKAMOTO HISASHI
    • H01G9/155C09K9/02H01B5/14H01G9/02H01G9/04H01M2/16H01M4/13H01M4/48H01M4/485H01M4/62H01M6/18H01M6/40H01M10/0525H01M10/0565H01M10/0569H01M10/36H01M10/40H01M10/04
    • H01M4/13C09K9/02H01G9/02H01G9/04H01M2/164H01M2/1673H01M4/0435H01M4/485H01M4/62H01M4/622H01M6/188H01M6/40H01M10/0525H01M10/0565H01M10/0569H01M2300/0085
    • A composite comprises Aa) at least one first layer which comprises a mixture Ia, comprising a mix IIa consisting of a) from 1 to 95 % by weight of a solid III, preferably a basic solid III, having a primary particle size of from 5 nm to 20 mu m and b) from 5 to 99 % by weight of a polymeric composition IV obtainable by polymerization of b1) from 5 to 100 % by weight, based on the composition IV, of a condensation product V of alpha ) at least one compound VI which is able to react with a carboxylic acid or a sulfonic acid or a derivative or a mixture of two or more thereof, and beta ) at least 1 mol per mol of the compound VI of a carboxylic acid or sulfonic acid VII which contains at least one free-radically polymerizable functional group, or a derivative thereof or a mixture of two or more thereof, and b2) from 0 to 95 % by weight, based on the composition IV, of a further compound VIII having a mean molecular weight (number average) of at least 5000 and polyether segments in the main chain or a side chain, where the proportion by weight of the mix IIa in the mixture Ia is from 1 to 100 % by weight, and the layer is free of an electron-conducting, electrochemically active compound, and B) at least one second layer which comprises an electron-conducting, electrochemically active compound, wherein the first layer or layers and the second layer or layers are joined to one another by one of the two methods V1 or V2: V1) Lamination of the first layer or layers with the second layer or layers under the action of heat or pressure or under the action of heat and pressure, or V2 Corona treatment of the first layer or layers, the second layer or layers or the first layer or layers and the second layer or layers and subsequent bringing together of the corona-treated first layer or layers with the corona-treated or untreated second layer or layers.
    • 复合材料包括Aa)至少一个包含混合物Ia的第一层,其包含混合物IIa,混合物IIa由以下组分组成:a)1至95重量%的固体III,优选碱性固体III,其初级粒度为5 nm至20μm,和b)5至99重量%的聚合物组合物IV,其可通过以b1)5至100重量%(基于组合物IV)将α缩合产物V至少 一种化合物VI,其能够与羧酸或磺酸或其两种或多种的衍生物或其混合物反应,并且β)每摩尔化合物VI至少1摩尔的羧酸或磺酸VII,其中 含有至少一个可自由基聚合的官能团,或其衍生物或其两种或多种的混合物,和b2)0至95重量%(基于组合物IV)的另一种化合物VIII具有平均分子量 重量(数均)至少5000和聚醚片段在。 n链或侧链,其中混合物Ia中混合物IIa的重量比例为1至100重量%,并且该层不含电子传导的电化学活性化合物,和B)至少一个 第二层,其包括电子传导的电化学活性化合物,其中第一层或第二层或第二层或两层通过两种方法V1或V2之一彼此连接:V1)第一层或第二层与第 在热或压力作用下或在热和压力的作用下的第二层或第二层,或V2电晕处理第一层或第二层或第二层或第一层或第二层或第二层或第二层或 随后将电晕处理的第一层或多层与电晕处理或未经处理的第二层或多层组合在一起。
    • 4. 发明申请
    • METHOD FOR PRODUCING A CROSS-LINKED POLYMER COMPOSITION WITH COLORING AGENTS FOR ELECTROPHOTOGRAPHIC TONER
    • 方法用于生产具有彩色资金有交联聚合物组成,电力照相调色剂
    • WO9915577B1
    • 1999-05-20
    • PCT/EP9805538
    • 1998-09-01
    • BASF AGBAUER STEPHANCZECH ERWINNEUSS MICHAEL
    • BAUER STEPHANCZECH ERWINNEUSS MICHAEL
    • C08G63/02C08G81/02C08L25/02C08L77/00G03G9/087
    • G03G9/08793C08G63/02C08G81/024C08L25/02C08L77/00G03G9/08708G03G9/08728C08L2666/14C08L25/00
    • The invention relates to a method for producing a polymer composition in which at least 1) a polymerization of a mixture comprised of a) from 60 to 99.999 wt. % styrene or a styrene derivative of general formula (I), wherein R1, R2, R3 are each independent of one another, represent hydrogen, methyl or ethyl, and denote n 1 or 2 or a mixture of two or more thereof; b) 0 to 40 wt. % of a C1-C12 alkyl ester of acrylic or methacrylic acid, acrylonitrile or methacrylonitrile, acrylamide or methacrylamide which can be substituted on the amide nitrogen by one or two C1-C4 alkyl groups, maleinic acid anhydride or maleinic acid imide, which can be substituted on the imide nitrogen by one C1-C4 alkyl group or a mixture thereof; and c) 0 to 20 wt. % of one or more hydroxy containing acrylate or methacrylate derivatives; d) 0.001 to 20 wt. % of a monomer comprising two or more radical polymerizable functional groups as a cross-linker to obtain the prepolymer A, whereby, when the monomer component (c) is absent, hydroxyl groups in A are incorporated by using regulators containing hydroxyl groups. 2) A polycondensation of a mixture is carried out in which said mixture is comprised of alpha ) 5 to 95 wt. % of the prepolymer A, beta ) 0 to 95 wt. % of one polyol, one polyester or one polamide or a mixture thereof, and gamma ) 5 to 95 wt. % of at least one aliphatic or aromatic carboxylic acid with at least two carboxylic groups or esters of C1-C20 hydrocarbon alcohols in the molecule or at least one anhydride or a mixture thereof.
    • 本发明涉及一种用于制备聚合物组合物,以及那些其中至少1)的苯乙烯或通式(I)的苯乙烯衍生物的)60至99.999重量.-%的混合物的聚合,其中R1,R2,R3 各自彼此独立地代表氢,甲基或乙基,n是1或2,或两种或更多种的混合物; B)0至40重量C1至丙烯酸或甲基丙烯酸,丙烯腈或甲基丙烯腈,丙烯酰胺或甲基丙烯酰胺的C 12烷基酯,其可以是在酰胺氮被1或2个C 1 -C 4取代的烷基的%,马来酸酐 或可被C1至在酰亚胺氮,或它们的混合物C4烷基取代的马来酰亚胺; 和c)0至20重量含有丙烯酸或甲基丙烯酸衍生物的一个或多个羟基的%; D)重量具有两个或更多个可自由基聚合的官能团的作为交联剂的预聚物A,其中(在不存在单体成分)的羟基基团通过使用含羟基的调节Ç并入A中的单体的0001-20%; 和2)从5至95重量多元醇,聚酯或聚酰胺或它们的混合物,和γ)%的阿尔法的混合物的缩聚%)重量%的预聚物A的.-%,β)从0至95:5〜95重量。 - %进行至少一种脂肪族或在分子中具有至少两个羧基基团或C 1的酯至C20 Kohlenwasserstoffalkoholaten芳族羧酸或至少一种酐或它们的混合物。