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    • 5. 发明授权
    • Cellulose ethers and cellulose mixed ethers having at least one
phosphorus-containing substituent, and process for their manufacture
    • 具有至少一个含磷取代基的纤维素醚和纤维素混合醚及其制造方法
    • US4413121A
    • 1983-11-01
    • US363148
    • 1982-03-29
    • Lothar BrandtArno HolstHans-Jerg Kleiner
    • Lothar BrandtArno HolstHans-Jerg Kleiner
    • C08B11/04C08B11/10C08B11/193C08B11/145
    • C08B11/10C08B11/04C08B11/193
    • Disclosed is a cellulose ether having at least one phosphorus-containing substituent or a mixed ether of said cellulose ether having in addition at least one phosphorus-free substituent comprising alkyl, hydroxyalkyl, carboxyalkyl, sulfonoalkyl, aminoalkyl, or diaminoalkyl, wherein the phosphorus-containing substituent(s) comprise(s) groups of the formula ##STR1## wherein R.sup.1 and R.sup.2 are OX; or R.sup.1 is OX and R.sup.2 is OY; or R.sup.1 is OX and R.sup.2 is (CH.sub.2).sub.n --CH.sub.3 ; or R.sup.1 and R.sup.2 are (CH.sub.2).sub.n --CH.sub.3 ; or R.sup.1 is (CH.sub.2).sub.n --CH.sub.3 and R.sup.2 is (CH.sub.2).sub.p --CH.sub.3, whereinX,Y are identical or different and comprise a hydrogen atom or a monovalent cation;m is an integer from 1 to 4; andn,p are identical or different and are 0 or 1; with the proviso that when m is 1 or 2, R.sup.1 and R.sup.2 may not be OX and R.sup.1 and R.sup.2 may not be OX and OY, respectively. Also disclosed is a process for producing these cellulose ether products.
    • 公开了具有至少一个含磷取代基的纤维素醚或所述纤维素醚的混合醚,另外还含有至少一个含有烷基,羟基烷基,羧基烷基,磺基烷基,氨基烷基或二氨基烷基的无磷取代基,其中含磷 取代基包含式(I)的基团,其中R 1和R 2是OX; 或R1是OX,R2是OY; 或R1是OX,R2是(CH2)n-CH3; 或R 1和R 2为(CH 2)n -CH 3; 或R 1为(CH 2)n -CH 3,且R 2为(CH 2)p -CH 3,其中X,Y相同或不同,并包含氢原子或一价阳离子; m是1至4的整数; 且n,p相同或不同,为0或1; 条件是当m为1或2时,R 1和R 2可以不是O X,并且R 1和R 2可以不分别为O X和O Y。 还公开了生产这些纤维素醚产物的方法。