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1. 发明申请

WO2012113761A1 METAL COMPLEXES WITH N-AMINOAMIDINATE LIGANDS 审中-公开
标题翻译：金属配合物与N-氨基酰胺配位体
公开(公告)号：WO2012113761A1
公开(公告)日：2012-08-30
申请号：PCT/EP2012/052878
申请日：2012-02-20
申请人： UMICORE AG & CO. KG , SUNDERMEYER, Joerg , SCHORN, Wolf , KARCH, Ralf
发明人： SUNDERMEYER, Joerg , SCHORN, Wolf , KARCH, Ralf
IPC分类号： C07F19/00 , C23C16/00
CPC分类号： C07F15/04 , B01J31/1805 , B01J2231/321 , B01J2531/0238 , B01J2531/10 , B01J2531/30 , B01J2531/40 , B01J2531/50 , C07C257/12 , C07C257/14 , C07F5/00 , C07F5/063 , C07F5/066 , C07F5/069 , C07F7/00 , C07F7/10 , C07F7/12 , C07F7/28 , C07F15/006 , C23C16/303 , C23C16/345
摘要： The invention relates to new metal complexes having N -aminoamidinate ligands, more particularly metal complexes having Ν,Ν' -bis(dimethylamino)acetamidinate, N,N' -bis(dimethylamino)formamidinate, N -dimethylaminoacetamidinate or N -dimethylamino-N'-isopropyl-acetamidinate ligands as well as to their preparation and use. The metal complexes are characterized by a five-membered chelate ring. The metal complexes are formed with the metals from the main groups of the PTE, but also with transition-group elements such as tantalum (Ta), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu) or zinc (Zn), and also with precious metals such as palladium (Pd). The complexes of the invention find use as precursors for the preparation of functional layers by means of gas-phase thin-film processes such as CVD, MO-CVD and ALD. Additionally they may be used as catalysts for olefin hydroamination and for olefin polymerization.
摘要翻译：本发明涉及具有N-氨基脒基配体的新的金属配合物，更具体地说，具有α，α'-双（二甲基氨基）乙酰胺化脒，N，N'-双（二甲基氨基）甲脒，N-二甲氨基乙酰脒基或N-二甲基氨基-N' - 异丙基 - 乙酰胺化物配体，以及它们的制备和用途。金属络合物的特征在于五元螯合环。金属络合物由PTE的主要金属形成，也可以与过渡族元素如钽（Ta），铁（Fe），钴（Co），镍（Ni），铜（Cu）或锌（Zn），以及贵金属如钯（Pd）。本发明的络合物通过气相薄膜工艺如CVD，MO-CVD和ALD，用作制备功能层的前体。另外它们可以用作烯烃聚合和烯烃聚合的催化剂。

2. 发明申请

WO2010127964A1 PROCESS FOR THE PREPARATION OF RUTHENIUM METATHESIS COMPLEX CATALYSTS 审中-公开
标题翻译：制备金属复合催化剂的方法
公开(公告)号：WO2010127964A1
公开(公告)日：2010-11-11
申请号：PCT/EP2010/055649
申请日：2010-04-27
申请人： F. HOFFMANN-LA ROCHE AG , DOPPIU, Angelino , KARCH, Ralf , PUENTENER, Kurt , RIVAS-NASS, Andreas , SCALONE, Michelangelo , WINDE, Roland , WOERNER, Eileen
发明人： DOPPIU, Angelino , KARCH, Ralf , PUENTENER, Kurt , RIVAS-NASS, Andreas , SCALONE, Michelangelo , WINDE, Roland , WOERNER, Eileen
IPC分类号： C07F15/00
CPC分类号： C07F15/0046
摘要： The invention relates to a novel process for the preparation of Ruthenium metathesis catalysts of the formula (I). Ruthenium metathesis catalysts have been widely applied in the synthesis of macrocyclic drug compounds.
摘要翻译：本发明涉及制备式（I）的钌复分解催化剂的新方法。钌复分解催化剂已经广泛应用于大环化合物的合成中。

3. 发明申请

WO2009121513A1 RUTHENIUM COMPLEXES HAVING (P-P)-COORDINATED DISPHOSPHORUS DONOR LIGANDS AND PROCESSES FOR PREPARING THEM 审中-公开
标题翻译：具有（P-P）相互作用的二磷酸盐配位体的钌络合物及其制备方法
公开(公告)号：WO2009121513A1
公开(公告)日：2009-10-08
申请号：PCT/EP2009/002204
申请日：2009-03-26
申请人： UMICORE AG & CO. KG , RIVAS-NASS, Andreas , KARCH, Ralf , WINDE, Roland , DOPPIU, Angelino , SCHNEIDER, Tina
发明人： RIVAS-NASS, Andreas , KARCH, Ralf , WINDE, Roland , DOPPIU, Angelino , SCHNEIDER, Tina
IPC分类号： C07F15/00
CPC分类号： C07F17/02 , B01J31/185 , B01J31/1865 , B01J31/2409 , B01J2231/643 , B01J2231/645 , B01J2531/821 , C07B53/00 , C07C51/36 , C07C53/126
摘要： The invention relates to ruthenium complexes which have a chiral diphosphorus donor ligand and in which the ruthenium has the oxidation state (+11) and the chiral diphosphorus donor ligand has bidentate P-P coordination to the ruthenium. The ruthenium complexes are present in two forms (cationic type A and uncharged type B), are cyclic and have a four- to six-membered ring incorporating the diphosphorus donor ligand. The chiral diphosphorus donor ligands are selected from the group consisting of diphosphines, diphospholanes, diphosphites, diphosphonites and diazaphospholanes. Furthermore, processes for preparing the ruthenium complexes of types A and B, which are based on ligand exchange reactions, are described. The Ru complexes are used as catalysts for homogeneous asymmetric catalysis for preparing organic compounds.
摘要翻译：本发明涉及具有手性二磷供体配体并且其中钌具有氧化态（+11）并且手性二磷供体配体的钌络合物与钌具有双齿P-P配位体。钌络合物以两种形式（阳离子型A和不带电荷的B）存在，是环状的并且具有掺入二磷供体配体的四至六元环。手性二磷供体配体选自二膦，二磷脂，二亚磷酸酯，二膦酸酯和二氮杂磷杂环戊烷。此外，描述了基于配体交换反应制备A型和B型钌络合物的方法。 Ru配合物用作制备有机化合物的均相不对称催化剂。

4. 发明申请

WO2008138540A1 RUTHENIUM COMPLEXES WITH (P-P)-COORDINATED FERROCENYLDIPHOSPHINE LIGANDS, PROCESS FOR PREPARING THEM AND THEIR USE IN HOMOGENEOUS CATALYSIS 审中-公开
标题翻译：具有（P-P）-COORINATED FERROCENYLDIPHOSPHINE LIGANDS的RUTHENIUM复合物，其制备方法及其在均相催化中的用途
公开(公告)号：WO2008138540A1
公开(公告)日：2008-11-20
申请号：PCT/EP2008/003695
申请日：2008-05-08
申请人： UMICORE AG & CO. KG , SALZER, Albrecht , DOPPIU, Angelino , LANGENSCHEIDT, Nadine , RIVAS-NASS, Andreas , KARCH, Ralf , WINDE, Roland , MAYRHOFER, Stefanie
发明人： SALZER, Albrecht , DOPPIU, Angelino , LANGENSCHEIDT, Nadine , RIVAS-NASS, Andreas , KARCH, Ralf , WINDE, Roland , MAYRHOFER, Stefanie
IPC分类号： C07F17/02 , B01J31/24
CPC分类号： B01J31/2409 , B01J2231/643 , B01J2231/645 , B01J2531/821 , C07F17/02
摘要： The invention relates to ruthenium complexes with a chiral ferrocenyldiphosphine ligand, wherein the ruthenium has the oxidation state (+II) and the chiral ferrocenyldiphosphine ligand has bidentate P-P coordination to the ruthenium. The ruthenium complexes are cyclic and with the ferrocenyldiphosphine ligand have an at least eight-membered ring. The ferrocenyldiphosphine ligands are selected from the group consisting of Taniaphos, Taniaphos-OH and Walphos ligands. A process for preparing the Ru complexes is described. The Ru complexes are used as catalysts for homogeneous asymmetric catalysis for preparing organic compounds.
摘要翻译：本发明涉及具有手性二茂铁基二膦配体的钌络合物，其中钌具有氧化态（+ II），并且手性二茂铁基二膦配体与钌具有双齿P-P配位。钌络合物是环状的，并且二茂铁基二膦配体具有至少八元环。二茂铁基二膦配体选自Taniaphos，Taniaphos-OH和Walphos配体。描述了Ru配合物的制备方法。 Ru配合物用作制备有机化合物的均相不对称催化剂。

5. 发明申请

WO2004039819A3 METHOD FOR THE PRODUCTION OF COMPOUNDS CONTAINING PALLADIUM (0) 审中-公开
标题翻译：用于生产钯（0）含CONNECTIONS
公开(公告)号：WO2004039819A3
公开(公告)日：2004-10-21
申请号：PCT/EP0312085
申请日：2003-10-30
申请人： UMICORE AG & CO KG , KAYSER BERND , KARCH RALF , BRIEL OLIVER , KLEINWAECHTER INGO
发明人： KAYSER BERND , KARCH RALF , BRIEL OLIVER , KLEINWAECHTER INGO
IPC分类号： C07F15/00
CPC分类号： C07F15/006
摘要： The invention relates to a method for the production of a compound containing palladium (0), which consists in reacting a palladium compound with one or several compounds of general (I), (II), (III). The compounds containing palladium (0) are suitable for use as homogeneous catalysts, as precursors in the in situ production of homogeneous catalysts or as precursors in the production of heterogeneous catalysts.
摘要翻译：本发明涉及一种方法，用于钯（0）含化合物，它包括一种钯化合物与通式（I）的一种或多种化合物反应的制备中，（II）或（III）在一种碱的存在下进行。含化合物的钯（0）可用作均相催化剂是有用的，作为用于生产均相催化剂的前体，如用于原位生产均相催化剂，或作为前体异构催化剂的制备前体。

6. 发明申请

WO2002095088A2 SURFACE COATING OF BLACK PLATINUM 审中-公开
标题翻译：黑色表面涂层
公开(公告)号：WO2002095088A2
公开(公告)日：2002-11-28
申请号：PCT/EP2002/005568
申请日：2002-05-21
申请人： OMG AG & CO. KG , OECHSLE, Michael , KARCH, Ralf , KAYSER, Bernd
发明人： OECHSLE, Michael , KARCH, Ralf , KAYSER, Bernd
IPC分类号： C23C18/08
CPC分类号： C23C18/122 , C23C18/08 , C23C18/1216 , C23C18/1266 , Y10T428/12875
摘要： The present invention provides a surface coating of platinum in which the coating is formed from platinum in a black modification. This can be obtained by applying an organic platinum complex compound with platinum in the oxidation state 0 that decomposes thermally at temperatures below 200 °C, or a coating composition which consists substantially of such a platinum complex compound, to the surface of a substrate and then thermally decomposing the platinum complex compound. The surface coatings can be used in many ways, for example as protective layers against mechanical and/or chemical and/or thermal effects, as antiadhesion layers, as antireflective layers or as catalytically active layers.
摘要翻译：本发明提供了铂的表面涂层，其中涂层由黑色改性的铂形成。这可以通过将氧化态为0的铂的铂有机合金化合物或者在低于200℃的温度下热分解的铂或铂基配合物的基本上由铂配位化合物组成的涂料组合物施加到基材的表面上热分解铂络合物。表面涂层可以以许多方式使用，例如作为抗机械和/或化学和/或热效应的保护层，作为抗粘附层，抗反射层或催化活性层。

7. 发明申请

WO2011057780A2 PROCESS FOR PREPARING RUTHENIUM(0)-OLEFIN COMPLEXES 审中-公开
标题翻译：制备（0） - 烯烃复合物的方法
公开(公告)号：WO2011057780A2
公开(公告)日：2011-05-19
申请号：PCT/EP2010/006858
申请日：2010-11-11
申请人： UMICORE AG & CO. KG , DOPPIU, Angelino , RIVAS-NASS, Andreas , KARCH, Ralf , WINDE, Roland , WOERNER, Eileen
发明人： DOPPIU, Angelino , RIVAS-NASS, Andreas , KARCH, Ralf , WINDE, Roland , WOERNER, Eileen
IPC分类号： C07F15/00 , C23C16/18 , B01J31/00 , A61K31/28
CPC分类号： C23C16/18 , A61K31/28 , B01J31/00
摘要： The present invention relates to a process for preparing ruthenium(0)-olefin complexes of the (arene)(diene)Ru(0) type by reacting a ruthenium starting compound of the formula Ru(+II)(X) p (Y) q (in which X = an anionic group, Y = an uncharged two-electron donor ligand, p = 1 or 2, q = an integer from 1 to 6), with a cyclohexadiene derivative or a diene mixture comprising a cyclohexadiene derivative, in the presence of a base. In this process, the arene bound in the (arene)(diene)Ru(0) complex is formed from this cyclohexadiene derivative by oxidation. Suitable ruthenium(II) starting compounds are, for example, RuCl 2 (acetonitrile) 4 , RuCl 2 (pyridine) 4 or RuCl 2 (DMSO) 4 . The bases used are inorganic or organic bases. The ruthenium(0)-olefin complexes prepared by the process according to the invention have a high purity and can be used as precursors for homogeneous catalysts, for preparation of functional ruthenium- or ruthenium oxide-containing layers and for therapeutic applications.
摘要翻译：本发明涉及一种制备（芳烃）（二烯）Ru（O）型钌（O） - 烯烃络合物的方法，通过使式钌（+ II）（X）p（Y） q（其中X =阴离子基团，Y =不带电荷的双电子供体配体，p = 1或2，q = 1至6的整数）与环己二烯衍生物或包含环己二烯衍生物的二烯混合物一个基地的存在。在该方法中，通过氧化由该环己二烯衍生物形成（芳烃）（二烯）Ru（O）络合物中的芳烃。合适的钌（II）起始化合物是例如RuCl 2（乙腈）4，RuCl 2（吡啶）4或RuCl 2（DMSO）4。使用的碱是无机或有机碱。通过本发明方法制备的钌（O） - 烯烃络合物具有高纯度，可用作均相催化剂的前体，用于制备功能性含钌或氧化钌层并用于治疗应用。

8. 发明申请

WO2010037550A1 METHOD FOR PREPARATION OF RUTHENIUM-INDENYLIDENE CARBENE CATALYSTS 审中-公开
标题翻译：制备亚苄基碳二亚胺催化剂的方法
公开(公告)号：WO2010037550A1
公开(公告)日：2010-04-08
申请号：PCT/EP2009/007072
申请日：2009-10-02
申请人： UMICORE AG & CO. KG , WINDE, Roland , KARCH, Ralf , RIVAS-NASS, Andreas , DOPPIU, Angelino , PETER, Gerhard , WOERNER, Eileen
发明人： WINDE, Roland , KARCH, Ralf , RIVAS-NASS, Andreas , DOPPIU, Angelino , PETER, Gerhard , WOERNER, Eileen
IPC分类号： C07F15/00
CPC分类号： C07F15/0046
摘要： The present invention is directed to a method for the preparation of ruthenium indenylidene carbene catalysts of the type (L)(L' )X 2 Ru(II)(aryl-indenylidene). The method comprises the steps of reacting the precursor compound Ru(PPh 3 ) n X 2 (n = 3 - 4) with a propargyl alcohol derivative in an cyclic diether solvent such as 1,4-dioxane at temperatures in the range of 80 to 130°C and reaction times of 1 to 60 minutes. Optionally, additional neutral electron donor ligands such as PCy 3 , phobane ligands or NHC ligands are added to the reaction mixture for ligand exchange. The method includes a precipitation step for purification, after which the product is isolated. The ruthenium-indenylidene carbene catalysts are obtained in high purity and are used as catalysts for metathesis reactions (RCM, ROMP and CM) and as precursors for the synthesis of modified ruthenium carbene catalysts.
摘要翻译：本发明涉及一种（L）（L'）X2Ru（II）（芳基 - 亚茚基）类型的钌亚茚基碳烯催化剂的制备方法。该方法包括以下步骤：使前体化合物Ru（PPh 3）n X 2（n = 3- 4）与炔丙醇衍生物在环状二醚溶剂如1,4-二恶烷中在80-130℃的温度下反应反应时间为1〜60分钟。任选地，向反应混合物中加入另外的中性电子给体配体如PCy3，phobane配体或NHC配体用于配体交换。该方法包括用于纯化的沉淀步骤，之后分离产物。获得高纯度的钌 - 亚茚基碳烯催化剂，并用作复分解反应（RCM，ROMP和CM）的催化剂，并用作合成改性钌卡宾催化剂的前体。

9. 发明申请

WO2009146870A1 PROCESS FOR PREPARING DIENYL-RUTHENIUM COMPLEXES 审中-公开
标题翻译：制备二烯 - 钌复合物的方法
公开(公告)号：WO2009146870A1
公开(公告)日：2009-12-10
申请号：PCT/EP2009/003904
申请日：2009-05-30
申请人： UMICOR AG & CO. KG , DOPPIU, Angelino , RIVAS-NASS, Andreas , KARCH, Ralf , WINDE, Roland
发明人： DOPPIU, Angelino , RIVAS-NASS, Andreas , KARCH, Ralf , WINDE, Roland
IPC分类号： C07F15/00 , C07F17/00
CPC分类号： C07F15/0046 , C07F17/02
摘要： The present invention relates to a single-stage process for preparing dienyl- ruthenium complexes of the formula Ru(+II)(dienyl) 2 , wherein an Ru(II) starting compound of the formula Ru(X) p (Y) q is reacted with a diene ligand in the presence of an inorganic and/or organic base in a single-stage process. Here, polar organic solvents, preferably mixtures of polar organic solvents with water, are used. The dienyl-ruthenium complexes prepared according to the invention are used as precursors for homogeneous catalysts, for producing functional coatings and for therapeutic applications.
摘要翻译：本发明涉及制备式Ru（+ II）（二烯基）2的二烯基 - 钌络合物的单阶段方法，其中式Ru（X）p（Y）q的Ru（II）起始化合物是在单级方法中在无机和/或有机碱的存在下与二烯配体反应。这里，使用极性有机溶剂，优选极性有机溶剂与水的混合物。根据本发明制备的二烯基 - 钌络合物用作均相催化剂的前体，用于制备功能性涂层和用于治疗应用。

10. 发明申请

WO2007010453A3 TRANSITION METAL COMPOUNDS HAVING A CYCLIC PHOSPHORUS-CONTAINING LIGAND AND A CYCLIC ORGANIC LIGAND FOR USE IN METATHESIS REACTIONS 审中-公开
公开(公告)号：WO2007010453A3
公开(公告)日：2007-01-25
申请号：PCT/IB2006/052374
申请日：2006-07-12
申请人： SASOL TECHNOLOGY (UK) LIMITED , WINDE, Roland , KARCH, Ralf Wilheim , RIVAS-NASS, Andreas , BRIEL, Oliver , TOOZE, Robert Paul , FORMAN, Grant Stephen , MEYER, Wolfgang Hubert
发明人： WINDE, Roland , KARCH, Ralf Wilheim , RIVAS-NASS, Andreas , BRIEL, Oliver , TOOZE, Robert Paul , FORMAN, Grant Stephen , MEYER, Wolfgang Hubert
IPC分类号： C07C6/02 , C07F15/00
摘要： According to the present invention there is provided a compound in the form of a transition metal compound including a transition metal, a phosphorus containing ligand, and a cyclic organic ligand. The phosphorus containing ligand is a heterocyclic organic compound with a ligating phosphorus atom which ligates with the transition metal, and which ligating phosphorus atom is an atom in the heterocyclic ring structure of the heterocyclic organic compound. The cyclic organic ligand is a cyclic organic compound with a ligating carbon atom in the cyclic ring structure of the cyclic organic compound which ligates with the transition metal by means of a double bound. The invention also relates to a method preparing such a compound and a metathesis reaction wherein such a compound is used as a catalyst.

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