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1. 发明授权

US4350632A Water-soluble phthalocyanine compounds 失效
标题翻译：水溶性酞菁化合物
公开(公告)号：US4350632A
公开(公告)日：1982-09-21
申请号：US280814
申请日：1981-07-06
申请人： Hartmut Springer
发明人： Hartmut Springer
IPC分类号： C09B47/24 , C09B62/517 , D06P1/384 , C09B47/04 , C09B47/28
CPC分类号： C09B62/517
摘要： Phthalocyanine compounds of the general formula ##STR1## in which Pc is the radical of copper, cobalt or nickel phthalocyanine which can be substituted by chlorine or phenyl, a denotes a whole or fractional number from 1 to 3, b denotes a whole or fractional number from 1 to 3 and c denotes a whole or fractional number from zero to 2, it being possible for a, b and c to be identical or different from one another, but the total of (a+b+c) is equal to a whole or fractional number from 2 to 4, R represents a hydrogen atom or an alkyl group having 1 to 4 C atoms, A is a direct bond or a group of the general formula --(CH.sub.2).sub.m -- or --(CH.sub.2).sub.n --NH-- in which m denotes a whole number from 1 to 4 and n denotes a whole number from 2 to 6, B is the phenylene or naphthylene radical which can be substituted by alkyl having 1 to 4 C atoms, alkoxy having 1 to 4 C atoms, halogen, carboxy, sulfo, carbamoyl, sulfamoyl, alkylsulfonyl having 1 to 4 C atoms, carboalkoxy having 2 to 5 C atoms, acetylamino and nitro, D represents a direct bond or a radical of the formula --CH.sub.2 -- or --CH.sub.2 --CH.sub.2 --, Y represents the vinyl group or the .beta.-sulfatoethyl, .beta.-phosphatoethyl, .beta.-thiosulfatoethyl, .beta.-hydroxyethyl or .beta.-chloroethyl group and X is a hydrogen atom or the equivalent of a monovalent, bivalent or trivalent metal.
摘要翻译：其中Pc为可被氯或苯基取代的铜，钴或镍酞菁的基团，a表示1至3的整数或分数，b表示整数或从1到3的分数，c表示从0到2的整数或分数，a，b和c可以彼此相同或不同，但是（a + b + c）的总和是等于2至4的整数或分数，R表示氢原子或具有1至4个C原子的烷基，A为直接键或通式 - （CH 2）m - 或 - （CH 2））n-NH-，其中m表示1至4的整数，n表示2至6的整数，B为可被具有1至4个C原子的烷基取代的亚苯基或亚萘基，烷氧基具有1 至4个C原子，卤素，羧基，磺基，氨基甲酰基，氨磺酰基，具有1至4个C原子的烷基磺酰基，具有2至5个C原子的烷氧基羰基，乙酰氨基和 tro代表直接键或式-CH 2 - 或-CH 2 -CH 2 - 的基团，Y代表乙烯基或β-磺基乙基，β-磷酰乙基，β-硫代乙酰基乙基，β-羟乙基或β-氯乙基且X为氢原子或相当于一价，二价或三价金属。

2. 发明申请

US20110316936A1 GALLIUM NAPHTHALOCYANINE SALTS EXHIBITING REDUCED KOGATION 有权
标题翻译： GALLIUM NAPHTHALOCANANINE SALTS展览减少了KOGATION
公开(公告)号：US20110316936A1
公开(公告)日：2011-12-29
申请号：US13225481
申请日：2011-09-05
申请人： Simone Charlotte Vonwiller , Sutharsiny Indusegaram , Graciel Gonzaga , Damon Donald Ridley , Kia Silverbrook
发明人： Simone Charlotte Vonwiller , Sutharsiny Indusegaram , Graciel Gonzaga , Damon Donald Ridley , Kia Silverbrook
IPC分类号： B41J2/05 , B41J2/175 , C09B47/28
CPC分类号： C09B47/04 , B41J2/1404 , B41J2002/14475 , B41J2202/03 , C09B47/065 , C09B47/0678 , C09B47/24 , C09B69/04 , C09D11/328 , Y10T428/24802
摘要： A sulfonated dye salt of formula (II): wherein M is Ga(A1); A1 is an axial ligand selected from the group consisting of: —OH and halogen; and Z1+, Z2+, Z3+ and Z4+ are independently selected from the group consisting of: H and an ammonium cation including 3 or more hydroxyl groups. At least one of Z1+, Z2+, Z3+ and Z4+ is the ammonium cation. Such salts exhibit reduced kogation in thermal bubble-forming inkjet printheads.
摘要翻译：式（II）的磺化染料盐：其中M是Ga（A1）; A1是选自-OH和卤素的轴向配体; 和Z 1 +，Z 2 +，Z 3 +和Z 4 +独立地选自：H和包含3个或更多个羟基的铵阳离子。 Z1 +，Z2 +，Z3 +和Z4 +中的至少一个是铵阳离子。这种盐在热气泡形成喷墨打印头中表现出减少的结垢。

3. 发明授权

US4726847A Copper phthalocyanine pigment systems 失效
标题翻译：铜酞菁颜料体系
公开(公告)号：US4726847A
公开(公告)日：1988-02-23
申请号：US843867
申请日：1986-03-24
申请人： Calvin C. Wanser
发明人： Calvin C. Wanser
IPC分类号： C09B67/08 , C09B67/22 , C09B47/28
CPC分类号： C09B67/0004 , C09B67/0035
摘要： Copper phthalocyanine pigment systems with improved rheological and optical performance characteristics comprising copper phthalocyanine or halogen-substituted copper phthalocyanines blended with sulfonated copper phthalocyanine and provided with an anionic-cationic surfactant coating, and a process for the preparation thereof.
摘要翻译：具有改善的流变学和光学性能特征的铜酞菁颜料体系及其制备方法，包括与磺化铜酞菁共混的铜酞菁或卤素取代的铜酞菁，并提供阴离子 - 阳离子表面活性剂涂料。

4. 发明申请

US20210253863A1 ARTICLE INCLUDING PHTHALOCYANINE DYES 有权
公开(公告)号：US20210253863A1
公开(公告)日：2021-08-19
申请号：US17308555
申请日：2021-05-05
申请人： VIAVI SOLUTIONS INC.
发明人： Jaroslaw ZIEBA , Kangning LIANG
IPC分类号： C09B47/22 , C09B47/24 , C09B47/28 , C09B47/30 , G02F1/01
摘要： An article, includes a selective light modulator layer including a phthalocyanine dye having substituents that provide a bathochromic shift or a hypsochromic shift in the absorption spectrum. A method of making an article is also disclosed.

5. 发明授权

US3236860A Water-soluble phthalocyanine dyestuffs containing thiosulfuric acid groups 失效
标题翻译：含有硫代硫酸基团的水溶性酞菁染料
公开(公告)号：US3236860A
公开(公告)日：1966-02-22
申请号：US2271960
申请日：1960-04-18
申请人： HOECHST AG
发明人： WERNER SCHULTHEIS , KURT SCHIMMELSCHMIDT , HERMANN HOFFMANN , EDWIN BAIER
IPC分类号： C09B47/28 , C09B69/00 , D06P3/04
CPC分类号： C09B69/00 , C09B47/28 , D06P3/042
摘要： The invention comprises water-soluble dyes of the formula where F is the radical of a dioxazine, triphenyl-methane, phthalocyanine or nitro dye, R is hydrogen or a hydrocarbon radical, A is an alkylene radical or an arylene-alkylene, arylene-sulphonylamino-alkylene or arylene-carbonyl-amino-alkylene radical in which the arylene group is attached to the nitrogen atom and the alkylene group to the -SSO3Me group, the aromatic nucleus of which may contain alkyl or alkoxy groups or halogen atoms, Z is -SO2- or -CO-, Me is an alkali metal ion or ammonium and n is 1, 2, 3 or 4 and which dyes may contain further groups imparting solubility in water. The invention further comprises a process for making the above dyes and dyes of the above formula where F is an anthraquinone or azo dye radical and A, R, Me, Z and n are as above, by condensing an amine of the formula with a dye of the formula wherein F is the radical of a dye mentioned above, Z and n are as above and the halogen atom is capable of reacting with the amine defined above, in an aqueous or non-aqueous medium in the presence of an acid-binding agent at a temperature from about 0 DEG to 60 DEG C. at a pH of about 7 to 10 and the dye-stuff is then precipitated as an alkali metal or ammonium salt. Examples are given. The dyes dye wool, silk, polyamides and polyurethanes from an acid bath.

6. 发明申请

US20100003470A1 INKJET DYES EXHIBITING REDUCED KOGATION 有权
标题翻译： INKJET DYES展览减少了KOGATION
公开(公告)号：US20100003470A1
公开(公告)日：2010-01-07
申请号：US12466337
申请日：2009-05-14
申请人： Simone Charlotte Vonwiller , Sutharsiny Indusegaram , Graciel Gonzaga , Damon Donald Ridley , Kia Silverbrook
发明人： Simone Charlotte Vonwiller , Sutharsiny Indusegaram , Graciel Gonzaga , Damon Donald Ridley , Kia Silverbrook
IPC分类号： B32B3/10 , C07F15/00 , B05D5/06 , C07F15/02 , C07F15/04 , C07F15/06 , C07F7/02 , C07F1/08 , C07F3/02 , C07F3/06 , C07F5/06 , C07F7/22 , C07F7/24 , C09B47/28
CPC分类号： C09B47/04 , B41J2/1404 , B41J2002/14475 , B41J2202/03 , C09B47/065 , C09B47/0678 , C09B47/24 , C09B69/04 , C09D11/328 , Y10T428/24802
摘要： A salt of a sulfonated dye comprising an ammonium cation as a counterion. The ammonium cation comprises at least 3 hydroxyl groups. The salt is useful in reducing kogation in thermal inkjet printheads. One example of these salts is the compound of formula (II): wherein M is Ga(OH); and each of Z1+, Z2+, Z3+ and Z4+ is protonated 2,2-bis(hydroxymethyl)-2,2′,2″-nitrilotriethanol.
摘要翻译：包含铵阳离子作为抗衡离子的磺化染料的盐。铵阳离子包含至少3个羟基。该盐可用于减少热喷墨打印头中的结垢。这些盐的一个实例是式（II）的化合物：其中M是Ga（OH）; 并且Z1 +，Z2 +，Z3 +和Z4 +各自为质子化的2,2-双（羟甲基）-2,2'，2“ - 次氮基三乙醇。

7. 发明授权

US4576755A Water-soluble fibre-reactive phthalocyanine compounds 失效
标题翻译：水溶性纤维反应性酞菁化合物
公开(公告)号：US4576755A
公开(公告)日：1986-03-18
申请号：US660266
申请日：1984-10-15
申请人： Peter Mischke , Hermann Fuchs
发明人： Peter Mischke , Hermann Fuchs
IPC分类号： C09B67/12 , C09B47/04 , C09B62/517 , C09B47/28 , C09B47/30
CPC分类号： C09B62/517
摘要： Water-soluble fiber-reactive phthalocyanine compounds of the general formula (1) ##STR1## in which Pc denotes the radical of metal-free or metal-containing phthalocyanine, with the sulfonic acid or sulfonamide groups being bonded in the 3-positions of the aromatic rings of the phthalocyanine, R.sub.1 and R.sub.2 each denote a hydrogen atom or an alkyl group of 1-6 carbon atoms and which can be substituted by methoxy, ethoxy, propoxy, C.sub.2 H.sub.5 --O--C.sub.2 H.sub.4 --O--, cyano, acetylamino, carboxyl, HO.sub.3 S--, H.sub.2 O.sub.3 P--, phenyl, methylphenyl, methoxyphenyl, dimethylamino, diethylamino, .beta.-hydroxyethylamino, .beta.-hydroxyethoxy, N-phenylureido, N-alkyl.sub.C.sbsb.1.sub.-C.sbsb.4 ureido or N-cycloalkylureido groups or an allyl, 2-methallyl, crotyl or cycloalkyl group, and R.sub.1 and R.sub.2, together with the nitrogen atom, can represent the radical of a heterocyclic saturated or unsaturated ring, or R.sub.1 and R.sub.2 represent a phenyl radical which can be substituted by methyl, ethyl, methoxy, ethoxy, carboxyl or sulfonic acid groups, R.sub.3 denotes a hydrogen atom or an alkyl group of 1 to 4 carbon atoms and which can be substituted by hydroxyl or carboxyl groups, X represents a hydrogen atom or an alkyl or alkoxy group of 1 to 4 carbon atoms, Y represents the vinyl group or the grouping of the formula --CH.sub.2 --CH.sub.2 --Z in which Z denotes an inorganic or organic radical which can be eliminated under alkaline conditions, a represents a number between 0 and 2, b represents a number between 0 and 2 and c represents a number between 1.7 and 2.6, with the proviso that the sum of a, b and c is at most 4, a process for their preparation, and their use for dyeing wool, silk, polyamide fibers, leather or materials containing hydroxyl groups.
摘要翻译：通式（1）的水溶性纤维反应性酞菁化合物（1）其中Pc表示无金属或含金属酞菁的基团，磺酸或磺酰胺基团键合在3- 酞菁的芳环的位置R1和R2各自表示氢原子或1-6个碳原子的烷基，可以被甲氧基，乙氧基，丙氧基，C2H5-O-C2H4-O-，氰基，乙酰氨基，羧基，HO3S-，H2O3P-，苯基，甲基苯基，甲氧基苯基，二甲基氨基，二乙基氨基，β-羟乙基氨基，β-羟基乙氧基，N-苯基脲基，N-烷基C1-C4脲基或N-环烷基脲基或烯丙基2-甲代烯丙基，巴豆基或环烷基，R 1和R 2与氮原子一起可以表示杂环饱和或不饱和环的基团，或R 1和R 2表示可被甲基，乙基，甲氧基，乙氧基，羧基取代的苯基或磺酸基，R 3表示氢原子或1〜4个碳原子的烷基，可以被羟基或羧基取代，X表示氢原子或1〜4个碳原子的烷基或烷氧基，Y表示乙烯基或式-CH2-CH2-Z，其中Z表示在碱性条件下可以除去的无机或有机基团，a表示0和2之间的数字，b表示0和2之间的数字，c表示1.7和2.6之间的数字，条件是a，b和c的总和最多为4，其制备方法及其用于染色羊毛，丝绸，聚酰胺纤维，皮革或含有羟基的材料的使用。

8. 发明授权

US3577429A Phthalocyanine dye and method for making same 失效
标题翻译：邻苯二甲酸染料及其制备方法
公开(公告)号：US3577429A
公开(公告)日：1971-05-04
申请号：US3577429D
申请日：1968-03-11
申请人： THOMAS C CRAWFORD
发明人： CRAWFORD THOMAS C
IPC分类号： C09B47/28 , C09B49/12 , D06P1/30 , C09B47/08
CPC分类号： C09B47/28 , C09B49/122 , D06P1/305
摘要： COPPER TETRA-(4)-SODIOTHIOSULFATOPHTHALOCYANINE DYE USEFUL FOR DYEING COTTON AND REGENERATED CELLULOSE TEXTILES GREEN IS PREPARED BY SIMULTANESOULY HEATING AND AERATING FOR 1-36 HOURS AT 40*C.-90*C. AND AT PH 6.57.5 AN AQUEOUS COMPOSITION COMPRISING 1 PART COPPER TETRA-(4)-THIOCYANOPHTHALOCYANINE, 0.65-1.3 PARTS SODIUM BISULFITE, AND 0.65-1.3 PARTS SODIUM SULFITE, AND FURTHER CHARACTERIZED IN THAT THE PARTS OF SODIUM SULFITE AND SODIUM BISULFITE ARE APPROXIMATELY EQUAL.

9. 发明授权

US07964719B2 Inkjet ink comprising gallium naphthalocyanine dye 有权
标题翻译：包含镓萘酞菁染料的喷墨油墨
公开(公告)号：US07964719B2
公开(公告)日：2011-06-21
申请号：US11583942
申请日：2006-10-20
申请人： Simone Charlotte Vonwiller , Scott Matthew Starling , Damon Donald Ridley , Lachlan Everett Hall , Simon Fielder , Sutharsiny Indusegaram , Kia Silverbrook , Paul Lapstun
发明人： Simone Charlotte Vonwiller , Scott Matthew Starling , Damon Donald Ridley , Lachlan Everett Hall , Simon Fielder , Sutharsiny Indusegaram , Kia Silverbrook , Paul Lapstun
IPC分类号： C07D209/62 , C09B47/28
CPC分类号： C09B47/24 , C09B47/045 , C09B47/0678 , C09B67/0086 , C09B67/009 , C09D11/32 , C09D11/328 , G06F3/03545
摘要： An inkjet ink for use in netpage, Hyperlabel and other applications. The ink includes an IR-absorbing dye of formula (I): wherein M is Ga(A1); A1 is an axial ligand selected from —OH, halogen, —OR3, —OC(O)R4, a hydrophilic ligand and/or a ligand suitable for reducing cofacial interactions; R1 and R2 may be the same or different and are selected from hydrogen or C1-12 alkoxy; R3 is selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl or Si(Rx)(Ry)(Rz); R4 is selected from C1-12 alkyl, C5-12 aryl or C5-12 arylalkyl; Rx, Ry and Rz may be the same or different and are selected from C1-12 alkyl, C5-12 aryl, C5-12 arylalkyl, C1-12 alkoxy, C5-12 aryloxy or C5-12 arylalkoxy; W is a hydrophilic group, each W group being independently selected from a substituent including a sulfonic acid group (including salts thereof), or a substituent comprising a sulfonamide group; n1 is 0, 1, 2 or 3; n2 is 0, 1, 2 or 3; n3 is 0, 1, 2 or 3; n4 is 0, 1, 2 or 3; and at least one of n1, n2, n3 or n4 is greater than 0.
摘要翻译：用于网页，超标签和其他应用的喷墨墨水。油墨包括式（I）的IR吸收染料：其中M是Ga（A1）; A1是选自-OH，卤素，-OR3，-OC（O）R4，亲水配体和/或适于还原亲合相互作用的配体的轴向配体; R 1和R 2可以相同或不同，并且选自氢或C 1-12烷氧基; R3选自C1-12烷基，C5-12芳基，C5-12芳基烷基或Si（Rx）（Ry）（Rz）; R4选自C1-12烷基，C5-12芳基或C5-12芳烷基; R x，R y和R z可以相同或不同，并且选自C 1-12烷基，C 5-12芳基，C 5-12芳基烷基，C 1-12烷氧基，C 5-12芳氧基或C 5-12芳烷氧基; W是亲水基团，每个W基团独立地选自包括磺酸基团（包括其盐）的取代基或包含磺酰胺基团的取代基; n1为0,1,2或3; n2为0,1,2或3; n3为0,1,2或3; n4为0,1,2或3; n1，n2，n3或n4中的至少一个大于0。

10. 发明申请

US20110073005A1 POLYPHENYLATED PHTHALOCYANINES WITH NEAR-INFRARED ABSORPTION 有权
标题翻译：具有近红外吸收的聚苯乙烯亚胺
公开(公告)号：US20110073005A1
公开(公告)日：2011-03-31
申请号：US12570902
申请日：2009-09-30
申请人： Sivapackia Ganapathiappan , Jayprakash Bhatt , Hou Ng
发明人： Sivapackia Ganapathiappan , Jayprakash Bhatt , Hou Ng
IPC分类号： C09D11/00 , C09B47/04 , C09B47/28 , C09B47/06
CPC分类号： C09D11/328 , C09B47/045 , C09B47/0678
摘要： Polyphenylated phthalocyanine water-soluble dyes with near-infrared absorption comprise four isoindole units linked together in a large ring to form a phthalocyanine macrocycle, with either four anthracenyl groups or four naphthacenyl groups each linked to an isoindole, and a metal atom optionally complexed to the phthalocyanine macrocycle.
摘要翻译：具有近红外吸收的多苯基酞菁水溶性染料包括四个异吲哚单元，其以大环连接在一起以形成酞菁大环化合物，其具有四个蒽基或四个连氮杂基基团，每个连接于异吲哚，并且金属原子任选地与酞菁大环。

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