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1. 发明授权

US11685870B2 Integrated process with a depolyaromatization column for the production of benzene, toluene and xylenes from pyrolysis fuel oil stream 有权
公开(公告)号：US11685870B2
公开(公告)日：2023-06-27
申请号：US17683575
申请日：2022-03-01
申请人： Saudi Arabian Oil Company
发明人： Miao Sun , Zhonglin Zhang , Sohel K. Shaikh , Omer Koseoglu
IPC分类号： C10G69/06 , C10G55/04 , C10G67/06 , C10G69/12 , C10G25/00
CPC分类号： C10G69/06 , C10G25/003 , C10G55/04 , C10G67/06 , C10G69/126 , C10G2400/30
摘要： A catalytic upgrading process includes introducing a feed comprising crude oil to a steam cracking unit, thereby producing pyrolysis fuel oil (PFO). The PFO is introduced to a first catalytic depolyaromatization reactor to remove polyaromatics from the feed, thereby producing polyaromatics adsorbed to the catalyst and depolyaromatized PFO. The depolyaromatized PFO is introduced to a hydrocracking unit. The resulting benzene-toluene-xylenes (BTX) and liquid petroleum gas (LPG) are separated, and the BTX is introduced to a BTX complex to produce refined BTX. The LPG can then be introduced to the steam cracking unit. After depolyaromatization, a wash solvent is introduced into the first catalytic depolyaromatization reactor to remove the polyaromatics, regenerate the catalyst, and produce a mixture comprising the wash solvent and the polyaromatics. The wash solvent is separated from the polyaromatics.

2. 发明申请

US20230091233A1 Hydrocarbon Pyrolysis of Feeds Containing Sulfur 有权
公开(公告)号：US20230091233A1
公开(公告)日：2023-03-23
申请号：US17904682
申请日：2021-03-09
申请人： ExxonMobil Chemical Patents Inc.
发明人： Alok Srivastava , Rodney S. Smith , James P. Chapman
IPC分类号： C10G55/04 , C07C4/06 , C07C5/05 , C10G69/06
摘要： The present disclosure relates to processes, apparatuses, and systems for the removal of sulfur compounds from a heavy hydrocarbon feed as part of steam cracking processes to produce light olefins. In at least one embodiment, the process includes introducing a hydrocarbon feed having a first sulfur content to a steam cracker to produce a steam cracker effluent having a second sulfur content less than the first sulfur content. The process includes introducing the steam cracker effluent to a fractionation system to produce a light hydrocarbon product stream having a third sulfur content less than the second sulfur content.

3. 发明授权

US11577227B1 Two stage catalytic process for pyrolysis oil upgrading to btex 有权
公开(公告)号：US11577227B1
公开(公告)日：2023-02-14
申请号：US17519758
申请日：2021-11-05
申请人： Saudi Arabian Oil Company
发明人： Miao Sun , Sohel K. Shaikh , Ibrahim A. Abba , Noor Al-Mana , Ke Zhang , Zhonglin Zhang
IPC分类号： C10G69/02 , B01J8/02 , B01J8/08 , B01J23/83 , B01J23/00 , B01J29/78 , C10G69/06
摘要： In accordance with one or more embodiments of the present disclosure, a multi-stage process for upgrading pyrolysis oil comprising polyaromatic compounds to benzene, toluene, ethylbenzene, and xylenes (BTEX) includes upgrading the pyrolysis oil in a slurry-phase reactor zone to produce intermediate products, wherein the slurry-phase reactor zone comprises a mixed metal oxide catalyst; and hydrocracking the intermediate products in a fixed-bed reactor zone to produce the BTEX, wherein the fixed-bed reactor zone comprises a mesoporous zeolite-supported metal catalyst.

4. 发明授权

US11549062B2 Renewable diesel fuel production in retrofitted fossil petroleum refinery to produce biofuel and bio-feedstock for steam crackers 有权
公开(公告)号：US11549062B2
公开(公告)日：2023-01-10
申请号：US17059581
申请日：2019-05-28
申请人： Total Research & Technology Feluy
发明人： Walter Vermeiren
IPC分类号： C10G3/00 , C10G69/06 , C11C1/04 , C11C1/08 , B01J19/00 , B01J19/24 , C11C1/10
摘要： The present invention relates to a process for the conversion of a feedstock comprising at least 50 wt % related to the total weight of the feedstock of triglycerides, fatty acid esters and/or fatty acids having at least 10 carbon atoms into hydrogen, olefins, dienes, aromatics, gasoline, diesel fuel, jet fuel, naphtha and liquefied petroleum gas comprising: a) introducing of said feedstock in a first reactor to produce linear paraffins in presence of a hydrodesulfurization catalyst and hydrogen, b) separating the effluent of said first reactor in at least three parts to produce at least a first stream comprising part of said linear paraffins and at least a second stream comprising part of said linear paraffins, and at least a third stream comprising part of said linear paraffins c) sending said first stream to a steam cracker to produce hydrogen, olefins, dienes, aromatics and gasoline, diesel fuel being further fractionated; d) introducing said second stream into a second reactor in presence of a hydrocracking or hydroisomerization catalyst to produce a mixture comprising diesel fuel, jet fuel, naphtha and liquefied petroleum gas being further fractionated e) blending said third stream with the diesel fuel obtained at said step d) wherein said feedstock of said first reactor is diluted in order to limit the temperature increase within said first reactor; and wherein before entering the first reactor said dilution is performed with a weight ratio diluent:feedstock being 1:1, and wherein said diluent comprises at least part of said paraffins obtained at step b).

5. 发明申请

US20220348834A1 CONFIGURATION FOR OLEFINS AND AROMATICS PRODUCTION 有权
公开(公告)号：US20220348834A1
公开(公告)日：2022-11-03
申请号：US17812808
申请日：2022-07-15
申请人： LUMMUS TECHNOLOGY LLC , Saudi Aramco Technologies Company , Chevron Lummus Global LLC
发明人： Kareemuddin Shaik , Ujjal Mukherjee , Essam Abdullah Al-Sayed , Pedro Santos , Theodorus Maesen , Mazin Tamimi , Julie Chabot , Ibrahim Abba , Kandasamy Sundaram , Sami Barnawi , Ronald M. Venner
IPC分类号： C10G69/06 , B01J19/24 , C10L1/08 , C10G45/26 , C10G45/32 , C10G45/44 , C10G49/22 , C10G65/12 , C10G9/36 , C10G47/30 , C10G49/02 , C10G21/00 , C10G47/26 , C10G55/04
摘要： Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into at least light and heavy fractions. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize an ebullated bed reactor. Products from the upgrading operations may be used as feed to a steam cracker.

6. 发明授权

US11485918B2 Process for conversion of crudes and condensates to chemicals utilizing a mix of hydrogen addition and carbon rejection 有权
公开(公告)号：US11485918B2
公开(公告)日：2022-11-01
申请号：US16819964
申请日：2020-03-16
申请人： LUMMUS TECHNOLOGY LLC
发明人： Ujjal K. Mukherjee , Kandasamy Sundaram
IPC分类号： C10G69/00 , C10G69/06 , B01J8/18 , B01J8/24 , B01J19/24
摘要： Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into light and heavy fractions utilizing convection heat from heaters used in steam cracking. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize either an ebullated bed reactor with extrudate catalysts or a slurry hydrocracking reactor using a homogeneous catalyst system, such as a molybdenum based catalysts which may optionally be promoted with nickel. Products from the upgrading operations can be finished olefins and/or aromatics, or, for heavier products from the upgrading operations, may be used as feed to the steam cracker.

7. 发明授权

US11473023B2 Hydrocarbon pyrolysis processes 有权
公开(公告)号：US11473023B2
公开(公告)日：2022-10-18
申请号：US16971621
申请日：2019-02-07
申请人： ExxonMobil Chemical Patents Inc.
发明人： Christopher M. Evans , James R. Lattner
IPC分类号： C10G49/04 , C10G69/06 , C10G9/00 , C10G9/36
摘要： A hydrocarbon conversion process comprises pyrolysing at a temperature ≥700° C. a feedstock comprising hydrocarbon to produce a pyrolysis effluent comprising at least one C2 to C4 olefin and C5+ aliphatic and aromatic hydrocarbons. The pyrolysis effluent is contacted with an oleaginous quench stream to reduce the temperature of the pyrolysis effluent to ≤400° C. At least first and second streams are separated from the cooled effluent. The first stream comprises at least one C2 to C4 olefin, and the second stream comprises a quench oil having an average boiling point at atmospheric pressure of at least 120° C. At least a portion of the second stream is catalytically hydroprocessed to produce a hydroprocessed stream, which is combined with at least a portion of any remainder of the second stream to form the quench stream.

8. 发明申请

US20220298437A1 FLUIDIZED BED DEVOLATILIZATION AND CRACKING OF SOLID REFINERY RESIDUE 有权
公开(公告)号：US20220298437A1
公开(公告)日：2022-09-22
申请号：US17637209
申请日：2020-09-01
申请人： SHELL OIL COMPANY
发明人： Vikrant Nanasaheb URADE , Rajeev NARAYAN , Ganesh CHINTAKUNTA , Harshavardhan Jayant CHOUDHARI , Dhairya Dilip MEHTA , Ashwin Kumar NAGARAJAN
IPC分类号： C10G69/06 , C10B57/04 , C10B55/00 , C10B57/18 , C10B49/10 , C10B49/22
摘要： Implementations of the disclosed subject matter provide a process for upgrading refinery residue feedstock. Step a) may include introducing the refinery residue feedstock into a fluidized bed reactor as a solid. In step b), the refinery residue feedstock may be heated to a devolatilizing and thermal cracking temperature in the fluidized bed reactor to produce a product stream comprising gaseous hydrocarbons and solid coke. The gaseous hydrocarbons may be subjected to catalytic hydroprocessing, in step c), in the presence of molecular hydrogen to increase the hydrogen to carbon ratio and lower the average molecular weight of the gaseous hydrocarbons. In step d), the gaseous hydrocarbons may be separated from the solid coke. In step e), the gaseous hydrocarbons from step d) may be subjected to further processing to produce at least one of: C1-C3 hydrocarbons, liquefied petroleum gas, naphtha range hydrocarbons, and middle distillate range hydrocarbons.

9. 发明授权

US11421167B2 Integrated pyrolysis and hydrocracking units for crude oil to chemicals 有权
公开(公告)号：US11421167B2
公开(公告)日：2022-08-23
申请号：US17039767
申请日：2020-09-30
申请人： LUMMUS TECHNOLOGY LLC
发明人： Ujjal K. Mukherjee , Kandasamy Meenakshi Sundaram , Ronald M. Venner , Stephen J. Stanley
IPC分类号： C10G69/06 , C10G69/14
摘要： Integrated pyrolysis and hydrocracking systems and processes for efficiently cracking of hydrocarbon mixtures, such as mixtures including compounds having a normal boiling temperature of greater than 450° C., 500° C., or even greater than 550° C., such as whole crudes for example, are disclosed.

10. 发明申请

US20220195307A1 TRANSFER HYDROGENATION OF HEAVY HYDROCARBONS WITH HYDROGEN-DONOR SOLVENTS 有权
公开(公告)号：US20220195307A1
公开(公告)日：2022-06-23
申请号：US17654076
申请日：2022-03-09
申请人： Battelle Memorial Institute
发明人： SATYA P. CHAUHAN , DANIEL B. GARBARK
IPC分类号： C10G1/06 , C10G1/02 , C10G69/06 , C10G45/32 , C10G45/44 , C10G1/00 , C10G1/04
摘要： Processes for converting the coal-derived heavy-oil fraction of syncrude to polyols are described. The processes involve mixing a feed stream comprising the coal-derived heavy-oil fraction with an alcohol and aqueous sulfuric acid, heating the mixture, reacting the coal-derived heavy-oil fraction with ozone, and reacting the ozonated heavy-oil fraction with glycerin to form the polyol. In some cases, the ozonated heavy-oil fraction can be neutralized before reacting the ozonated heavy-oil fraction with the glycerin.

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